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921.
Molybdenum is extracted as the thiocyanate complex with the quaternary long-chain aliphatic amine Aliquat 336 in chloroform, followed by evaporation of the solvent, dissolution in MIBK, and atomic-absorption spectroscopy. The method is simple, rapid and sensitive, with few interference problems for the determination of the Mo content of soils and sediments in the range 0.1-1.0 ppm with a relative standard deviation better than 5% when 1-g samples are used. Quantitative extraction from large volumes of aqueous solution has also been confirmed, allowing the determination of Mo in natural waters in the ppM range. 相似文献
922.
Using the results obtained from an MO SCF ab initio calculation on P2H4 in four different conformations, the 1J(PP) NMR coupling constants have been calculated. The 1J(PP) values are highly dependent upon the rotational angle φ (?238.0 Hz in the eclipsed conformation, 10.9 Hz in the staggered one). The shape of the theoretical 1J(PP) plot seems to be in good agreement with experimentally measured 1J(PP) values. 相似文献
923.
Langlet J. Claverie P. Pullman B. Piazzola D. Daudey J. P. 《Theoretical chemistry accounts》1977,46(2):105-116
The effect of water on the conformational preferences of acetylcholine has been studied within the discrete, the continuum and the combined discrete-continuum models described in parts I and II of this series. All the models lead to the conclusion that the trans-gauche form which is, following refined quantum-mechanical computations, the intrinsically preferred one and the one observed in the crystal of acetylcholine and of a number of analogues should remain also the preferred conformation in water. This result agrees with NMR studies. The results of the empirical discrete model used here compare favorably to those obtained by an ab initio super-molecule treatment. The continuum model utilized here represents a net improvement above such models utilized in other works. 相似文献
924.
Gregory D. Cuny 《Tetrahedron letters》2004,45(26):5167-5170
A synthesis of the alkaloid (±)-aporphine is reported. The initial key step of the synthesis involves a Pictet-Spengler cyclization of N-tosyl tyramine with 2-bromophenylacetaldehyde in trifluoroacetic acid. This step was followed by the second strategic transformation a palladium-mediated intramolecular phenol ortho-arylation reaction utilizing tricyclohexylphosphine as co-catalysts in the presence of cesium carbonate. Finally, de-oxygenation of the phenol, removal of the tosyl group and methylation gave the desired alkaloid. 相似文献
925.
A comparison of some results from Xα-scattered wave (Xα-SW) and extended Hückel (EH) calculations for metal clusters is given. It is found that small clusters of atoms (≈ 13 atoms) using the Xα-SW method reproduce many of the features of the electronic structure of the bulk metals, whereas this is not the case for the same clusters using the EH method. A more systematic approach to EH parametrizations is suggested in order to make this method a more viable approach to treating metal clusters. 相似文献
926.
927.
Zusammenfassung Es werden Untersuchungen beschrieben, bei denen Rückstoßprodukte schnell und selektiv in der Gasphase aufgetrennt werden. Ziel dieser Untersuchungen ist es, kurzlebige Kernreaktionsprodukte zu identifizieren, einerseits zum Studium der Kernreaktion und andererseits zur Messung von Zerfallsdaten neuer Nuklide.Die Rückstoßprodukte wurden von einer Cf-252-Quelle geliefert. Transportstrecke und Kühlfalle konnten auf verschiedene Temperaturen gebracht werden. Mit N2 als Trägergas war es möglich, unter geeigneten Bedingungen Te selektiv abzutrennen. Durch Zugabe von Cl2 wurden Sb, Tc, Nb, Mo, Zr, Ru und Sn transportiert. Transportausbeuten in Abhängigkeit von der Temperatur und der Gaszusammensetzung wurden bestimmt.Für die finanzielle Unterstützung danken wir der Gesellschaft für Schwerionenforschung, Darmstadt. 相似文献
928.
L.J. Vanmaele P.J. De Clercq M. Vandewalle S.J. Halkes W.R.M. Overbeek 《Tetrahedron》1984,40(7):1179-1182
An efficient method for the preparation of crystalline α-hydroxy previtamin D3 is described. Also the stereoselective reduction of 1-keto previtamin is discussed; it was observed that with aluminum hydride is the most abundant product. This stands in contrast with previously reported LiAlH4 and NaBH4 mediated reductions. 相似文献
929.
Zusammenfassung In der vorliegenden Arbeit wird das Sedimentationsgleichgewicht der Systeme Na6[H2W12O40]—NaCI—H2O und Na6[H2W12O40]—NaClO4— H2O untersucht. Die scheinbare molare Masse Mapp des Natriummetawolframats wird in beiden Systemen als Funktion der Natriummetawolfrarnat-Anfangspartialdichte
0
PX
z gemessen. Durch lineare Extrapolation der Funktion Mapp = Mapp (PP,, ) auf die Polymerelektrolyt-Anfangspartialdichte Null können die Grenzwerte der scheinbaren molaren Masse (Mapp)o ermittelt werden. Aus den (Mapp)o-Werten wird die Abhängigkeit der Größe (ln
PXz
/m
BX
)
mPXz von der NaCI- bzw. NaClO4-Molalität berechnet.Die Bestimmung der molaren Masse und der (stöchiometrischen) Ladungszahl eines Polymerelektrolyten aus den experimentell ermittelten (Mapp)o-Werten unter Anwendung der Lamm-Williams-Gleichung wird diskutiert. Zur Ermittlung der beiden Größen müssen mehrere Versuchsreihen mit zwei verschiedenen Fremdelektrolyten durchgeführt werden. Externe Messungen sind nicht erforderlich.Man erhält auf diese Weise verläßliche Werte so-wohl der molaren Masse als auch der (stächiometrischen) Ladungszahl.
Mit 5 Abbildungen und 3 Tabellen 相似文献
Summary The sedimentation equilibria of the systems sodium metatungstate-sodium chloride-water and sodium metatungstate-sodium perchlorate-water are investiated. In both systems the apparent molecular mass Mapp of sodium metatungstate (PX z) is measured in dependence on partial density 0 PX z before centrifugation. By linear extrapolation of the function Mapp = Mapp ( 0 PX z the limiting value (Mapp)o for 0 PX z = 0 is obtained. The variation with sodium chloride and sodium perchlorate molality of the quantity (ln PX z m BX )mPXz is calculated from (Mapp)o data.The determination of the molecular mass and the algebraic valency of a polymeric ion by means of the (Mapp)o values calculated by Lamm-Williams equation is discussed. In order to obtain these two quantities at least two series of experiments are required, each of which using a different supporting electrolyte. External measurements are not necessary. In this way reliable values for the molecular mass as well as for the stoichiometric valency are obtained.
Mit 5 Abbildungen und 3 Tabellen 相似文献
930.
Decomposition of isopropanol on V2O5 and the bonzes Li0.02V2O5, Na0.02V2O5, Na0.06V2O5, Li0.33V2O5, and Na0.33V2O5 has been studied in the temperature range 168–300°C. The main reaction was found to be dehydration to propene with negligible dehydrogenation to acetone on the first four catalysts. Dehydration on these catalysts increased with the alkali metal content, but the energy of activation remained unchanged. On the last two catalysts, dehydration and dehydrogenation proceeded at comparable rates. A tentative mechanism for the dehydration of isopropanol is proposed, based on the effect of the product on the initial rate, the electric conductivity of the catalysts and their ESR spectra.
V2O5 : Li0,02V2O5, Na0,02V2O5, Na0,06V2O5, Li0,33V2O5 Na0,33V2O5 186–300°C. . , . . , , .相似文献