The inclusion of electrostatic and dispersion interactions into potentials of mean torque for solutes dissolved in uniaxial liquid crystal solvents

A potential of mean torque is derived for a solute at infinite dilution in a uniaxial liquid crystal solvent, which contains terms originating from the dispersion interaction, and the electrostatic interaction between quadrupole moments on both molecules. It is shown that the electrostatic term is non-zero only if the solute-solvent vectors are distributed with lower than spherical symmetry. If this distribution has cylindrical symmetry then both the electrostatic and dispersion terms in the potential of mean torque are shown to depend on order parameters for the orientational distribution of the solute-solvent vectors, as well as on the order parameters of the solvent molecules.     

Energy transfer between the flavin chromophores of electron-transferring flavoprotein fromMegasphaera elsdenii as inferred from time-resolved red-edge and blue-edge fluorescence spectroscopy

Both a mode-locked argon-ion laser and synchrotron radiation were used as excitation sources to obtain time-resolved polarized fluorescence of the two FAD cofactors in electron transferring flavoprotein fromMegasphaera elsdenii. Red-edge excited and blue-edge detected fluorescence anisotropy decay curves did not contain a fast relaxation process which was observed upon mainband excitation and detection. This relaxation was assigned to homo-energy transfer between the two FAD cofactors. Failure of energy transfer as observed with edge spectroscopy on this protein excludes restricted reorientational motion of the flavins as a possible mechanism of depolarization. From the global analysis of the fluorescence anisotropy decay surface obtained at multiple excitation and detection wavelengths, the distance between and the relative orientation of the flavins could be estimated. The methodology described has general applicability in other multichromophoric biopolymers and has the potential to acquire accurate geometrical parameters in these systems.     

Laser stabilitron

We consider a new method for producing intensity stabilization of cw lasers. This method incorporates negative feedback from a nonlinear saturable absorber to provide wideband noise-reduction and may produce an output beam for which shot noise is below the quantum limit. This new method can be used with a large variety of cw lasers and is particularly applicable to frequency-stabilized lasers which are locked to absorption lines.Permanent address: Institute of Laser Physics, Novosibirsk 630090, Russia     

Towards an Operational Model for Prevention and Treatment of Asthma Attacks

Asthma is one of the major chronic diseases in many countries. At present there is no cure for asthma, but medical advances can help to reduce the chances of attacks of the condition. Efficient care for asthma involves complexity, uncertainty, variability and the use of scarce resources, and these are the same conditions that indicate a possible use for the modelling approach of operational research. This paper is concerned with a pilot model that was developed through joint work by medical professionals and operational researchers. The development of the model is explained and illustrative results indicate the potential value of the modelling approach for the care of asthma in the community.     

A Note on an Input Control Model of a Predictive Regression Interval

A well-known problem of prediction in linear regression models is to find a confidence interval for the random value of the dependent variable when the values of the independent variables are given. Such a situation may arise in economic quality control models when the independent variables are costly inputs and the dependent variable is some measure of quality or production. In such a circumstance, an important control objective may be to find values for the inputs that will maximize the lower limit of the prediction confidence interval for a fixed budget, or alternatively, to minimize the cost of the inputs for a fixed lower limit of the confidence interval. In this paper, we shall show that global optima can be found using known algorithms. The special case of simple linear regression is discussed and an illustrative example is provided.     

On aq-deformation of the discrete Painlevé I equation andq-orthogonal polynomials

We present aq-analog of the discrete Painlevé I equation, and a special realization of it in terms ofq-orthogonal polynomials.     

Some aerodynamic and acoustic characteristicsof acute laryngitis

The purpose of the present study was to describe the effects ofacute laryngitis on some aerodynamic, acoustic, and perceptual measures. Eleven subjects with diagnosed acute laryngitis due to upper respiratory infection were recorded during a laryngitic episode and 1 week to 10 days after amelioration of the laryngitic condition. Fundamental frequency values, collapsed across the five vowels, were significantly reduced in the laryngitic compared with the normal speaking condition. The decrease in fundamental frequency associated with acute laryngitis suggests an increase in the mass of the vocal folds. In addition, aerodynamic values differed significantly for the laryngitic condition compared with the normal speaking condition, suggesting the presence of laryngeal hypofunction. Perceptual data indicated that speakers in the laryngitic condition were judged to have a hoarse voice when compared with the normal speaking condition.     

Quark models and polarized electroproduction of the Roper resonance

We calculate the recoil polarization observables for neutral pion electroproduction on the proton. In particular, for theN(938)→N ^*(1440) transition, we study these observables for several quark models of the resonant amplitudes. We find that the polarization response functions, unlike the unpolarized cross section, have encouragingly large sensitivity to the presence of the Roper. Furthermore, these observables can clearly reveal the presence of a longitudinal coupling.