全文获取类型
收费全文 | 230562篇 |
免费 | 1351篇 |
国内免费 | 483篇 |
专业分类
化学 | 104881篇 |
晶体学 | 3608篇 |
力学 | 12128篇 |
综合类 | 5篇 |
数学 | 37167篇 |
物理学 | 74607篇 |
出版年
2018年 | 10137篇 |
2017年 | 11054篇 |
2016年 | 5621篇 |
2015年 | 1942篇 |
2014年 | 1452篇 |
2013年 | 4907篇 |
2012年 | 8018篇 |
2011年 | 17724篇 |
2010年 | 10451篇 |
2009年 | 10330篇 |
2008年 | 15282篇 |
2007年 | 19173篇 |
2006年 | 4246篇 |
2005年 | 11408篇 |
2004年 | 7195篇 |
2003年 | 6775篇 |
2002年 | 4557篇 |
2001年 | 3744篇 |
2000年 | 2996篇 |
1999年 | 2235篇 |
1998年 | 1931篇 |
1997年 | 1891篇 |
1996年 | 1980篇 |
1995年 | 1878篇 |
1994年 | 1639篇 |
1993年 | 1616篇 |
1992年 | 1822篇 |
1991年 | 1822篇 |
1990年 | 1752篇 |
1989年 | 1764篇 |
1988年 | 1775篇 |
1987年 | 1761篇 |
1986年 | 1666篇 |
1985年 | 2228篇 |
1984年 | 2363篇 |
1983年 | 1979篇 |
1982年 | 2296篇 |
1981年 | 2112篇 |
1980年 | 2157篇 |
1979年 | 2163篇 |
1978年 | 2295篇 |
1977年 | 2123篇 |
1976年 | 2182篇 |
1975年 | 2103篇 |
1974年 | 1944篇 |
1973年 | 2194篇 |
1972年 | 1322篇 |
1971年 | 1000篇 |
1968年 | 1152篇 |
1967年 | 1131篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
71.
The finite-difference method is a numerical technique for obtaining approximate solutions to differential equations. The main
objective of the present study is to give a new aspect to the finite-difference method by using a variational derivative.
By applying this formulation, accurate values of the buckling loads of beams and frames with various end supports are obtained.
The performance of this formulation is verified by comparison with numerical examples in the literature
__________
Published in Prikladnaya Mekhanika, Vol. 41, No. 7, pp. 139–144, July 2005. 相似文献
72.
L. B. Beinenson 《Journal of Mathematical Sciences》2005,129(2):3730-3756
For an arbitrary poset H and measure ρ on H × R (where R is the real axis), we construct a monotone decreasing stochastic field ηρ and compute its finite-dimensional distributions. In the case where H is a Λ-semilattice and the measure ρ satisfies additional conditions, we compute various characteristics of the field ηρ such as the expectation of the field value at a point, variance of the field value at a point, and correlation function of the field. The described construction of random fields gives a new method for constructing positive definite functions on posets. Bibliography: 6 titles.__________Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 301, 2003, pp. 92–143. 相似文献
73.
Catalytic properties of silica-supported heteropolyacids (HPA) in a mechanical mixture with reduced Me-Ce oxides (Me = Ni,
Pd) in n-hexane isomerization are studied. The role of each component of the mixed oxides (Ce and, typically, Ni and Pd) and their
optimum content has been illuminated: cerium is not only beneficial for eliminating or preventing coke deposition but is also
effective for maintaining the Keggin structure of the highly-organized HPA during the reaction and probably allows a better
dispersion of the second metal species. Nickel and palladium, present as Ni0 and Pd0, reinforce the activation of the alkane, which is difficult to obtain by means of a direct attack by an acid, and, thus,
enhance noticeably the activity of the catalyst. The best mechanical mixtures are obtained with 30–70 wt % NiCeO-HPW/SiO2 and 50–50 wt % Pd0.1CeO-HPW/SiO2. These mixtures have the highest efficiency for a Ni/(Ni + W) atomic ratio of 0.66 and a Pd/(Pd + W) ratio of 0.40, respectively.
Finally, the conversion of n-hexane is in the order HPW > HSiW > HBW, which seems to be consistent with the order of their acid strength as per the literature,
but the isomerization selectivity appears to be slightly higher on HSiW.
Published in Russian in Kinetika i Kataliz, 2006, Vol. 47, No. 1, pp. 24–28.
The text was submitted by the authors in English. 相似文献
74.
Morey Timothy E. Varshney Manoj Flint Jason A. Seubert Christoph N. Smith W. Brit Bjoraker David G. Shah Dinesh O. Dennis Donn M. 《Journal of nanoparticle research》2004,6(2):159-170
Background: Although microemulsion-based nanoparticles (MEs) may be useful for drug delivery or scavenging, these benefits must be balanced against potential nanotoxicological effects in biological tissue (bio-nano interface). We investigated the actions of assembled MEs and their individual components at the bio-nano interface of thrombosis and hemolysis in human blood.
Methods: Oil-in-water MEs were synthesized using ethylbutyrate, sodium caprylate, and pluronic F-68 (ME4) or F-127 (ME6) in 0.9% NaClw/v. The effects of MEs or components on thrombosis were determined using thrombo-elastography, platelet contractile force, clot elastic modulus, and platelet counting. For hemolysis, ME or components were incubated with erythrocytes, centrifuged, and washed for measurement of free hemoglobin by spectroscopy.
Results and conclusions: The mean particle diameters (polydispersity index) for ME6 and ME4 were 23.6 ± 2.5 nm (0.362) and 14.0 ± 1.0 nm (0.008), respectively. MEs (0, 0.03, 0.3, 3 mM) markedly reduced the thromboelastograph maximal amplitude in a concentration-dependent manner (49.0 ± 4.2, 39.0 ± 5.6, 15.0 ± 8.7, 3.8 ± 1.3 mm, respectively), an effect highly correlated (r2 = 0.94) with similar changes caused by pluronic surfactants (48.7 ± 10.9, 30.7 ± 15.8, 20.0 ± 11.3, 2.0 ± 0.5) alone. Neither oil nor sodium caprylate alone affected the thromboelastograph. The clot contractile force was reduced by ME (27.3 ± 11.1–6.7 ± 3.4 kdynes/cm2, P = 0.02, n = 5) whereas the platelet population not affected (175 ± 28–182 ± 23 106/ml, P = 0.12, n = 6). This data suggests that MEs reduced platelet activity due to associated pluronic surfactants, but caused minimal changes in protein function necessary for coagulation. Although pharmacological concentrations of sodium caprylate caused hemolysis (EC50 = 213 mM), MEs and pluronic surfactants did not disrupt erythrocytes. Knowledge of nanoparticle activity and potential associated nanotoxicity at this bio-nano interface enables rational ME design for in vivo applications. 相似文献
75.
V. S. Berezinsky 《Physics of Atomic Nuclei》2003,66(3):423-434
About 400 years have passed since the great discoveries by Galileo, Kepler, and Newton, but astronomy still remains an important source of discoveries in physics. They start with puzzles, with phenomena difficult to explain, and phenomena which in fact need new physics for explanation. Do such puzzles exist now? There are at least three candidates: absence of absorption of TeV gamma radiation in extragalactic space (violation of Lorentz invariance?), absence of GZK cutoff in the spectrum of ultrahigh-energy cosmic rays (new particle physics?), tremendous energy (up to 1054 erg) released in gamma ray bursts on a time scale of a second (collapsing stars or sources of a new type?). Do these puzzles really exist? A critical review of these phenomena is given. 相似文献
76.
Yu. A. Kumzerov L. S. Parfen’eva I. A. Smirnov H. Misiorek J. Mucha A. Jezowski 《Physics of the Solid State》2003,45(1):57-60
The thermal conductivity of crystalline chrysotile asbestos made up of hollow tubular Mg3Si2O5(OH)4 filaments is measured in the range 5–300 K. The paper discusses the possibility of using this material in studies of the thermal conductivity of thin filaments of metals and semiconductors incorporated into the channels of crystalline chrysotile asbestos tubes. 相似文献
77.
Dominique Fourdrinier William E. Strawderman 《Annals of the Institute of Statistical Mathematics》2003,55(4):803-816
We consider estimation of loss for generalized Bayes or pseudo-Bayes estimators of a multivariate normal mean vector, θ. In
3 and higher dimensions, the MLEX is UMVUE and minimax but is inadmissible. It is dominated by the James-Stein estimator and by many others. Johnstone (1988,
On inadmissibility of some unbiased estimates of loss,Statistical Decision Theory and Related Topics, IV (eds. S. S. Gupta and J. O. Berger), Vol. 1, 361–379, Springer, New York) considered the estimation of loss for the usual
estimatorX and the James-Stein estimator. He found improvements over the Stein unbiased estimator of risk. In this paper, for a generalized
Bayes point estimator of θ, we compare generalized Bayes estimators to unbiased estimators of loss. We find, somewhat surprisingly,
that the unbiased estimator often dominates the corresponding generalized Bayes estimator of loss for priors which give minimax
estimators in the original point estimation problem. In particular, we give a class of priors for which the generalized Bayes
estimator of θ is admissible and minimax but for which the unbiased estimator of loss dominates the generalized Bayes estimator
of loss. We also give a general inadmissibility result for a generalized Bayes estimator of loss.
Research supported by NSF Grant DMS-97-04524. 相似文献
78.
I. A. Vasilieva 《Journal of Experimental and Theoretical Physics》2003,97(3):539-553
The stationary condition is derived taking into account the polarization of radiation in the general case of a scattering inhomogeneous medium in an arbitrary-shape emitter. The necessary stationary condition for an emitter in which radiation is emitted and extinguished simultaneously is complete extinction of the entire emitted radiation. Radiation extinction as a result of absorption by the medium and the emergence of radiation from the emitter is analyzed. The stationary condition is an analytical form of writing that extinction of radiation is a sure event whose probability is equal to unity. The passage of radiation through the medium is described on the basis of the linear transport theory with the help of the matrices of the Green functions. The stationary condition includes the characteristics of polarized radiation extinction of which is analyzed, the absorption coefficients of the medium, and the elements of the matrices of the Green functions, which are determined by optical and geometrical parameters of the emitter. The stationary condition obtained is used for deriving the relations between the components of scalar intensity observed in an arbitrary region of the emitter. These relations include, in addition to the absorption coefficients and the matrix elements of the Green functions, the powers of the primary radiation. Possible applications of the stationary condition and the relations between intensity components in computations and experimental studies are considered. 相似文献
79.
A. A. Nazarov 《Physics of the Solid State》2003,45(6):1166-1169
A solution to the equation of grain-boundary diffusion is obtained under conditions where migration of the diffusant from the boundaries into the grains is absent and the diffusion coefficient decreases with time from an increased value to a value characteristic of equilibrium grain boundaries. The specific features of the grain-boundary diffusion in nanocrystals are qualitatively analyzed in terms of this solution. 相似文献
80.