Spectroelectrochemistry of Poly(3,4-Ethylenedioxythiophene)–Tungsten Oxide Composite Films in Dilute Sulfuric Acid Solution

Russian Journal of General Chemistry - Using electrochemical deposition of tungsten oxide from a metastable acidic solution of isopolytungstates into a poly(3,4-ethylenedioxithiophene) film,...     

Effects of Dry-Jet Wet Spinning Parameters on Properties of Polysulfone Hollow Fiber Membranes

Russian Journal of Applied Chemistry - The influence of parameters of the dry-jet wet spinning process was studied on properties of porous polysulfone hollow fiber membranes. The air gap distance,...     

Synthesis and Crystal Structure of Fluoride K2(Ta0.9I0.1)F7 with the Micro-Isomorphic Substitution in the Ta Cationic Position

Crystallography Reports - Fluoride crystals K2(Ta0.9I0.1)F7 (sp. gr. Р21/c) complementary to the K2TaF7 and K2NbF7 fluoride family have been obtained by hydrothermal synthesis. Their...     

Nanocomposites Based on Poly(Amide-Imide) Matrix with Na–Mg Triple Chain Hydrosilicate

Crystallography Reports - A new polymer-inorganic nanocomposite composed of fibrous Na–Mg triple chain hydrosilicate with a poly(amide-imide) matrix was developed. Its structure, morphology,...     

Measurement of Cross Sections for Inclusive Forward Charged Hadron Production in Carbon–Carbon Collisions at Beam Energy of 19.6 GeV per Nucleon

Physics of Atomic Nuclei - The invariant cross sections for forward charged-hadron production at zero angle in carbon–carbon collisions at a beam kinetic energy of 19.6 GeV per nucleon were...     

Synthesis and Crystal Structure of New Indium Iodate (K<Subscript>0.6</Subscript>Na<Subscript>0.4</Subscript>Ba)In[IO<Subscript>3</Subscript>]<Subscript>6</Subscript>

Crystals of new indium iodate (K_0.6Na_0.4Ba)In[IO₃]₆ were prepared by the hydrothermal synthesis. The unit-cell parameters are a = 11.3984(3) Å, с = 11.3817(3) Å, sp. gr. R3?. The chemical formula of the compound was derived from the structure determination and refinement with anisotropic displacement parameters to R = 0.0284. In the structure the InO₆ octahedra share vertices with six umbrella-like [IO₃]–groups typical of iodates and form isolated 3?-symmetric charged \(\rm{In[IO_{3}]_6^{3-}}\) clusters. Large Ba, K, and Na cations occupy a common site on a threefold axis due to the isomorphous substitution and compensate the charge of the clusters. The new structure extends the family of the recently discovered alkali-metal and barium iodates containing Ti and Zr atoms in octahedral sites. The iodate K₂Ge[IO₃]₆ containing Ge atoms in the centers of octahedra is the parent compound of this structural family.     

Synthesis and properties of isopropylamine borane i-C3H7NH2 · BH3

Isopropylamine borane i-C₃H₇NH₂ · BH₃ was synthesized by the reaction of sodium tetrahydroborate NaBH₄ with isopropylamine hydrochloride in tetrahydrofuran followed by extraction with diethyl ether. Its synthesis conditions were determined and optimized. The compound was characterized by chemical analysis, IR spectroscopy, and differential thermal analysis.     

Influence of the initial parameters of spray water on its motion through a counter flow of high-temperature gases

The motion of spray water through a counter flow of high-temperature gases is experimentally studied on a macroscopic level using optical techniques for diagnostics of two-phase liquid-gas and vapor-liquid flows. It is found that the initial temperature, concentration of typical impurities, and dispersity of water influence the component composition of the forming gas-vapor-droplet mixture. The integral characteristics of evaporation of solitary droplets with initial sizes (conditional characteristic radii) of 3–5 mm and a spray water flow with droplets less than 0.5 mm across through a high-temperature gaseous medium are compared.     

Electromagnetic vibrator: An initiator of air breakdown in the subcritical field of a quasi-optical microwave beam

The subject of investigation is the resonance properties of cylindrical electromagnetic vibrators with different diameters and spherically rounded ends acting as initiators of air breakdown in the subcritical field of a quasi-optical microwave beam. The vibrator is placed both in the field of a traveling electromagnetic wave and at the antinode of the field above a screen inserted in the microwave beam. The shortening of the half-wave vibrator that governs its ability to initiate air breakdown, the field at the top-pole of this vibrator, and a tolerance on its resonance length are found from experimental data.     

Experimental estimation of evaporation rates of water droplets in high-temperature gases

Evaporation rates of water droplets in high-temperature gases were experimentally determined using high-speed video recording cameras and low-inertia thermocouples (for heated air flow as an example). The experiments were carried out for droplets of initial size (radius) 1–3 mm at an air temperature of 500–1000 K. Dependences of the evaporation rate of water droplets on time and gas temperature were obtained for various initial droplet sizes.