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41.
K. H. Neeb G. Karnath H. Richter W. Schweighofer H. Stöckert 《Journal of Radioanalytical and Nuclear Chemistry》1976,32(2):523-531
The working techniques used for the investigation of129I and3H sectional distribution in highly irradiated UO2 pellets are described. The analytical samples are taken by a micro drilling technique. For the determination of129I concentration in the UO2 samples neutron activation analysis following iodine separation from uranium and bulk fission products is used.3H is measured by liquid scintillation counting after distillation. Reliability of the analytical results is discussed as well as possible interferences. 相似文献
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J. Adam Jr. J. Mareš O. Richter M. Sotona S. Frullani 《Czechoslovak Journal of Physics》1992,42(11):1167-1196
Formalism for the electroproduction of strange particles based on the one photon exchange approximation and the Feynman diagrams representation of hadron current is reviewed. Different photoproduction models are compared with available photo and electroproduction data. New experiments are proposed that may resolve existing uncertainties and inconsistencies. The formation of hypernuclei via kaon electroproduction is investigated theoretically and compared with other reactions involving purely hadronic processes. 相似文献
46.
Joachim G. Liehr Gareth A. Brenton John H. Beynon James A. McCloskey Wolfgang Blum Wilhelm J. Richter 《Helvetica chimica acta》1981,64(3):835-843
In isobutane chemical ionization mass spectrometry benzyl alcohol exhibits ions at m/z 147 (‘M + 39’) that arise by a loss of H2O from [M + C4H9]+, i.e. ‘M + 57’ complex ions. Electrophilic aromatic substitution of a proton at an ortho-position of neutral C6H5CH2OH with [t-C4H9]+ and, alternatively, nucleophilic substitution of H2O at the benzylic carbon in \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm C_6 H_5 CH_2}\mathop {\rm O}\limits^+ {\rm H}_2 $\end{document} with CH2?C (CH3)2 are discussed as possible pathways. Evidence in favor of the latter is derived from the analysis of C6D5CH2OH and C6H5CD2OH for the origin of the H-atoms lost in H2O. The inferred ion structure of m/z 147 is verified by mass-analyzed ion kinetic energy (MIKE.) measurements of its collision-activated (CA.) decomposition. MIKE./CA. spectra of mass-selected m/z 147 ions, once generated by (CI(i-C4H10) from benzyl alcohol and, once, from 2-methyl-4-phenyl-2-butanol match closely and, thus, reflect identical ion structures. With reference to the simple genesis of this ion from the latter precursor, the structure in question can be concluded to be \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm C_6 H_5 CH_2 CH_2}\mathop {\rm C}\limits^+ ({\rm CH}_3)_2 $\end{document} . 相似文献
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H. Spieler H. J. K?rner K. E. Rehm M. Richter H. P. Rother 《Zeitschrift für Physik A Hadrons and Nuclei》1976,53(5):241-250
The reactions120Sn+72 MeV18O and122Sn+74 MeV16O were investigated with time of-flightE-E-telescopes. Data are presented for all quasi-elastic reaction channels. The two neutron stripping and pickup reactions (18O,16O), (18O,20O) and (16O,18O) are analyzed in detail. It is shown that these heavy ion induced two neutron transfer reactions proceed with essentially the same type of selectivity as the corresponding light ion induced reactions. The differential cross sections for transfer reactions leaving the120, 122Sn nuclei in their 2+ first excited states are shown to be influenced by interference effects due to additional inelastic excitations. 相似文献
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Alejandro Cañas Samuel Valdebenito Pablo Richter 《Analytical and bioanalytical chemistry》2014,406(8):2205-2210
A novel extraction approach was developed based on rotating-disk sorptive extraction (RDSE). In this approach the rotating-disk extraction device consists of a Teflon disk, with a cavity that is loaded with a commercial sorbent phase selected according to the polarity of the analyte. To avoid leakage of the sorbent, the cavity is covered with a fiberglass filter and sealed with a Teflon ring. The proposed novel analytical RDSE technique was used in this study to determine florfenicol levels in plasma as a model analyte, or sample system, to describe the pharmacokinetics of a veterinary formulation. The sorbent used for this application was the copolymer of divinylbenzene and N-vinylpyrrolidone (Oasis HLB), which was selected because the florfenicol molecule contains both hydrophilic and lipophilic moieties. After the extraction, final determination of the analyte was performed by HPLC–DAD. Calibration plots and other analytical features were obtained after 90 min of extraction. The calibration plot was linear over the interval 0.4–16 μg mL?1 (n?=?6), with R 2?=?0.9999. Recovery and repeatability were determined using a blank plasma sample spiked with 4.8 μg mL?1 florfenicol. A recovery of 91.5 %, with a relative standard deviation (RSD) of 8.8 %, was obtained when the extraction was evaluated using six different rotating-disk devices. Precision was also assessed, using the same disk (containing the same sorbent phase) for eight aliquots of the same sample. The RSD under these conditions was 10.2 %, clearly indicating that the sorptive phase could possibly be re-used. Accordingly, RDSE is a suitable sample preparation alternative to liquid–liquid extraction (LLE), solid-phase extraction (SPE), and stir-bar sorptive extraction (SBSE). 相似文献