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31.
A class of finite simplicial complexes, which we call Buchsbaum* over a field, is introduced. Buchsbaum* complexes generalize triangulations of orientable homology manifolds as well as doubly Cohen-Macaulay complexes. By definition, the Buchsbaum* property depends only on the geometric realization and the field. Characterizations in terms of simplicial homology are given. It is proved that Buchsbaum* complexes are doubly Buchsbaum. Various constructions, among them one which generalizes convex ear decompositions, are shown to yield Buchsbaum* simplicial complexes. Graph theoretic and enumerative properties of Buchsbaum* complexes are investigated. 相似文献
32.
Variability of higher trophic level stable isotope data in space and time – a case study in a marine ecosystem 下载免费PDF全文
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Volkmar Leute 《Journal of Physics and Chemistry of Solids》2010,71(12):1768-1773
The diffusion profiles and the reaction paths in ternary solid solutions are determined by both thermodynamics and kinetics. The matrix of the diffusion coefficient can be described as the product of the Hessian matrix for the thermodynamic influences and the Onsager matrix for kinetic influences.In this paper the interest is focused on the influence of the ideal part of the Hessian matrix, i.e. the ideal mixing entropy on interdiffusion. The ideal diffusion profiles are calculated by a computer simulation and they are compared with experimental results from the literature. These comparisons reveal that in most cases the qualitative shape of the diffusion profiles and of the reaction paths can be considered as caused by the ideal mixing entropy. Surprisingly, the shape of the diffusion profiles turns out to depend on the component that was chosen as the so-called solvent of the ternary mixture. This means that the ideal reaction paths do not show the triangular symmetry expected for an ideal ternary system. Especially, reaction paths between starting positions showing the same concentration of one of the three components do not run along straight lines. 相似文献
34.
Hans Matter Dr. Marc Nazaré Dr. Stefan Güssregen Dr. David W. Will Dr. Herman Schreuder Dr. Armin Bauer Dr. Matthias Urmann Dr. Kurt Ritter Dr. Michael Wagner Dr. Volkmar Wehner Dr. 《Angewandte Chemie (International ed. in English)》2009,48(16):2911-2916
Attractive chlorine : Noncovalent interactions between chlorine or bromine atoms and aromatic rings in proteins open up a new method for the manipulation of molecular recognition. Substitution at distinct positions of two factor Xa inhibitors improves the free energy of binding by interaction with a tyrosine unit. The generality of this motif was underscored by multiple crystal structures as well as high‐level quantum chemical calculations (see picture).
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Volkmar Vill Hanns-Walter Tunger Horst Stegemeyer Karsten Diekmann 《Tetrahedron: Asymmetry》1994,5(12):2443-2446
A four-step synthesis starting from tri-O-acetyl-D-glucal leads to chiral trioxadecalin compounds containing a cyano group. The mesogenic properties of a homologous series of liquid crystals are reported; for two derivatives a helix inversion of the cholesteric phase is observed. 相似文献
37.
Volkmar Liebscher Michael Skeide 《Proceedings of the American Mathematical Society》2008,136(3):989-997
We prove a criterion that allows us to construct units in product systems of correspondences with prescribed infinitesimal characterizations. This criterion summarizes proofs of known results and new applications. It also frees the hypotheses from the assumption that the units are contained in a product system of time ordered Fock modules.
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Three twin types of troponoid liquid crystals, in which the directions of the tropone carbonyl groups are different from each other, were prepared to establish their thermal properties. Symmetrical type I dimers, in which the two tropone carbonyl groups are directed inwards, had monotropic smectic C phases, whereas two other symmetrical type IIa and IIb dimers, whose troponoid dipoles are directed outwards, were not mesomorphic except for one type IIa compound having two long terminal chains and a short alkylene spacer. Unsymmetrical type III dimers had smectic A phases. Among the dimers, unsymmetrical type III dimers had the highest clearing point when the number of atoms of the inner and outer spacers was fixed. X-ray diffraction studies of a type III dimer, in which the number of the atoms of the inner spacer was odd, showed that the molecules form an interdigitated layer structure. The binary system between type I and type IIb dimers showed an induced enantiotropic smectic A phase, in which the dipole moments of the tropone rings were cancelled. 相似文献
40.
Milkereit G Garamus VM Veermans K Willumeit R Vill V 《Journal of colloid and interface science》2005,284(2):704-713
Three new alkyl glycosides with similar molecular structures (oleyl and oleoyl alkyl chains and various head groups: disaccharide, trisaccharide and disaccharide with an additional amidoethoxy spacer) were synthesized and their supramolecular structure in aqueous solution was investigated. Small angle neutron scattering, surface tension measurement and the contact preparation method were applied to get molecular structure-property relationships. Although the chemical structures differ only in small details, their CMC values, lyotropic phase behaviour, surface area per surfactant molecule in the micelle and at the liquid-air interface, and the size and shape of the micelles are very different. We have found three different types of aggregates: spherical, cylindrical and polymer-like micelles in dilute solutions. 相似文献