Photoluminescence of supernatant liquid of washed erythrocytes upon ultraviolet excitation

In this paper, we present the results of the study of supernatant liquid of washed erythrocytes by the photoluminescence upon ultraviolet excitation. The spectra of intrinsic photoluminescence of an aqueous solution of “Sodium adenosine triphosphate-Vial” (Na₂ATP) were compared with the spectra of supernatant liquid of erythrocytes with added Na₂ATP, glucose, and without additional substances. The results of the comparison suggest that ATP emerging from washed erythrocytes into environment can be recorded in supernatant liquid.     

Transfer of energy from an evaporating drop in a vapor medium

The article considers the temperature distribution around an evaporating drop in a vapor medium. The transfer of energy is effected by molecular thermal conductivity, convection, and radiation. The mean length of the free flight path of the radiation considerably exceeds the characteristic distance at which the temperature changes. The times required for relaxation of the temperature to a steady-state value are determined, as well as the characteristic distances at which the temperature distribution changes.Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 1, pp. 74–78, January–February, 1972.The authors thank V. G. Levich for his evaluation of the results obtained.     

Motion and filling of cavities in a boundless liquid and close to a plane

The motion of bubbles in liquids has been studied in many earlier papers [1–8]. In this paper methods of the projection type are applied to the problem of a cavity in an ideal, incompressible liquid in the absence of vortices. The collapse of a bubble having a finite initial velocity in a boundless liquid is considered; also considered is the collapse of a stationary bubble close to a solid wall. Using the small-parameter method the generation of a jet is examined analytically. A numerical computing method not involving small parameters is developed; it is based on calculating the projection by numerical computation of the corresponding integrals. The method combines economy and simplicity of application with a high accuracy in the region in which the representation of the velocity potential by a series of spherical functions remains effective.     

Motion of a variable-volume sphere in an ideal fluid near a plane surface

The motion of a spherical cavity in a fluid is investigated. The radius of the sphere varies under the action of a constant pressure at infinity. The problems of the collapse of a cavity moving in an unbounded fluid and of the collapse of a cavity near a plane are solved in the exact formulation. The occurrence of an initial translational velocity or the presence of a solid surface, by contrast with the collapse of a sphere at rest in an unbounded fluid [1], yields a limiting radius at which the process of collapse ceases. A sphere initially at rest near a plane always comes into contact with the plane as a result of collapse. The radius and velocities at which the sphere arrives the plane are calculated for various initial distances from the latter. The possible mechanism of the action of a cavitation bubble on a solid surface is discussed.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 5, pp. 94–103, September–October, 1971.     

Electron Capture,Collision-Induced,and Electron Capture-Collision Induced Dissociation in Q-TOF

Recently, we demonstrated that a radio-frequency-free electromagnetostatic (rf-free EMS) cell could be retrofitted into a triple quad mass spectrometer to allow electron-capture dissociation (ECD) without the aid of cooling gas or phase-specific electron injection into the cell (Voinov et al., Rapid Commun Mass Spectrom 22, 3087–3088, 2008; Voinov et al., Anal Chem 81, 1238–1243, 2009). Subsequently, we used our rf-free EMS cell in the same instrument platform to demonstrate ECD occurring in the same space and at the same time with collision-induced dissociation (CID) to produce golden pairs and even triplets from peptides (Voinov et al., Rapid Commun Mass Spectrom 23, 3028–3030, 2009). In this report, we demonstrate that ECD and CID product-ion mass spectra can be recorded at high resolution with flexible control of fragmentation processes using a newly designed cell installed in a hybrid Q-TOF tandem mass spectrometer.