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861.
The one-pot cyclocondensation of 2,6-diaminopyrimidin-4-one, an aromatic or aliphatic aldehyde and a beta-ketoester in acetic acid, or dimethyl sulfoxide in the presence of zinc(II) bromide, under thermal conditions provided dihydropyrido[2,3-d]pyrimidin-4(3H)-ones in good yield and with total regiocontrol. 相似文献
862.
863.
FT-IR and Raman spectroscopic study of hydrated rubidium (cesium) borates and alkali double borates 总被引:1,自引:0,他引:1
Zhu Lixia Yue Tao Wang Jiang Gao Shiyang 《Russian Journal of Inorganic Chemistry》2007,52(11):1786-1792
FT-IR and Raman spectra of five hydrated alkali borates and five hydrated alkali double borates have been recorded at room
temperature in the range 400 to 4000 cm−1, and analyzed. Fundamental vibrational modes have been identified and assignments tentatively made in comparison with the
work of Janda and Heller, and Li Jun.
The text was submitted by the authors in English. 相似文献
864.
Polymer electrolyte systems were prepared for the first time by dissolution of amidomagnesium chlorides in poly(ethylene oxide),
(PEO). For the preparation, solutions of (hexamethyldisilylamido)magnesium chloride, (dimethylpyrrolyl)magnesium chloride,
(diisopropylamido)magnesium chloride, piperidinomagnesium chloride and morpholinomagnesium chloride were chosen. The composition
of these polymer electrolyte systems corresponds to the general formula R2NMgCl·P(EO)n·THF. Most work has been done with the system (hexamethyldisilylamido)magnesium chloride in PEO, (Me3Si)2NMgCl·P(EO)n·THF, with n= 3, 4, 5, or 7. The electrolytes have a soft rubber-like consistency. At 30 °C, electrical conductivities of 10−6–10−5 S/cm were found. The conductivities were measured in the temperature range 20–60 °C. Within this temperature range a linear
dependence of the logarithms of the conductivity on the inverse temperature was found and activation energies for the conducting
process of 30–60 kJ/mol were calculated. Using those polymer electrolytes with a high content of the amidomagnesium compound,
a reversible magnesium deposition takes place by cathodic reduction at potentials below −1.9 V vs. a Ag/AgCl reference electrode.
These polymer electrolytes were found to be stable against oxidation up to about −0.3 V vs. Ag/AgCl.
Electronic Publication 相似文献
865.
The micellization behavior of an anionic gemini surfactant, GA with nonionic surfactants C12E8 and C12E5 in presence of 0.1 M NaCl at 298 K temperature, has been studied tensiometrically in pure and mixed states, and the related
physicochemical parameters (cmc, γ
cmc, pC
20, Γ
max, and A
min) have been evaluated. Tensiometric profile (γ vs log [surfactant]), for conventional surfactants, generally consists of a single point of intersection; a gradually decreasing
line (normally linear, or with slight curvature) ultimately saturates in γ at a particular [surfactant], corresponding to complete monolayer saturation. The gemini, in this report, led to two unequivocal
breaks in the tensiometric isotherm. An attempt to the interpretation of the two breaks from molecular point of view is provided,
depending solely on the chemical structure of the surfactant. The gemini, even in mixed state with the conventional nonionic
surfactants C12E5 and C12E8, manifested the dual breaks; of course, the dominance of the feature decreases with increasing mole fraction of the nonionics
in the mixture. Theories of Clint, Rosen, Rubingh, Motomura, Georgiev, Maeda, and Nagarajan have been used to determine the
interaction between surfactants at the interface and micellar state of aggregation, the composition of the aggregates, the
theoretical cmc in pure and mixed states, and the structural parameters according to Tanford and Israelachvili. Several thermodynamic
parameters have also been predicted from those theories. 相似文献
866.
Takayuki Abe Shingo Higashide Mitsuhiro Inoue Satoshi Akamaru 《Plasma Chemistry and Plasma Processing》2007,27(6):799-811
Fine particles were modified with a thin film of SnO2 by using a barrel sputtering system that is a dry process. The conditions for the preparation of SnO2 were studied by reactive sputtering onto a glass plate substrate. The optimal conditions for the preparation of tetragonal
SnO2 were identified as 60% partial oxygen pressure and 1.0 Pa total gas pressure with the substrate at room temperature. Under
the optimized conditions, the surfaces of Al flake particles were modified with a thin film of SnO2. XRD and SEM/EDS analysis of the prepared samples showed that the Al particle surfaces were uniformly modified by a thin
film of SnO2 in all cases. The film thicknesses were 80, 130, and 180 nm at RF outputs of 195, 350, and 490 W. These measured thicknesses
coincided with the values estimated from the interference colors of the samples. 相似文献
867.
Mesoporous material as catalyst for the production of fine chemical: Synthesis of dimethyl phthalate assisted by hydrophobic nature MCM-41 总被引:1,自引:0,他引:1
Seshachalam Udayakumar Arumugam Pandurangan Predeep Kumar Sinha 《Journal of molecular catalysis. A, Chemical》2005,240(1-2):139-154
Aluminum, iron and zinc containing MCM-41 molecular sieves were prepared by the hydrothermal method. The catalyst was characterized by the XRD, BET (surface area), FT–IR and 29Si, 27Al MAS–NMR techniques. The catalytic activity of these molecular sieves was tested with esterification reaction used with phthalic anhydride (PAH) and methanol (MeOH) in the autoclave at 135 °C, 150 °C and 175 °C. Conversion increases with an increase in temperature and mole ratio. The activity of these catalysts followed the order: Al-MCM-41 (112) > Fe-MCM-41 (115) > Al-MCM-41 (70) > Al-MCM-41 (52) > Fe-MCM-41 (61) > Al, Zn-MCM-41 (104) > Al-MCM-41 (30). The reaction yielded both monomethyl phthalate (MMP) and dimethyl phthalate (DMP). The nature of the catalyst sites has been proposed using with water as an impurity. The selectivity of the dimethyl phthalate increases with increase in temperature and mole ratio. The weight of the catalyst was optimized at 0.07 g. The hydrophilic and hydrophobic nature of the catalyst has been explained by the influence of water and the external surface acidity also facilitates the reaction and this has been confirmed by the supporting reaction. 相似文献
868.
Om Prakash Ajay Kumar Richa Prakash Rosa M. Claramunt Ibon Alkorta José Elguero 《Tetrahedron》2005,61(27):6642-6651
Treatment of α,β-unsaturated carbonyl compounds, obtained by the reaction of DHA and aromatic (or heteroaromatic) aldehydes, with o-aminothiophenol results in the formation of 1,5-benzothiazepines and/or 1,4-benzothiazines depending upon the reaction conditions and structure of the aldehydes. The products were characterized by the combined use of multinuclear 1D and 2D NMR and GIAO/DFT calculations of 1H, 13C and 15N chemical shifts. The tautomerism of these compounds in solution was determined, they have an exocyclic CC double bond. 相似文献
869.
G. Ziegler S. V. K. Kumar P. Dittmann K. Bergmann 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1988,10(2-3):247-252
Differential cross sections for state-to-state rotationally inelastic electron-Na2 scattering, with the molecule being in the vibrational levelv′'=31, are measured at a collision energy of 150 eV. Angular momentum transfer of up to Δj=26 is observed, which is even more than previously obtained for the vibrational ground statev′'=0. Good agreement is found with theoretical results from a spectator scattering model. This work, in general, elucidates the role of vibrational excitation in collision dynamics under vibrationally sudden conditions. 相似文献
870.
A solid membrane electrode made with titanium arsenate as membrane material and "Araldite" as binder has been used to measure the activity of lead in the concentration range from 0.1 M to 5 x 10(-6)M. The electrode is unaffected by many cations, nitrate and acetate. The response time is 40-60 sec over the whole concentration range (in a static system) and the electrode has a working life of at least four months. The electrode can work in the pH range 2-5 and is tolerant of ethanol up to a content of 30% v v . It has been successfully used for end-point indication in potentiometric titration of lead. A membrane treated with cationic surfactant exhibits better selectivity. 相似文献