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101.
Ville Anton Vuorinen Harri Hillamo Ossi Kaario Mika Nuutinen Martti Larmi Laszlo Fuchs 《Flow, Turbulence and Combustion》2011,86(3-4):533-561
The paper is mainly focused to the vast number of researchers who work within direct injection (DI) engine fuel spray simulations. The most common simulation framework today within the community is the Reynolds Averaged Navier Stokes (RANS) approach together with the Lagrangian Particle Tracking (LPT) method. In fact, this study is one of the first studies where high resolution LES/LPT diesel spray modeling is considered. The potential of LES to deepen the present day multidimensional LPT fuel spray simulations is discussed. Spray evolution is studied far from an injector by modeling a spray as a particle laden jet (PLJ). The effect of d on mixing in non-atomizing and atomizing sprays is thoroughly investigated at jet inlet Reynolds number Re?=?104 and Mach number Ma?=?0.3. Based on and justified by rather recent and also quite old ideas, novel and compact views on droplet breakup in turbulent flows are pointed out from the literature. We use LES/LPT to illustrate that even in a low Weber number flow (We?<?13) the droplet breakup modeling may need considerable attention in contrast to what is typically assumed in the present-day breakup models. LES and LPT techniques are first applied to essentially confirm certain expected droplet size effects on spray shape in non-atomizing monodisperse sprays. In the simulations LES e.g. produces an expected turbulent dispersion pattern that depends on droplet diameter (d) without a droplet dispersion model in contrast to RANS. A new compact droplet breakup model is formulated and tested for droplets that break with a natural resonance time rate according to the Poisson process. As a result of the study: 1) the analysis gives a rigorous and enriching proof of currently existing views on droplet size effects on mixing, and 2) the presented a priori analysis points out the importance of modeling the resonance breakup even at a low We. 相似文献
102.
Ville Hakulinen 《Communications in Mathematical Physics》2003,235(1):1-45
We prove estimates for the stationary state n-point functions at zero molecular diffusivity in the Kraichnan model [13]. This is done by proving upper bounds for the heat
kernels and Green's functions of the degenerate elliptic operators M
n
that occur in the Hopf equations for the n-point functions.
Received: 25 August 2001 / Accepted: 30 September 2002 Published online: 20 January 2003
Communicated by A. Kupiainen 相似文献
103.
104.
Kramers-Kronig analysis on the real refractive index of porous media in the terahertz spectral range
We present a terahertz time-domain experimental technique for the detection of scattering from porous media. The method for detection of the scattering enables one to make a decision when Fresnel or Kramers-Kronig (K-K) analysis can be applied for a porous medium. In this study the real refractive index of a tablet is calculated using the conventional K-K dispersion relation and also using a singly subtractive K-K relation, which are applied to the extinction coefficient obtained from the Beer-Lambert law. The advantage of the K-K analysis is that one gets estimates both for absolute refractive index and also dispersion of the porous tablet, whereas Fresnel analysis provides only the absolute value of the index. 相似文献
105.
James R. Wootton Ville Lahtinen Benoit Doucot Jiannis K. Pachos 《Annals of Physics》2011,(9):2307-2314
In three spatial dimensions, particles are limited to either bosonic or fermionic statistics. Two-dimensional systems, on the other hand, can support anyonic quasiparticles exhibiting richer statistical behaviors. An exciting proposal for quantum computation is to employ anyonic statistics to manipulate information. Since such statistical evolutions depend only on topological characteristics, the resulting computation is intrinsically resilient to errors. The so-called non-Abelian anyons are most promising for quantum computation, but their physical realization may prove to be complex. Abelian anyons, however, are easier to understand theoretically and realize experimentally. Here we show that complex topological memories inspired by non-Abelian anyons can be engineered in Abelian models. We explicitly demonstrate the control procedures for the encoding and manipulation of quantum information in specific lattice models that can be implemented in the laboratory. This bridges the gap between requirements for anyonic quantum computation and the potential of state-of-the-art technology. 相似文献
106.
A novel digital in-line holographic imaging instrument designed for acquiring properties of individual hydrometeors in situ is presented. The instrument has a large measurement volume of 670 cm3. This combined with fast frame rate imaging and software controlled multi-exposure capabilities results in a representative sampling of rain and snowfall events. Hydrometeors are measured and analyzed from the in-focus images with microscopic resolution, and their 3D locations inside the measurement volume are determined. The instrument is designed to operate in cold climates and to produce reliable measurements also during strong winds. The imaging rate of the instrument was designed to be adequately high to observe the dynamic nature of rain and snow falls. By recording multi-exposure holograms, the effective frame rate can be increased. This allows the measurements of the velocities of the fast-falling hydrometeors. The instrument and the hologram processing are described; as well as results from laboratory tests and the first field measurements are shown. As a result, the resolving power of the instrument was measured to vary between 11 and 18 microns inside the measurement volume near the center of the field-of-view. Velocity vectors were measured both from multi-exposure and high frame rate holograms. The measured velocities ranged from 0.1 to 4 m/s. In addition, the projections of a flat-shaped and rotating snowflake imaged at different locations inside the measurement volume demonstrated the possibility to estimate the shape of the hydrometeor from multiple viewing angles. 相似文献
107.
Ultrafast Two‐Dimensional NMR Relaxometry for Investigating Molecular Processes in Real Time
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Nuclear spin–lattice (T1) and spin–spin (T2) relaxation times provide versatile information about the dynamics and structure of substances, such as proteins, polymers, porous media, and so forth. Multidimensional experiments increase the information content and resolution of NMR relaxometry, but they also multiply the measurement time. To overcome this issue, we present an efficient strategy for a single‐scan measurement of a 2D T1–T2 correlation map. The method shortens the experimental time by one to three orders of magnitude as compared to the conventional method, offering an unprecedented opportunity to study molecular processes in real‐time. We demonstrate that, despite the tremendous speed‐up, the T1–T2 correlation maps determined by the single‐scan method are in good agreement with the maps measured by the conventional method. The concept of the single‐scan T1–T2 correlation experiment is applicable to a broad range of other multidimensional relaxation and diffusion experiments. 相似文献
108.
Jared N. King Vanessa J. Lee Dr. Susanna Ahola Dr. Ville‐Veikko Telkki Prof. Dr. Tyler Meldrum 《Angewandte Chemie (International ed. in English)》2016,55(16):5040-5043
Laplace NMR (LNMR) consists of relaxation and diffusion measurements providing detailed information about molecular motion and interaction. Here we demonstrate that ultrafast single‐ and multidimensional LNMR experiments, based on spatial encoding, are viable with low‐field, single‐sided magnets with an inhomogeneous magnetic field. This approach shortens the experiment time by one to two orders of magnitude relative to traditional experiments, and increases the sensitivity per unit time by a factor of three. The reduction of time required to collect multidimensional data opens significant prospects for mobile chemical analysis using NMR. Particularly tantalizing is future use of hyperpolarization to increase sensitivity by orders of magnitude, allowed by single‐scan approach. 相似文献
109.
Ville Aumala Filip Mollerup Dr. Edita Jurak Fabian Blume Dr. Johanna Karppi Antti E. Koistinen Eva Schuiten Moritz Voß Prof. Uwe Bornscheuer Prof. Jan Deska Prof. Emma R. Master 《ChemSusChem》2019,12(4):848-857
Plant-derived carbohydrates are an abundant renewable resource. Transformation of carbohydrates into new products, including amine-functionalized building blocks for biomaterials applications, can lower reliance on fossil resources. Herein, biocatalytic production routes to amino carbohydrates, including oligosaccharides, are demonstrated. In each case, two-step biocatalysis was performed to functionalize d -galactose-containing carbohydrates by employing the galactose oxidase from Fusarium graminearum or a pyranose dehydrogenase from Agaricus bisporus followed by the ω-transaminase from Chromobacterium violaceum (Cvi-ω-TA). Formation of 6-amino-6-deoxy-d -galactose, 2-amino-2-deoxy-d -galactose, and 2-amino-2-deoxy-6-aldo-d -galactose was confirmed by mass spectrometry. The activity of Cvi-ω-TA was highest towards 6-aldo-d -galactose, for which the highest yield of 6-amino-6-deoxy-d -galactose (67 %) was achieved in reactions permitting simultaneous oxidation of d -galactose and transamination of the resulting 6-aldo-d -galactose. 相似文献
110.
Dr. Pravin Kumar Ankush Jagtap Dr. Sam Asami Claudia Sippel Prof. Dr. Ville R. I. Kaila Prof. Dr. Felix Hausch Prof. Dr. Michael Sattler 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(28):9529-9533
The recently discovered SAFit class of inhibitors against the Hsp90 co‐chaperone FKBP51 show greater than 10 000‐fold selectivity over its closely related paralogue FKBP52. However, the mechanism underlying this selectivity remained unknown. By combining NMR spectroscopy, biophysical and computational methods with mutational analysis, we show that the SAFit molecules bind to a transient pocket in FKBP51. This represents a weakly populated conformation resembling the inhibitor‐bound state of FKBP51, suggesting conformational selection rather than induced fit as the major binding mechanism. The inhibitor‐bound conformation of FKBP51 is stabilized by an allosteric network of residues located away from the inhibitor‐binding site. These residues stabilize the Phe67 side chain in a dynamic outward conformation and are distinct in FKBP52, thus rationalizing the basis for the selectivity of SAFit inhibitors. Our results represent a paradigm for the selective inhibition of transient binding pockets. 相似文献