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131.
The mechanism of directed substrate-parallel motion of molecules caused by photoinduced potential energy fluctuations is investigated. Unlike simplistic models (e.g., an on-off ratchet), the approach suggested implies that the necessary asymmetry of the potential energy can arise not only from the asymmetry of the substrate potential but also from an asymmetric distribution of the fluctuating charge density in the molecule. The thus induced asymmetry of the potential energy governs the direction motion and enables, under certain conditions, its reversal at some frequencies of resonant laser pulses or temperature. These inferences are exemplified by the model charge distributions in the molecule and substrate, and the charge density fluctuations which are obtained by quantum chemical calculations for the realistic molecule of a substituted phenylpyrene compound on a model substrate. 相似文献
132.
A resin-bound nitroso compound sequestered a single unexpected component from crude plant seed extracts. Several plants, including Piper nigrum, Eugenia caryophyllata, and Pimenta dioica, were extracted with organic solvent in the presence of a nitroso-containing resin. The nitroso resin selectively sequestered a single compound, β-caryophyllene, via a chemo- and regioselective ene reaction. The ene product was released from the resin, and proper selection of the solid-phase linker and cleavage cocktail allowed concomitant further transformation of the primary ene product to a novel functionalized polycycle. Preliminary studies indicate that the new hydroxylamine-containing natural product derivatives have antibiotic activity. 相似文献
133.
134.
Methodology and Computing in Applied Probability - 相似文献
135.
Alexandr Zalessky Yuriy Fedotov Elizaveta Yashkina Viktor Nadtochenko Andreyan N. Osipov 《Molecules (Basel, Switzerland)》2021,26(13)
To assess the prospects for using intense femtosecond laser radiation in biomedicine, it is necessary to understand the mechanisms of its action on biological macromolecules, especially on the informational macromolecule—DNA. The aim of this work was to study the immunocytochemical localization of DNA repair protein foci (XRCC1 and γH2AX) induced by tightly focused femtosecond laser radiation in human cancer A549 cells. The results showed that no XRCC1 or γH2AX foci tracks were observed 30 min after cell irradiation with femtosecond pulses of 1011 W∙cm−2 peak power density. An increase in the pulse power density to 2 × 1011 W∙cm−2 led to the formation of linear tracks consisting both of XRCC1 and γH2AX protein foci localized in the places where the laser beam passed through the cell nuclei. A further increase in the pulse power density to 4 × 1011 W∙cm−2 led to the appearance of nuclei with total immunocytochemical staining for XRCC1 and γH2AX on the path of the laser beam. Thus, femtosecond laser radiation can be considered as a tool for local ionization of biological material, and this ionization will lead to similar effects obtained using ionizing radiation. 相似文献
136.
Melanie Kaliwoda Rupert Hochleitner Viktor H. Hoffmann Takashi Mikouchi Alexander M. Gigler Wolfgang W. Schmahl 《光谱学快报》2013,46(2):141-146
The archaeological site of Pintia (Padilla de Duero/Peñafiel, Valladolid), considered one of the first cities on the Iberian Peninsula, has yielded very interesting archaeological records regarding the different functional areas that involve the oppidum. Pottery, metal, and bone/skeletal remains are very well preserved, being optimal for analysis and study of the ancient food contained, such as milk-based products, animal fats, beer, and wine. The combination of Raman Microscopy (RM) with other analytical techniques such as Light Microscopy (LM) and Environmental Scanning Electron Microscopy equipped with Energy Dispersive X-ray Spectroscopy (ESEM-EDX) becomes a powerful tool to obtain information on the possible content in the ceramic receptacles from historical-archaeological heritage. It can lead to an interpretation of their specific use or functionality. In this work, a unique sample preparation was used for all techniques, which lead to a very simple procedure and documentation. The degradation and aging of natural fibers and the presence of organic matter with low crystallinity and calcium oxalate–related residuals can be studied by these combined techniques. The archaeological residuals can be separated from modern contamination coming from agriculture processes, surrounding land minerals, or fresh vegetal matter. 相似文献
137.
Viktor Abramov 《Advances in Applied Clifford Algebras》2007,17(4):577-588
We construct a q-analog of exterior calculus with a differential d satisfying d
N
= 0, where N ≥ 2 and q is a primitive Nth root of unity, on a noncommutative space and introduce a notion of a q-differential k-form. A noncommutative space we consider is a reduced quantum plane. Our construction of a q-analog of exterior calculus is based on a generalized Clifford algebra with four generators and on a graded q-differential algebra. We study the structure of the algebra of q-differential forms on a reduced quantum plane and show that the first order calculus induced by the differential d is a coordinate calculus. The explicit formulae for partial derivatives of this first order calculus are found. 相似文献
138.
139.
It is proved that for a Riemannian manifold M with nonpositive sectional curvature and finite volume the space of directions at each point in which geodesic rays avoid
a sufficiently small neighborhood of a fixed rank 1 vector v∈UM looks very much like a generalized Sierpinski carpet. We also show for nonpositively curved manifolds M with dim M≥ 3 the existence of proper closed flow invariant subsets of the unit tangent bundle UM whose footpoint projection is the whole of M.
Received: 6 July 2000 / Revised version: 11 October 2001 相似文献
140.