Study of solid-state polymerization by positron lifetime measurements

The positron lifetime measurement technique was applied to analyze the structural changes occurring in solid-state polymerization of acrylamide and trioxane. Positronium (Ps) parameters, τ₂ and I₂, which show a marked change as a function of the γ-ray irradiation dose, signaled the presence of three clearly defined stages in the polymerization process: initiation, propagation, and saturation. The initial increase in τ₂, may very well be the result of efficient trapping of Ps in vacancies created around the polymer nuclei. The complicated behavior of I₂ may be explained as a chemical reaction between Ps precursors and the radiolysis products of this polymerization process.     

Synthesis of a new catechin-pyrylium derived pigment

A new catechin-pyrylium derived pigment compound was synthesised from the reaction of catechin with sinapaldehyde in acidic conditions and its structure has been characterised by UV-vis, MS and NMR spectroscopy. Similar compounds could be expected to be formed in wines and contribute to changes in colour and astringency during ageing.     

High-resolution synchrotron radiation core-level spectroscopy of semiconductor surfaces

Thanks to recent technical developments (optics and detection systems), at several synchrotron radiation facilities in the world, it is possible to perform photoemission spectroscopy studies with very high resolution. In the present report, we will review the new insights gained from high-resolution core-level spectroscopy on the structural and electronic properties of different semiconductor surfaces, such as InAs(110), Si and Ge (100) and (111), as well as clean and adsorbate covered Si and Ge(111) surfaces.     

The reduction of oxygen on titanium oxide electrodes

The cathodic reduction of oxygen in 1 mol dm⁻³ sodium hydroxide solutions has been investigated at several types of titanium oxide cathodes. Layers of TiO₂ were prepared on titanium by spraying and thermal decomposition of solutions of titanium n-butoxide in 2-propanol and titanium tetrachloride in methanol+water and also by anodization; the reduction was also studied at Ebonex®, a conducting ceramic consisting mainly of Ti₅O₉. In all cases, the reduction of oxygen occurs largely by a 4e⁻ reaction to water and the reaction occurs at potentials close to −1.0 V vs. SCE. Cyclic voltammetry in the absence of oxygen shows that, at these potentials, the surfaces undergo reduction and the electrochemistry of the Fe(CN)₆⁴⁻ /Fe(CN)₆³⁻ couple has been used to probe further the properties of the TiO₂ surfaces.     

Axiomatizations of Euclidean geometry in terms of points,equilateral triangles or squares, and incidence

Dimension-free Euclidean geometry over Euclidean ordered fields can be axiomatized in a two-sortedfirst-order language, with points and regular n-gons (with n = 3 or 4) as variables, and with a binary predicate standing for the incidence of a point and a regular n-gon as the only primitive notions.     

Inspheres and inner products

Among normed linear spacesX of dimension ≧3, finite-dimensional Hilbert spaces are characterized by the condition that for each convex bodyC inX and each ballB of maximum radius contained inC,B’s center is a convex combination of points ofB ∩ (boundary ofC). Among reflexive Banach spaces of dimension ≧3, general Hilbert spaces are characterized by a related but weaker condition on inscribed balls. Research of the first author was partially supported by the U.S. National Science Foundation. Research of the second and third authors was supported by the Consiglio Nazionale delle Ricerche and the Ministero della Pubblica Istruzione of Italy, while they were visiting the University of Washington, Seattle, USA.     

Reduction of copper (II) chloride by molybdenum and rhenium biscyclopentadienyl hydrides. Investigation of the crystal and molecular structure of [(η5-C5H5)2Re]+[CuCl2]−

The reduction of copper (II) chloride by molybdenum and rhenium biscyclopentadienyl hydrides upon their interaction in donor-type solvents has been studied by NMR, X-ray diffraction, and magnetic methods. It is established that the ionic complex [(η⁵-C₅H₅)₂Re]⁺[CuCl₂]^? forms ortho rhombic crystals with a - 13.696(2) Å, b = 7.317(1) Å, c = 5.969(1) Å, space group Pm2₁n, Z = 2. The cyclopentadienyl rings make a bent-sandwich with an angle between the ring centres and Re atom of 150.1°; the ClCuCl angle being 174.8° and the ReCu minimum distance 4.346(29) Å. The solution of [(η⁵-C⁵H₅)²Re]⁺ [CuCl₂]^? seems to activate the CH bond of the C₅H₅ rings, which results in the addition of the [(C₅H₅)(C₅H₄)ReH]⁺ hydride ion.     

Zum Studium der alkoholischen G?hrung

Ohne Zusammenfassung     

Operator synthesis. I. Synthetic sets, bilattices and tensor algebras

The interplay between the invariant subspace theory and spectral synthesis for locally compact abelian group discovered by Arveson (Ann. of Math. (2) 100 (1974) 433) is extended to include other topics as harmonic analysis for Varopoulos algebras and approximation by projection-valued measures. We propose a “coordinate” approach which nevertheless does not use the technique of pseudo-integral operators, as well as a coordinate free one which allows to extend to non-separable spaces some important results and constructions of Arveson. We solve some problems posed in Arveson (1974).