New version of the integrated method for measuring small effects in experiments on beams extracted from a nuclear reactor at the effect sign switching frequency above the fundamental frequencies of the reactor power fluctuation spectrum

The principles of construction and the results of testing of a system for measuring P-odd asymmetries in nuclear reactions with polarized cold neutrons by the integrated method of recording events at the neutron polarization switching frequency above the fundamental frequencies of the reactor power fluctuation spectrum are presented. It is shown experimentally that if the signal under investigation is characterized by the spectral density of power decreasing with increasing frequency, switching of the equipment at a higher frequency decreases the measuring error. The dependence of the error of measurements of P-odd asymmetry in the emission of γ quanta in the ¹⁰B(n, α)⁷Li* ⟹ γ ⟹ ⁷Li(g.s.) reaction on the neutron polarization switching frequency is derived. The system described here is implemented experimentally for the first time.     

Asymmetric synthesis of the cytotoxic lactone (+)-cardiobutanolide and two novel analogues

A new asymmetric synthesis of the naturally occurring styryl lactone cardiobutanolide and two novel analogues have been achieved starting from d-xylose. The key steps of the synthesis included an initial zinc mediated reductive THF-ring opening, stereoselective olefination and Sharpless asymmetric dihydroxylation. It was shown that cardiobutanolide (1) exhibits promising in vitro antitumour properties against certain human neoplastic cell lines. It was more potent than the commercial anticancer agent doxorubicin against three cell lines (K562, HL-60 and Raji).     

Ecological studies of the naturally occurring radionuclides, 137Cs and heavy metals in soil,plants and milk in surrounding of Kragujevac city,Serbia

Journal of Radioanalytical and Nuclear Chemistry - Vertical distribution of natural radionuclides, 137Cs and heavy metals were measured in soil and plants collected from Kragujevac surroundings....     

Volatiles composition and antioxidant activity Inula oculus-christi L. from Serbia

Abstract

The chemical composition of the essential oil and the volatiles obtained by static headspace (HS) of Inula oculus-christi L. is presented. The GC-MS analysis of the hydrodistilled oil resulted in the identification of 90 components, representing 92.7% of the oil. The most abundant compounds were: caryophyllene oxide (9.8%), trans-longipinocarveol (9.2%), eucalyptol (7.3%) and intermedeol (6.2%). The major constituent of I. oculus-christi L. HS volatiles was eucalyptol (87.4%). The antioxidant activity was evaluated by four different methods: 2,2-diphenyl-1-picryl-hydrazylhydrate free radical assay (DPPH), 2,2-azino-bis-3-ethylbenzothiazoline-6-sulfonic acid (ABTS) method, total reducing power (TRP), ferric reducing antioxidant power (FRAP), and cupric reducing antioxidant capacity (CUPRAC). Total phenolic content in (TPC) examined oil was 177.95?µg GAE/mg oil. Radical scavenging potential of the oil was promising RSC-DPPH was 57.4% and RSC-ABTS was 82.7%.

     

A preliminary survey of natural radionuclides in soil and indoor radon in the town of Niš, Serbia

Journal of Radioanalytical and Nuclear Chemistry - The activity concentration of natural radionuclides in the samples of soil from the town of Ni? were measured using the gamma spectroscopy...     

Protein stability in an ionic liquid milieu: on the use of differential scanning fluorimetry

Protein stability is a major bottleneck in the biotechnological application of ionic liquid-containing solvents, either in the frame of biocatalysis or protein storage. Herein, differential scanning fluorimetry was successfully implemented as a high throughput method to fast scan the impact of a number of cholinium-based ionic liquids on the stability of proteins.     

Topologies of some new sequence spaces, their duals, and the graphical representations of neighborhoods

Many interesting topologies arise in the theory of FK spaces. Here we present some new results on the topologies of certain FK spaces and the determinations of their dual spaces. We also apply our software package for visualization and animations in mathematics and its extensions to the representation of neighborhoods in various topologies.     

Multifunctional PES fabrics modified with colloidal Ag and TiO2 nanoparticles

This study is aimed to highlight the possibility of engineering the multifunctional textile nanocomposite material based on the polyester (PES) fabric modified with colloidal Ag and TiO₂ nanoparticles (NPs). The effects of concentration of NPs as well as the order of Ag and TiO₂ NPs loading on antimicrobial, UV protective, and photocatalytic properties of PES fabrics were examined. The antimicrobial activity of differently modified PES fabrics was tested against Gram‐negative bacterium Escherichia coli, Gram‐positive bacterium Staphylococcus aureus, and fungus Candida albicans. The concentration of Ag colloid and the order of Ag and TiO₂ NPs loading considerably affected the antimicrobial efficiency of PES fabrics. The fabrics provided maximum UV protection upon surface modification with Ag and TiO₂ NPs. Ag NPs enhanced Ag NPs enhanced the photodegradation activity of TiO₂ NPs and total photodegradation of methylene blue was achieved after 24 hr of UV illumination. Copyright © 2010 John Wiley & Sons, Ltd.     

Chemical profile and biological activities of Peltigera horizontalis (Hudson) Baumg. thallus and apothecia extracts

Abstract

The aim of this study was to determine, for the first time, the chemical composition of Peltigera horizontalis thallus and apothecia extracts (ether, ethyl acetate, dichloromethane and acetone) by HPLC-UV and GC-MS, and evaluate activity of genotoxic, anticholinesterase, antioxidant and antibacterial potential of acetone extracts. Major constituents of thallus extracts were gyrophoric acid, and methyl gyrophorate while dominant component of apothecia extracts was tenuiorin. The predominant volatile compounds in extracts were methyl orsellinate, dodecyl acrylate, orcinol and orcinol monomethyl ether. The thallus acetone extract at concentration of 2.0 µg mL^?1 gave the greatest decrease in the micronuclei frequency (22.4%) of all tested extracts. Apothecia extract showed stronger antioxidant activity as compared to thallus extract. Tested extracts at concentration of 10?mg mL^?1 exhibited inhibitory effect (16.5% for thallus and 12.8% for apothecia) on pooled human serum cholinesterase. P. horizontalis acetone extracts had no activity against the tested five bacteria strains.     

The Structure of Aminopropylsiloxane Polymerized in DC Electric Field

Summary : The Raman spectra of aminopropylsiloxane (APS) polymerized on PVC substrate in DC electric field were measured to study the structure of deposited films. The modelling of low wavenumber Raman spectra was achieved using contribution of acoustic phonons, intramolecular vibrations as well as optical phonons related to librational motions of ladders. Results suggest that electric field influences the orientations of ladders increasing thus the degree of order in microdomains.