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排序方式: 共有673条查询结果,搜索用时 281 毫秒
61.
Narayanan Prakash Georg Csanády Markus R. A. Michaelis Günter Knapp 《Mikrochimica acta》1989,99(3-6):257-265
Automated preconcentration techniques for off/on-line determination with ICP-OES have been developed for various metal ions of environmental interest. Preconcentration studies were performed on two different types of chemically bonded chelating ion-exchangers, namely EDTrA-cellulose (iminoacetate groups) and HSO3 · oxine-cellulose. Enrichment studies were carried out at various preconcentration factors and also at different loadings.Presented in part at the 1989 European Winter Conference on Plasma Spectrochemistry, Reutte, Austria 相似文献
62.
A. Narayanan 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2006,39(1):13-22
An effective four-level system around the D2 line
of 85Rb at room temperature, is experimentally investigated
by fluorescent studies
under the action of two driving fields L1 and L2.
This system exhibits unique features in fluorescence as a function of frequency
separation between L1 and L2. In particular, at two-photon resonance,
when the Rabi frequency of L1 exceeds that of L2,
signatures of Electromagnetically Induced Transperancy effect (EIT)
arising from the three-level Λ sub-system
is present as a sub-natural dip in fluorescence from the fourth level.
At comparable strengths of L1 and L2
the fluorescence features indicate a regime, where
the effects arising
from optical pumping and EIT effect due to ground hyperfine level coherence
coexist. We see in the coexistence regime, saturation
effects arising from difference frequency crossing (DFC) resonances and optical
pumping around the EIT window. At low strengths of L1, all signs of
coherence vanishes from the system and the fluorescent features result
from incoherent optical pumping through the
Autler-Townes split states of the excited state
hyperfine levels, which are split due to the stronger L2 laser.
The dominant role of the L1 laser in creating a robust transparency signal even
in the presence of an off-resonant excitation is brought out.
The results are supported by density matrix calculations. 相似文献
63.
Madhavan Narayanan Vijay R. Singh Goutham Kodali Katarina Moravcevic Robert J. Stanley 《Photochemistry and photobiology》2017,93(1):343-354
Reduced anionic flavin adenine dinucleotide (FADH?) is the critical cofactor in DNA photolyase (PL) for the repair of cyclobutane pyrimidine dimers (CPD) in UV‐damaged DNA. The initial step involves photoinduced electron transfer from *FADH? to the CPD. The adenine (Ade) moiety is nearly stacked with the flavin ring, an unusual conformation compared to other FAD‐dependent proteins. The role of this proximity has not been unequivocally elucidated. Some studies suggest that Ade is a radical intermediate, but others conclude that Ade modulates the electron transfer rate constant (kET) through superexchange. No study has succeeded in removing or modifying this Ade to test these hypotheses. Here, FAD analogs containing either an ethano‐ or etheno‐bridged Ade between the AN1 and AN6 atoms (e‐FAD and ε‐FAD, respectively) were used to reconstitute apo‐PL, giving e‐PL and ε‐PL respectively. The reconstitution yield of e‐PL was very poor, suggesting that the hydrophobicity of the ethano group prevented its uptake, while ε‐PL showed 50% reconstitution yield. The substrate binding constants for ε‐PL and rPL were identical. ε‐PL showed a 15% higher steady‐state repair yield compared to FAD‐reconstituted photolyase (rPL). The acceleration of repair in ε‐PL is discussed in terms of an ε‐Ade radical intermediate vs superexchange mechanism. 相似文献
64.
An integral equation formulation for buoyancy-driven convection problems is developed and illustrated. Buoyancy-driven convection in a bounded cylindrical geometry with a free surface is studied for a range of aspect ratios and Nusselt numbers. The critical Rayleigh number, the nature of the cellular motion, and the heat transfer enhancement are computed using linear theory. Green's functions are used to convert the linear problem into linear Fredholm integral equations. Theorems are proved which establish the properties of the eigenvalues and eigenfunctions of the linear integral operator which appears in these equations. 相似文献
65.
66.
Acoustic characteristics of chamfered Hartmann whistles 总被引:1,自引:0,他引:1
Experimental studies are conducted to investigate the effect of internal chamfer at the mouth of Hartmann resonators. Studies involve a range of nozzle pressure ratios from 4 to 6, and chamfer angles 15°, 30°, and 45°. Further, the effects of cavity length and stand-off distance are also considered. The spectra, directivity, and acoustic power characteristics are studied in detail. Detailed numerical simulations are carried out to capture the flow oscillations inside as well as at the outside of the mouth of the chamfered cavities. Computations show flow diversion in chamfered cavities and explain the shift in the directivity observed experimentally. The fundamental frequency of cavities with 15° and 30° chamfers is observed to be higher than that of regular cavities. Resonance is intensified by the presence of chamfer resulting in higher overall sound pressure levels of chamfered whistles. Thus, chamfered Hartmann whistles are found to emit more than twice the acoustic power of a regular cylindrical whistle. The tonal quality of sound is analyzed using a new metric termed as “resonance index”. 相似文献
67.
Mithu VS Paul S Kurur ND Madhu PK 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2011,209(2):359-363
We compare in this communication several heteronuclear dipolar decoupling sequences in solid-state nuclear magnetic resonance experiments under a magic-angle spinning frequency of 60 kHz. The decoupling radiofrequency field amplitudes considered are 190 and 10 kHz. No substantial difference was found among the sequences considered here in performance barring the difference in the optimisation protocol of the various schemes, an aspect that favours the use of swept-frequency two pulse phase modulation (SW(f)-TPPM). 相似文献
68.
Facile,Template‐Free Synthesis of Stimuli‐Responsive Polymer Nanocapsules for Targeted Drug Delivery
69.
70.
Ram M. Narayanan Brett R. J. Snuttjer 《International Journal of Infrared and Millimeter Waves》1997,18(11):2077-2109
Millimeter-wave short range radar systems have unique advantages in surface navigation applications, such as military vehicle
mobility, aircraft landing assistance, and automotive collision avoidance. In collision avoidance applications, characterization
of clutter due to terrain and roadside objects is necessary in order to maximize the signal-to-clutter ratio (SCR) and to
minimize false alarms. The results of two types of radar cross section (RCS) measurements at 95 GHz are reported in this paper.
The first set of measurements presents data on the normalized RCS (NRCS) as well as clutter distributions of various terrain
types at low grazing angles of 5° and 7.5°. The second set of measurements presents RCS data and statistics on various types
of roadside objects, such as metallic and wooden sign posts. These results are expected to be useful for designers of short-range
millimeter-wave collision avoidance radar systems.
Brett Snuttjer is presently an Air Force Lieutenant at Rome Laboratory, Rome, NY 13441 相似文献