全文获取类型
收费全文 | 407篇 |
免费 | 9篇 |
国内免费 | 4篇 |
专业分类
化学 | 237篇 |
力学 | 4篇 |
数学 | 103篇 |
物理学 | 76篇 |
出版年
2023年 | 1篇 |
2022年 | 21篇 |
2021年 | 18篇 |
2020年 | 9篇 |
2019年 | 6篇 |
2018年 | 8篇 |
2017年 | 4篇 |
2016年 | 10篇 |
2015年 | 9篇 |
2014年 | 20篇 |
2013年 | 42篇 |
2012年 | 27篇 |
2011年 | 30篇 |
2010年 | 17篇 |
2009年 | 16篇 |
2008年 | 33篇 |
2007年 | 22篇 |
2006年 | 17篇 |
2005年 | 14篇 |
2004年 | 12篇 |
2003年 | 16篇 |
2002年 | 9篇 |
1999年 | 2篇 |
1998年 | 4篇 |
1997年 | 3篇 |
1996年 | 1篇 |
1994年 | 4篇 |
1993年 | 5篇 |
1991年 | 1篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1979年 | 3篇 |
1978年 | 3篇 |
1977年 | 1篇 |
1976年 | 3篇 |
1975年 | 3篇 |
1974年 | 2篇 |
1973年 | 3篇 |
1972年 | 3篇 |
1971年 | 1篇 |
1970年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有420条查询结果,搜索用时 15 毫秒
51.
We present a model of gauge theory based on the symmetry group G×SU(2) where G is the gravitational gauge group and SU(2) is the internal group of symmetry. We employ the spacetime of four-dimensional Minkowski, endowed with spherical coordinates, and describe the gauge fields by gauge potentials. The corresponding strength field tensors are calculated and the field equations are written. A solution of these equations is obtained for the case that the gauge potentials have a particular form potentials induces a metric of Schwarzschild type on with spherical symmetry. The solution for the gravitational the gravitational gauge group space. 相似文献
52.
53.
Nicoleta Petrea Răzvan Petre Andrada Pretorian Constantin Toader Vasile Şomoghi Florentina Neaţu Mihaela Florea Ştefan Neaţu 《Comptes Rendus Chimie》2018,21(3-4):339-345
The catalytic methanolysis of the chemical warfare nerve agents soman, sarin, and VX was investigated by using Cu or Zn complexes. Although VX withstood decontamination, the decomposition yield being around 96%, the soman and sarin deposited on different surfaces were almost fully destroyed under ambient conditions. The catalytic tests performed on a wide range of contaminated surfaces confirm the activity of the investigated catalytic systems, these complexes being suitable, from an economical point of view, for use in the formulation of a possible decomposition kit with military or civilian applicability. 相似文献
54.
Vasile Lauric 《Proceedings of the American Mathematical Society》1997,125(11):3371-3379
It is known that every operator on a Hilbert space whose invariant subspace lattice is possibly is a norm-limit of a sequence of nilpotent operators. In this note we study properties of such approximating sequences.
55.
Nikolaos S. Papageorgiou Eugénio M. Rocha Vasile Staicu 《Calculus of Variations and Partial Differential Equations》2008,33(2):199-230
In this paper we study second order elliptic equations driven by the Laplacian and p-Laplacian differential operators and
a nonlinearity which is (p-)superlinear (it satisfies the Ambrosetti–Rabinowitz condition). For the p-Laplacian equations
we prove the existence of five nontrivial smooth solutions, namely two positive, two negative and a nodal solution. Finally
we indicate how in the semilinear case, Morse theory can be used to produce six nontrivial solutions.
This paper was completed while the first author was visiting the University of Aveiro as an Invited Scientist. The hospitality
and financial support of the host institution are gratefully acknowledged. The second and third authors acknowledge the partial
financial support of the Portuguese Foundation for Science and Technology (FCT) under the research project POCI/MAT/55524/2004. 相似文献
56.
Cojocaru B Laferrière M Carbonell E Parvulescu V García H Scaiano JC 《Langmuir : the ACS journal of surfaces and colloids》2008,24(9):4478-4481
Singlet oxygen has been characterized spectroscopically as a product of the exposure of suspensions of zeolites containing oxidation catalysts. Spectroscopic and lifetime studies show that a part of the singlet oxygen formed reacts within the zeolite porous structure, while a significant fraction escapes and becomes available for reaction in the bulk media. The liquid phase plays a key role in determining intra- and extracavity dynamics. 相似文献
57.
Neaţu F Li Z Richards R Toullec PY Genêt JP Dumbuya K Gottfried JM Steinrück HP Pârvulescu VI Michelet V 《Chemistry (Weinheim an der Bergstrasse, Germany)》2008,14(30):9412-9418
A novel class of heterogeneous gold catalysts supported on zeolite beta-NH4+ was prepared by the deposition-precipitation method. This new class of catalyst showed interesting catalytic activities for the intramolecular cycloisomerization of gamma-acetylenic carboxylic acids leading to functionalized gamma-alkylidene gamma-butyrolactones. Analysis of the supported gold species with in situ X-ray photoelectron spectroscopy (in situ XPS) suggests that cationic Au (possibly AuIII) can play an important role in such reactions. The high discrepancy in catalyst stability in favor of the Au supported on the zeolite system over bulk Au2O3 is explained by 1) the size of the particles and 2) the reversibility of the redox deactivating process (AuIII-->AuI) in the presence of oxygen for the supported system. The efficiency of this system allowed reaction under mild heterogeneous conditions. The potential for catalyst recycling was also highlighted. 相似文献
58.
Dr. Nicolas D'Imperio Dr. Valentina Pelliccioli Dr. Sara Grecchi Dr. Alberto Bossi Prof. Francesca Vasile Prof. Silvia Cauteruccio Dr. Anna I. Arkhypchuk Dr. Arvind Kumar Gupta Prof. Dr. Andreas Orthaber Prof. Dr. Sascha Ott Prof. Emanuela Licandro 《European journal of organic chemistry》2023,26(4):e202201209
The first examples of a π-conjugated benzo[b]phosphole P-oxide in which two phosphole P-oxide units are connected by a carbon-carbon double bond are described. The molecules are synthesized as E isomers with respect to the carbon-carbon double bond and exist as stable cis and trans isomers (chiral and meso one respectively) relatively to the two stereogenic P atoms. The optical and electrochemical properties of both isomers have been investigated by experiment and computations. 相似文献
59.
Frunza L Schönhals A Frunza S Parvulescu VI Cojocaru B Carriazo D Martín C Rives V 《The journal of physical chemistry. A》2007,111(24):5166-5175
The rotational molecular dynamics of water confined to layered oxide materials with brucite structure was studied by dielectric spectroscopy in the frequency range from 10(-2) to 10(7) Hz and in a broad temperature interval. The layered double hydroxide samples show one relaxation process, which was assigned to fluctuations of water molecules forming a layer, strongly adsorbed to the oxide surface. The temperature dependence of the relaxation rates has an unusual saddlelike shape characterized by a maximum. The model of Ryabov et al. (J. Phys. Chem. B 2001, 105, 1845) recently applied to describe the dynamics of water molecules in porous glasses is employed also for the layered materials. This model assumes two competing effects: rotational fluctuations of water molecules that take place simultaneously with defect formation, allowing the creation of free volume necessary for reorientation. The activation energy of rotational fluctuations, the energy of defect formation, a pre-exponential factor, and the defect concentration are obtained as main parameters from a fit of this model to the data. The values of these parameters were compared with those found for water confined to nanoporous molecular sieves, porous glasses, or bulk ice. Several correlations were discussed in detail, such as the lower the value of the energy of defect formation, the higher the number of defects. The pre-exponential factor increases with increasing activation energy, as an expression of the compensation law, and indicates the cooperative nature of the motional process. The involvement of the surface OH groups and of the oxygen atoms of the interlayer anions in the formation of hydrogen bonds was further discussed. For the birnessite sample, the relaxation processes are probably overlaid by a dominating conductivity contribution, which is analyzed in its frequency and temperature dependence. It is found that the conductivity of birnessite obeys the characteristics of semiconducting disordered materials. Especially the Barton/Nakajima/Namikawa relationship is fulfilled. Analyzing the temperature dependence of the direct current (dc) conductivity sigma0 in detail gives some hint that sigma0(T) has also an unusual saddlelike form. 相似文献
60.
Bhattacharyya S Salvetat JP Roy D Heresanu V Launois P Saboungi ML 《Chemical communications (Cambridge, England)》2007,(41):4248-4250
Highly ordered self-assembled multi-layer structures with denatured collagen wrapped single wall carbon nanotubes and surfactant systems were obtained through bioinspired methodology. 相似文献