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41.
Paulose M Shankar K Yoriya S Prakasam HE Varghese OK Mor GK LaTempa TJ Latempa TA Fitzgerald A Grimes CA 《The journal of physical chemistry. B》2006,110(33):16179-16184
Described is the fabrication of self-aligned highly ordered TiO(2) nanotube arrays by potentiostatic anodization of Ti foil having lengths up to 134 mum, representing well over an order of magnitude increase in length thus far reported. We have achieved the very long nanotube arrays in fluoride ion containing baths in combination with a variety of nonaqueous organic polar electrolytes including dimethyl sulfoxide, formamide, ethylene glycol, and N-methylformamide. Depending on the anodization voltage, pore diameters of the resulting nanotube arrays range from 20 to 150 nm. Our longest nanotube arrays yield a roughness factor of 4750 and length-to-width (outer diameter) aspect ratio of approximately 835. The as-prepared nanotubes are amorphous but crystallize with annealing at elevated temperatures. In initial measurements, 45 mum long nanotube-array samples, 550 degrees C annealed, under UV illumination show a remarkable water photoelectrolysis photoconversion efficiency of 16.25%. 相似文献
42.
Swamy V Kuznetsov A Dubrovinsky LS McMillan PF Prakapenka VB Shen G Muddle BC 《Physical review letters》2006,96(13):135702
We investigated the size-dependent high-pressure phase transition behavior of nanocrystalline anatase TiO2 with synchrotron x-ray diffraction and Raman spectroscopy to 45 GPa at ambient temperature. Pressure-induced amorphization results in a high-density amorphous (HDA) form when the starting crystallite size is < 10 mm. The HDA-TiO2 transforms to a low-density amorphous form at lower pressures. Harnessing the nanometer length scale thus provides a new window for experimental investigation of amorphization in poor glass formers and a synthesis route for new amorphous materials. 相似文献
43.
FT-IR, FT-Raman and SERS spectra of Vitamin C 总被引:1,自引:0,他引:1
Yohannan Panicker C Tresa Varghese H Philip D 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2006,65(3-4):802-804
FT-IR and FT-Raman spectra of Vitamin c have been recorded and analysed. SERS spectrum was recorded is silver colloid. The molecule is thought to adsorb with the lactone ring in a tilted side on orientation with respect to the silver surface. 相似文献
44.
45.
Olga Varghese 《Archiv der Mathematik》2018,111(3):231-238
We show that certain representations over fields with positive characteristic of groups having CAT\((0)\) fixed point property \(\mathrm{F}\mathcal {B}_{\widetilde{A}_n}\) have finite image. In particular, we obtain rigidity results for representations of the following groups: the special linear group over \({\mathbb {Z}}\), \({\mathrm{SL}}_k({\mathbb {Z}})\), the special automorphism group of a free group, \(\mathrm{SAut}(F_k)\), the mapping class group of a closed orientable surface, \(\mathrm{Mod}(\Sigma _g)\), and many other groups. In the case of characteristic zero, we show that low dimensional complex representations of groups having CAT\((0)\) fixed point property \(\mathrm{F}\mathcal {B}_{\widetilde{A}_n}\) have finite image if they always have compact closure. 相似文献
46.
MATHAI Varghese 《中国科学 数学(英文版)》2010,(3)
We review the Reidemeister, Ray-Singer’s analytic torsion and the Cheeger-Mller theorem. We describe the analytic torsion of the de Rham complex twisted by a flux form introduced by the current authors and recall its properties. We define a new twisted analytic torsion for the complex of invariant differential forms on the total space of a principal circle bundle twisted by an invariant flux form. We show that when the dimension is even, such a torsion is invariant under certain deformation of the metric and the flux form. Under T-duality which exchanges the topology of the bundle and the flux form and the radius of the circular fiber with its inverse, the twisted torsion of invariant forms are inverse to each other for any dimension. 相似文献
47.
Mohammad Bodiuzzaman Atanu Ghosh Korath Shivan Sugi Abhijit Nag Esma Khatun Babu Varghese Ganesan Paramasivam Sudhadevi Antharjanam Ganapati Natarajan Thalappil Pradeep 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(1):195-200
Two ligand‐protected nanoscale silver moieties, [Ag46(SPhMe2)24(PPh3)8](NO3)2 and [Ag40(SPhMe2)24(PPh3)8](NO3)2 (abbreviated as Ag46 and Ag40, respectively) with almost the same shell but different cores were synthesized simultaneously. As their external structures are identical, the clusters were not distinguishable and become co‐crystallized. The occupancy of each cluster was 50 %. The outer shell of both is composed of Ag32S24P8, which is reminiscent of fullerenes, and it encapsulates a well‐studied core, Ag14 and a completely new core, Ag8, which correspond to a face‐centered cube and a simple cube, respectively, resulting in the Ag46 and Ag40 clusters. The presence of two entities (Ag40 and Ag46 clusters) in a single crystal and their molecular formulae were confirmed by detailed electrospray ionization mass spectrometry. The optical spectrum of the mixture showed unique features which were in good agreement with the results from time‐dependent density functional theory (TD‐DFT). 相似文献
48.
Maruthibabu Paidikondala Vignesh Kumar Rangasami Ganesh N. Nawale Tommaso Casalini Giuseppe Perale Sandeep Kadekar Gaurav Mohanty Turkka Salminen Oommen P. Oommen Oommen P. Varghese 《Angewandte Chemie (International ed. in English)》2019,58(9):2815-2819
Circulating nucleic acids, such as short interfering RNA (siRNA), regulate many biological processes; however, the mechanism by which these molecules enter the cell is poorly understood. The role of extracellular‐matrix‐derived polymers in binding siRNAs and trafficking them across the plasma membrane is reported. Thermal melting, dynamic light scattering, scanning electron microscopy, and computational analysis indicate that hyaluronic acid can stabilize siRNA via hydrogen bonding and Van der Waals interactions. This stabilization facilitated HA size‐ and concentration‐dependent gene silencing in a CD44‐positive human osteosarcoma cell line (MG‐63) and in human mesenchymal stromal cells (hMSCs). This native HA‐based siRNA transfection represents the first report on an anionic, non‐viral delivery method that resulted in approximately 60 % gene knockdown in both cell types tested, which correlated with a reduction in translation levels. 相似文献
49.
Supramolecular hydrogels are a class of self‐assembled network structures formed via non‐covalent interactions of the hydrogelators. These hydrogels capable of responding to external stimuli are considered to be smart materials due to their ability to undergo sol–gel and/or gel–sol transition upon subtle changes in their surroundings. Such stimuli‐responsive hydrogels are intriguing biomaterials with applications in tissue engineering, delivery of cells and drugs, modulating tissue environment to promote innate tissue repair, and imaging for medical diagnostics among others. This review summarizes the recent developments in stimuli‐responsive supramolecular hydrogels and their potential applications in regenerative medicine. Specifically, various structural aspects of supramolecular hydrogelators involved in self‐assembly, the role of external stimuli in tuning/controlling their phase transitions, and how these functions could be harnessed to advance applications in regenerative medicine are focused on. Finally, the key challenges and future prospects for these versatile materials are briefly described. 相似文献
50.
We describe an improved method for coherence domain path length resolved measurements of multiply scattered photons in turbid media. An electro-optic phase modulator sinusoidally modulates the phase in the reference arm of a low coherence fiber optic Mach-Zehnder interferometer, at a high phase modulation angle. For dynamic turbid media this results in Doppler broadened phase modulation interference peaks at the modulation frequency and its multiples. The signal to noise ratio is increased by almost one order or magnitude for large modulation angles and the shape of the spectral peaks resulting from the interference of Doppler shifted sample waves and reference light is not changed. The path length dependent Doppler broadening is compared with the theoretical predictions in the single scattered and diffusive regimes. The experimentally measured optical path lengths are validated with the Monte Carlo technique. 相似文献