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81.
In ultrasonic non-destructive testing of materials with a coarse-grained structure the scattering from the grains causes backscattering noise, which masks flaw echoes in the measured signal. Several filtering methods have been proposed for improving the signal-to-noise ratio. In this paper we present a comparative study of methods based on the wavelet transform. Experiments with stationary, discrete and wavelet packet de-noising are evaluated by means of signal-to-noise ratio enhancement. Measured and simulated ultrasonic signals are used to verify the proposed de-noising methods. For comparison, we use signal-to-noise ratio enhancement related to fault echo amplitudes and filtering efficiency specific for ultrasonic signals. The best results in our setup were achieved with the wavelet packet de-noising method. 相似文献
82.
Unique information about the chemical vicinity of positron annihilation sites is provided by the contribution of high electron momenta to the Doppler spectrum, since this momentum range is characteristic for the annihilation with core electrons and hence element specific. However, the corresponding energy region in the spectrum is overlaid by a huge background caused by the annihilation radiation itself and the Compton spectrum of other gamma lines having an energy above 511 keV. Usually these backgrounds are reduced by measuring both annihilation quanta in coincidence.By mathematically analyzing the background contributions, we open another possibility to obtain the high-momentum region employing one single germanium detector. A necessary precondition is employing either background-free positron beams or a low-background positron source, e.g. 68Ge, instead of the widely used positron emitter 22Na. The 68Ge-source emits positrons with an endpoint energy of about 1.9 MeV, where as the contribution of gamma quanta having higher energies than the annihilation radiation at 511 keV is negligible low.When analyzing spectra from metals and semiconductors according to the described background subtraction, the same information contained in the momentum range up to 35 × 10−3m0c or beyond can be extracted, as if the spectra were measured employing a coincidence setup with two Ge-detectors. 相似文献
83.
We present preliminary results on the structure of nano-sized particles (clusters of solute atoms or Guinier-Preston-Bagaryatsky (GPB) zones) in aluminum alloys. Hindering the motion of dislocations, these GPB zones (precipitates) are responsible for the strength of AlCuMg-alloys - used e.g. as AA2024 - for the outer shell plates in aircraft industry. We will discuss the role of quenched-in vacancies for the formation and growth of the precipitates. Using positron annihilation (Doppler broadening together with the recently developed tool of high-momentum analysis (HMA)) and X-ray absorption spectroscopy measurements, we are able to characterize the local atomic environment in the vicinity of vacancies and selected elements (Cu) forming the precipitates. The interpretation will be based on a comparison to numerical calculations of positron lifetimes and momentum distributions as well as simulated X-ray absorption spectra. Often reliable numerical calculations of experimental quantities are possible only if relaxed atomic positions - calculated employing an ab-initio code like SIESTA - are used as input. 相似文献
84.
The narrow absorption peak at 163 meV has been studied as a function of temperature. It is proposed that the peak is due to an electronic transition at a localised defect and that it and its satellites at higher energy are typical of a general class of absorption spectra in ionic crystals. 相似文献
85.
K. Henning L.P. Kaun B. Lippold S. Matthies W. Matz W. Drexel P. Seifert N.I. Moreva 《Solid State Communications》1977,21(3):297-300
We report the.results of an experimental determination of the crystal field splitting of Pr3+ in PrAl2 by means of inelastic neutron scattering. For the crystal field parameters we obtain B4 = (47.2 ± 4.0) × 10?4 meV and B6 = ? (156 ± 12) × 10?6 meV. 相似文献
86.
Jing B Janout V Herold BC Klotman ME Heald T Regen SL 《Journal of the American Chemical Society》2004,126(49):15930-15931
A series of persulfated molecular umbrellas have been synthesized from putrescine, spermidine, spermine, lysine, and cholic acid (1a, 2a, 3a, 4a, and 5a) and their anti-HIV and anti-HSV activities determined. Despite it size, the most active of these conjugates (5a) was able to cross phospholipid bilayers made from 1-palmitoyl-2-oleyol-sn-glycero-3-phosphocholine (POPC) and 1-palmitoyl-2-oleoyl-sn-glycero-3-phosphatidylglycerol (POPG). The unique combination of anti-viral activity, an ability to cross hydrophobic barriers, a lack of cytotoxicity, and a simple three-step synthesis from biogenic starting material suggests that 5a and related conjugates may be exploitable as a novel class of anti-viral agents for systemic and topical applications. 相似文献
87.
This paper reports the first example of electrospray ionization (ESI) for the separation and detection of anions in aqueous solutions by ion mobility spectrometry (IMS). Standard solutions of arsenate, phosphate, sulfate, nitrate, nitrite, chloride, formate, and acetate were analyzed using ESI-IMS and distinct peak patterns and reduced mobility constants (K(0)) were observed for respective anions. Real world water samples were analyzed for nitrate and nitrite to determine the feasibility of using ESI-IMS as a rapid analytical method for monitoring nitrate and nitrite in water systems. The data showed satisfactory correlation between the measured value ([similar]0.16 ppm) and the reported maximum nitrate-nitrogen concentration (0.2 ppm) found in a local drinking water system. For on-site measurement applications, direct sample introduction and air as an alternate drift gas to nitrogen were evaluated. The identities of the nitrite and nitrate mobility peaks were verified by comparison of reduced mobility constants with mass identified nitrate and nitrite ions reported in literature. In the mixing ratio, a linear dynamic range of 3 orders of magnitude and instrument detection limits of 10 ppb for nitrate and 40 ppb for nitrite were obtained. The calibration curves showed r(2) value of 0.98 and slope of 0.06 for nitrate and r(2) value of 0.99 and slope of 0.11 for nitrite. 相似文献
88.
In the presence of acid, 2-alkyl-2-vinylcyclobutanones rearrange mainly by a 1,2-acyl migration to give cyclopentenones while 2-vinylcyclobutanones lacking 2-alkyl substituents undergo a 1,3-acyl migration to produce cyclohexenones; the former rearrangement can be used to produce angularly substituted fused bicyclic systems. 相似文献
89.
90.
Janout V Myers SB Register RA Regen SL 《Journal of the American Chemical Society》2007,129(17):5756-5759
This paper introduces a fundamentally new concept in adsorbents, whereby the sorption of an aqueous solute by a cross-linked polymer is controlled by a gel to liquid-crystalline phase transition. To demonstrate proof of principle, a bilayer forming surfactant, N,N-dioctadecyl,N,N-dimethylammonium bromide (DODAB) has been immobilized onto a cation exchange resin, Dowex 50WX2, and its thermotropic phase behavior and solute-adsorption properties have been investigated. Examination by a combination of differential scanning calorimetry and X-ray scattering has confirmed the retention of a gel to liquid-crystalline phase transition of the surfactant, occurring between 296 and 318 K. Adsorption measurements that were made for 4-chlorotetrahydropyran, 1,2-dichloroethane, and benzyl alcohol have also confirmed uptake by the resin in the liquid-crystalline phase and release in the gel phase. 相似文献