Carbonization and graphitization of pitch applied for anode materials of high power lithium ion batteries

The artificial graphite materials were prepared by carbonizing coal tar pitch using two methods, namely, one- and two-step processes, and all sintered samples were graphitized at 2800 °C. Effects of different heat treatments on the performance of the samples were characterized by scanning electron microscopy, transmission electron microscopy (TEM), X-ray diffraction, Brunauer–Emmett–Teller, electrochemical impedance spectroscopy (EIS), particle size analysis, polarized light microscopy, and charge–discharge measurements. All samples show a typical graphite crystalline structure; moreover, the degree of graphitization (g factor) and crystallite size along the c-axis (L _c ) were calculated from (002) peak. The polarized light microscopy indicates that the coke with carbonization at 700 °C has an obvious wide domain (D) optical structure, while that with two-step sintering at 400 and 700 °C has a mixed optical structures of wide D, flow domains, and mosaics. TEM analysis revealed a number of irregular graphene layer images which are caused by the defects of graphite. EIS shows that the sample carbonized by two-step has a larger diffusion coefficient than the sample carbonized at 700 °C by one step. Higher carbonization temperature leads to better cycle performance as the temperature increasing from 500 to 700 °C in the one-step route. Specifically, the charge (Li⁺ extraction) capacity at the 50th cycle increases from 318 mA?h?g^?1 to 357 mA?h?g^?1. The results show that the rate performance of the artificial graphite is improved with the addition of the presintering at 400 °C.     

On resistive nonlocal Josephson electrodynamics

New solutions of one-dimensional nonlocal Josephson electrodynamics are proposed that describe the steady and nonsteady Abrikosov-Josephson vortex states of the resistive model; these solutions are based on the superposition principle of the vortex structures whose properties are determined by the nonlinear interaction of the vortices. The stability of the current-voltage characteristic (1.13) is shown and the relaxation-oscillation mode of establishing the corresponding state is investigated. The laws governing the annihilation and dispersal of the interacting Abrikosov-Josephson vortices are examined. Zh. éksp. Teor. Fiz. 112, 1396–1408 (October 1997)     

Solution methods for two-player differential games

A numerical solution method is proposed for the pursuit-and-evasion game in which the terminal set is the sum of a two-dimensional convex compactum and a linear subspace of codimension 2. The “convexification method” is applied to compute the alternated sums. Simple switching lines are constructed for the case when the set of constraints on pursuer controls is a polyhedron. These simple switching lines essentially simplify the construction of a pursuit strategy in the convex programming problem. Translated from Nelineinye Dinamicheskie Sistemy: Kachestvennyi Analiz i Upravlenie — Sbornik Trudov, No. 2, pp. 49–66, 1994.     

两奇点外不同时存在半稳定环的条件

研究Ⅲ类方程在其两焦点附近的半稳定环不能同时存在的问题。首先利用半稳定环存在的必要条件建立一个积分等式，借助于它就可得到若干不能同时存在的充分条件。     

Anomalous kinetics of plasmas in high-power radiation fields

Transport equations are obtained in the nine-moment approximation for plasmas in intense radiation fields where the amplitude of the electron oscillations in the electromagnetic field exceeds the thermal speed. It is shown that for plasmas with a high degree of ionization, Z, the electron thermal conductivity is higher by approximately a factor of Z. The change in the frictional force on electrons colliding with ions owing to the effect of the radiation field leads to the possibility of electron acceleration and to a change in the sign of the dc and low-frequency electrical conductivities. Zh. éksp. Teor. Fiz. 111, 478–495 (February 1997)     

Effect of hydrogen enrichment of laminar ethylene diffusion flames on thermal structure and soot yields at pressures up to 10 bar

A series of high-pressure experiments were conducted to assess the influence of hydrogen enrichment of laminar diffusion flames of nitrogen-diluted ethylene on the thermal flame structure and soot yields at pressures above atmospheric. In parallel experiments, added hydrogen is replaced by helium, either in equal mole fractions or in mass fractions, to evaluate the thermal, dilution, and direct chemical interaction effects of hydrogen in soot formation. Experiments covered pressures from atmospheric to 10 bar. In the first set of experiments, conducted at 3, 6, and 10 bar pressure, base fuel was an ethylene-nitrogen mixture with 33.3% ethylene and 66.7% nitrogen (by mole as well as by mass). This base fuel was doped with either hydrogen or helium such that hydrogen and helium mass fractions and mole fractions in the fuel stream are matched in two cases. In the second set of experiments, which were conducted at 1.2 bar pressure with ethylene as the base fuel, hydrogen or helium is added such that additive mole fraction in the fuel stream was 44%. Temperature measurements in the first set of experiments indicate that, when hydrogen is added to nitrogen-diluted ethylene, the changes in the temperature field of the co-flow diffusion flames are negligible, except at lower in the flame where hydrogen added flames display slightly higher temperatures. When helium is added instead of hydrogen, however, the temperatures were measurably lower than those of the base fuel. Results show that, once the dilution effects are accounted for, the hydrogen addition to ethylene does not suppress soot formation by direct chemical interaction at elevated pressures. These findings, which are not in agreement with the previous experimental results obtained at atmospheric pressure, are discussed in terms of the higher molecular diffusivity of hydrogen and shorter residence times of high-pressure flames.     

On the velocity of a 4π kink moving under the action of current

The dependence of bias current density through a junction on the velocity of a uniformly moving vortex carrying two magnetic flux quanta is established in the approximation of weakly nonlocal Josephson electrodynamics. It is shown that the velocity quantization of free motion of the vortex, which is induced by the Cherenkov interaction with Swihart waves, leads to the emergence of a discrete family of curves on the velocity-current plane.