Synthesis and investigation of the mesomorphic properties of pyran derivatives

4-[(5,6-Dihydro-2H-pyran-4-yl)methoxy]benzylidene-4-alkoxyanilines, which have the properties of smectic liquid crystals, were synthesized. The effect of the pyran ring in the benzylidene component and the length of the aliphatic radical in the aniline component on the type and thermal stability of the meso phase was ascertained.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 327–328, March, 1992.     

Synthesis of 24-epiteasterone

Starting from ergosterol, the synthesis of the brassinosteroid 24-epiteasterone has been achieved by the use of a new scheme for introducing a 3-hydroxy-6-keto group as the result of the Birch reduction of the corresponding 5-hydroxy-⁷-3,6-dione.Institute of Bioorganic Chemistry, Belorussian Academy of Sciences, Minsk. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 224–227, March–April, 1992.     

Harary-Read numbers for catafusenes: Complete classification according to symmetry

The classical Harary-Read numbers for catafusenes (catacondensed simply connected polyhexes) are reproduced without using generating functions. A complete (mathematical) solution is given for the distribution of these numbers over the different symmetry groups to which the catafusenes belong.     

Synthesis of 2-R-fluorantheno[2,3-d]- and 2-R-fluorantheno[3,2-d]oxazoles

2-R-Fluorantheno[2,3-d]- and 2-R-fluorantheno[3,2-d]oxazoles were synthesized, and their UV and IR spectra were studied. Ten new compounds are described.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 905–907, July, 1974.     

Otpically illuminated dielectric interfaces as high-speed far-infrared modulators

A new device for the gigahertz modulation of far-infrared radiation is analytically and numerically analyzed. It consists of a thin layer of a high-mobility, direct-bandgap semiconductor, such as GaAs, in which a high-density electron-hole plasma is rapidly created and destroyed, thereby rapidly changing the free-carrier reflectivity of the active layer. Illumination by a high-power, near-infrared laser diode array generates the plasma through intrinsic photoconduction. It is shown that this device acis primarily as an amplitude modulator, and that its efficiency increases sharply with increasing far-IR frequency, in contrast to a Schottky diode, which acts primarily as a phase modulator, and whose efficiency falls off sharply with far-IR frequency. The breakeven frequency lies at about 1.5 THz, depending slightly on the assumed device parameters. The relative advantage of the new device increases rapidly with increasing far-infrared frequency. At an operating frequency of 2.5 THz (119 m), for example, a 1 GHz modulation bandwidth may be achieved with a single-sideband conversion loss of only-21 db, versus a Schottky's loss of-39 db, assuming a laser diode power of 1 W, which is readily available from recently developed laser diode arrays.     

Calculation of exclusive processes with baryons

Using the nucleon andΔ ₃₃-resonance wave functions found out in previous papers [14, 15] we calculate the electromagnetic and weak nucleon formfactors, the transition formfactorγ \(\bar N\) Δ and the decay widths of charmonium levels³ S ₁,³ P ₂ and³ P ₁ into \(\bar N\) N and \(\bar \Delta \) Δ.     

C-odd exchange in high energypp andp \bar p elastic diffraction

Following the arguments of QCD, a proposed model takes into account the significant difference ofpp andp \(\bar p\) elasticd σ/dt discovered at the ISR. An expression forC-odd exchange is discussed and comparison with data is made. Starting from the ISR energies, the model is shown to describe well the data in a wide range of transverse momenta 0≦?t≦10 (GeV/c)² (including the Coulomb-nuclear interference region). Several peculiar predictions of the model will be testable in the TeV energy range and beyond.     

Relativistic correction to the triton binding energy in the framework of relativistic Hamiltonian dynamics

The relativistic correction to the triton binding energy approximated to the order (v/c)² is calculated in the framework of relativistic Hamiltonian dynamics. We discuss the generator representation of the Poincaré group for three relativistic particles and its connection with the Feynman diagrams in the infinite-momentum frame (the light-front dynamics). The relativistic correction enhances the attraction in the three-nucleon system. The five-channel calculation with the Reid soft-core potential yeilds the result =–0.54 MeV, which is governed mainly by theD-wave contribution. TheS-wave contributions to are only –0.10 MeV.     

Laser-pulse fluctuations due to thermal self-action in a turbulent atmosphere

Conclusions Refractive-index fluctuations caused by heating alter the intensity and phase fluctuation spectra arising from the turbulence. The large-scale part of the spectra is weakened, whereas the small-scale part is strengthened, and the spatial-frequency range in which the fluctuations are attenuated becomes narrower as the beam energy increases. Correspondingly, the fluctuation structure functions alter. For values of the arguments in those functions less than the radius of the first Fresnel zone , the thermal nonlinearity causes increases in the structural functions D_, with the energy. For , the dependence of D_, on energy is nonmonotone, with the fluctuations at first weakened but then strengthened. The reduction in fluctuation variance and the improvement in coherence is less pronounced over long lines than on short ones. The range in which geometrical optics can be used to derive the fluctuations is independent of the nonlinearity and is defined by k₂z/2k /4. The trend to the diffraction asymptote becomes slower as the nonlinearity increases.Atmospheric Physics Institute, Academy of Sciences of the USSR. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 32, No. 9, pp. 1063–1071, September, 1989.