Thermal transformation of color centers in neutron-irradiated sapphire

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 56, No. 2, pp. 268–273, February, 1992.     

Thermoelastic contact interaction of bodies in the presence of surface thermophysical irregularities

We study the thermoelastic contact interaction (in the absence of friction) of half-spaces under conditions of planar deformation in the presence of thin surface thermophysical irregularities that are taken into account by means of generalized conditions of thermal contact with one another. The problem is reduced to solving a system of singular integrodifferential equations with respect to the jumps of temperature and heat flow on the boundary of a section. We analyze the influence of a nonuniform thermal resistance distributed periodically along the surface or localized in one region of it on the distribution of temperature and stresses in the bodies and on their boundary. Four figures.Translated fromMatematicheskie Metody i Fiziko-Mekhanicheskie Polya, Issue 27, 1988, pp. 23–28.     

Violation of KNO scaling and the NBD phenomenon in the framework of the statistical bootstrap model

The connection is considered of multiplicity distributions in three stages: partonic, hadronization, and hadronic. An interpretation of the LoPHD parameter is found. It is shown that under specific hypotheses on the form of the mass spectrum, the statistical bootstrap model leads to the negative binomial distribution (NBD) at the hadronic stage of development of the multiple production process with specific analytic dependences of the parameters of the NBD.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 28–32, May, 1991.One of the authors (V. I. Kuvshinov) is thankful to R. Hagedorn and G. Burgers for numerous discussions.     

Direct electrosynthesis of halo and mixed-halo complexes of palladium(II and IV) by the dissolution of a sacrificial palladium anode in aqueous medium

A rapid single-step method for the electrosynthesis of chloro and bromo complexes of palladium(II and IV), viz. M₂[PdX₄] and M₂[PdX₆], by the dissolution of a palladium anode in chloride or bromide containing media is described. Electrolysis of dilute HX solution in the presence of pyridine, 2,2′-bipyridyl or 1,10-phenanthroline gives rise to non-electrolytes, e.g. trans-[PdX₂(py)₂], [PdX₂(bipy)] and [PdX₂(phen)]. Anodic oxidation of palladium in HX medium in the presence of acetonitrile and benzonitrile also gives the non-electrolytes trans-[PdX₂(CH₃CH₂NH₂)₂] and trans-[PdX₂(C₆H₅CH₂NH₂)₂], respectively.     

Metal complexation of crosslinked polyacrylamide-supported dithiocarbamates: Effect of the molecular character and extent of crosslinking on complexation

Dithiocarbamate functions were incorporated into different polyacrylamide matrices crosslinked with a flexible and hydrophilic crosslinking agent, tetraethyleneglycol diacrylate (TEGDA), and their complexation behaviours were investigated. Crosslinked polyacrylamides with varying extents of the tetrafunctional TEGDA crosslinks were prepared by free radical solution polymerization at 60°C using potassium persulphate as initiator in ethanol. The dithiocarbamate functionality was incorporated into these polyacrylamides by a two-step polymer-analogous reaction involving (i)trans-amidation with ethylenediamine and (ii) dithiocarbamylation of the aminopolyacrylamide with carbon disulphide and alkali. The complexations of dithiocarbamate with Cu(II), Ni(II), Zn(II), Co(II) and Hg(II) ions were followed under different conditions. The metal ion intake varied with the extent of the crosslinking agent and the observed trend in complexation is Hg(II) > Cu(II)> Zn(II)> Co(II)> Ni (II). The time-course of complexation, the possibility of recycling, swelling characteristics, and spectral and thermal analyses were carried out. The thermal stability increases upon complexation with metal ions.