2,3-Diphenylthiazolo[3,2-a]pyrimidinium salts

The corresponding 2,3-diphenyl[3,2-a]pyrimidinium salts were obtained by the condensation of 4,5-diphenyl-2-aminothiazole perchlorate with -diketones, -chlorovinyl ketones, -chlorovinyl aldehydes, and 1,1,3,3-tetraethoxypropane. The PMR spectra were used to prove the structures of the compounds obtained, particularly to select the structures of the isomeric salts obtained in the condensation with unsymmetrical -diketones, -chlorovinyl ketones, and -chlorovinyl aldehydes. As a rule, the latter give one isomer — the -unsubstituted (relative to the bridge nitrogen atom) derivative.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 629–631, May, 1972.     

Catalytic properties of iron tetracarbonyl π-complexes of vinylsilanes in the addition of polyhalomethanes and hydrosilanes to vinylsilanes

Conclusions The high catalytic activity of (CH₂=CHSiR₃)·Fe(CO)₄ complexes was demonstrated in the reaction of vinylsilanes with polyhalomethanes and hydrosilanes.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 914–920, April, 1982.     

Peculiar features of application of pH gradients formed in borate buffer with a polyhydroxy compound for separation of proteins in a free-flow electrophoretic apparatus

The use of pH gradients in borate buffer with a polyhydroxy compound for separation of proteins in a free-flow electrophoretic apparatus is outlined. The composition of the pH gradients, the free-flow apparatus design and its operation, and the main causes of failures in the protein separation are considered.