Synthesis and crystal and molecular structure of newN-substituted γ-hydroxybutyramides

TheN-(2-phenylethyl)amide of-(1, 1-ethylenedioxy)-ethyl--hydroxybutyric acid (II) and theN-(p-methoxybenzyl)amide of-(1, 1-ethylenedioxy)-ethyl--hydroxybutyric acid (III) have been synthesized and the crystal structure ofIII has been solved. CompoundIII, C₁₆H₂₃O₅N, crystallizes in the monoclinic space groupP2₁/c witha=12.572(2),b=11.149(2),c=12.317(2) Å and=106.53(1)°. The structure was solved by direct methods, and refined by full-matrix least squares to giveR=0.040 (R _w =0.047) for 2004 intensities. The dioxolane ring has a deformed half-chair conformation.     

Crystal structure and vibrational spectra of hydrazinium (2+) tri-μ-fluoro bis[pentafluorozirconate (IV)] fluoride and vibrational spectra of its hafnium analogue

Monoclinic (N₂H₆)₃Zr₂F₁₃·F crystallizes in space group P2₁-C ₂ ² (No. 4) with unit cell dimensionsa=5.670(1),b=10.984(2),c=10.601(2) Å,=93.88(1)°,V=658.7(4) ų andZ=2. Two different types of N₂H₆ ²⁺ ions are present. One is involved in strong H-bonds to F^– ions in infinite chains running along the a axis (the shortest N-F distance is 2.437(5) Å), and the other links the structure through weaker bi- and trifurcated H-bonds to fluorine ligands of the Zr₂F₁₃ ^5– ions. The N-N bond lengths range from 1.430(5) to 1.446(5) Å with apparently no meaningful correlation to the type of N₂H₂ ²⁺ ions. The Zr₂F₁₃ ^5– ions have very nearly C₂ point symmetry and are formed by joining two distorted bicapped trigonal prisms of ZrF₈-units through a common face. Distances of Zr-F terminal bonds range from 2.015(2) to 2.112(2) Å and of bridging bonds from 2.133(2) to 2.212(2) Å. (N₂H₆)₃Hf₂F₁₃·F is isomorphous. The vibrational spectra of the two compounds are nearly identical, with the exception of a strong infrared band, which is assigned to a stretching mode with the moving central atom within the anion. The anion part of the spectrum is simple, showing broad unresolved bands. The cation part shows two types of N₂H₆ ^– ions. H-Bonding is strongly present in the spectra, but no simple correlations with the H-bond strength is evident.     

Behavior on the real line of entire functions represented by Dirichlet series with complex exponents

It is shown, in particular, that if _{n k} when n k, Re _n > 0, and , then an entire function F that is bounded on the real line and represented by a Dirichlet series d_n exp (_nz) that is uniformly and absolutely convergent on each compactum in is identically zero.Translated from Ukrainskii Matematicheskii Zhurnal, Vol. 42, No. 7, pp. 882–888, July, 1990.     

A certain functional algebra

We study the algebra of functions on the set of natural numbers with respect to the generalized convolution, generated by the generalized translation operator T_nf(k)=f(max (n, k)), n, k. With the help of the generalized Fourier transform, connected with this convolution, we establish numerous identities and recurrence relations, connecting, in particular, sums of powers of natural numbers.Translated from Ukrainskii Matematicheskii Zhurnal, Vol. 42, No. 3, pp. 372–377, March, 1990.     

A numerical analysis of chaotic behaviour in Bianchi IX models

In this paper we investigate the chaotic behaviour of the Bianchi IX cosmological models using techniques developed in the study of dynamical systems and chaotic behaviour. We numerically calculate the Lyapunov exponent, , and show that instead of converging to a constant value, it decreases steadily. We study this effect further by studying the Lyapunov exponent using short-time averages. We show that the usual method of calculating is invalid in the case of a cosmological model.     

Random fields and quantum effects in proton glasses

The effects of quantum fluctuations on the proton glass phase in mixed hydrogen-bonded ferro-antiferroelectric systems are considered. The system is described in terms of the infinite-ranged Ising pseudospin glass model in a transverse tunneling field in the presence of random parallel fields. The stability limit of the high-temperature proton glass phase is determined within the thermofield dynamic approach, and the behavior or linear and nonlinear susceptibility is evaluated.     

Relativistically covariant chronological ordering of interaction lagrangians

A general form of chronological ordering is proposed, based on introduction of relativistically invariant multipoint step functions (x₁, ..., x_n). A system of recursive relations is established for these functions, which guarantees that the scattering matrix is unitary, covariant, and causal. The explicit form of the first four -functions is found. A comparative analysis of the known methods of chronological ordering is given.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 70–73, May, 1990.     

Excitation spectrum of anisotropic non-dissipative elastic-plastic medium

The simplest gauge theory of an elastic-plastic medium is considered in this paper that takes account of just translational plasticity. The equations of motion for such a model turn out to be linear and permit the normal modes spectrum of a medium to be obtained. Taking account of plasticity results in a cardinal transformation of the elastic branches of the spectrum and the appearance of a group of plasma oscillations of a dislocation gas.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 64–68, June, 1990.     

Upper-Branch Instability of Flow in Pipes of Large Aspect Ratio with Three-Dimensional Nonlinear Viscous Critical Layers

We consider the upper-branch neutral stability of flow in pipesof large aspect ratio, basically extending the work of F. T.Smith to the nonlinear regime. The inclusion of weak nonlinearityleads to an eigenproblem whose solution depends on the propertiesof three-dimensional nonlinear critical layers. Two specialcases are considered. The first is for very small amplitude perturbations, where R is a Reynolds numberbased on the height of the tube and which is assumed large.Then a fully analytical solution of the three-dimensional criticallayers is possible, from which the linear results of Smith maybe deduced. The second case studied is that of flow in a rectangularpipe, where a solution of the nonlinear critical layer problemcan be obtained. Further analysis of neutral modes in this lattercase suggests the possible existence, inter alia, of neutralmodes for finite aspect ratio tubes. These modes depend on thescaled amplitude and have O(1) wavespeeds.     

On the dynamics of cosmological particle production

The time evolution of the particle number density and spectrum of massive scalar particles, coupled conformally to a classical Friedman-Robertson-Walker gravitational field is followed numerically. Not only for a pure radiation cosmos, but also for one with an inflationary interlude, the density of particles produced remains constant in time. This results in a constant equivalent temperature scale up to the Compton time of the massive particles, and opens the possibility that during a sufficiently long inflation the energy density of the particles produced can exceed that of the radiation background.