Evaluation of atomic fluorescence, absorption and emission techniques for the determination of mercury

Summary Atomic fluorescence (AFS), absorption (AAS) and emission (AES) systems were evaluated for the determination of inorganic mercury. Identical vapour generation and amalgamation procedures were used to permit direct comparison of the performance of a commercial long-path AAS instrument to laboratory constructed non-dispersive AFS as well as He-MIP based AES instruments. Instrumental noise-limited detection limits (LOD) were 0.94, 2.4, 2.8 pg for AAS, AES and AFS techniques, respectively. Methodological LOD's were found to be blank controlled and similar for all three instruments, viz. 9, 25 and 16 pg for AAS, AFS and AES, respectively. All three systems produced accurate results at the low ng/l concentration, as verified by the analysis of a certified river water reference material (NRCC ORMS-1).     

Axial Structure of the Field Intensity in Diffusion-Controlled Surface-Wave Produced Plasmas

Surface-wave gas discharges sustained under the conditions of a diffusion controlled regime are studied on the basis of the fluid plasma model. The self-consistent behaviour of the plasma density and of the field intensity along the discharge length is obtained. It is shown that the nonlinearity in the particle balance equation due to stepwise ionisation determines the plasma density in terms of the field intensity and ensures self-consistent behaviour of the wave ? discharge characteristics in a diffusion controlled regime.     

Statistical approach to light scattering from deformed textured heterogeneous polymer materials

A statistical theory of light scattering from deformed isotropic and textured heterogeneous polymer materials is formulated. Two types of textured structures are analyzed: assemblies of optically isotropic and anisotropic rods and a spatially anisotropic distribution of isotropic spherical inclusion centers. The small-angle H_v light-scattering patterns are calculated. The appearance of scattering from isotropic rods and spheres in deformed materials has been demonstrated. The changes of the H_v scattering patterns as a function of elongation and strucuture parameters are discussed. © 1993 John Wiley & Sons, Inc.     

Measurement of Hartmann-Hahn cross-polarization dynamics with quenching of proton T1ρ relaxation dependence

A simple modification of the standard cross-polarization method designed for quenching the proton T_1ρ dependence when studying polarization transfer is presented. It is demonstrated that by using this simple procedure, new and subtle details of cross-polarization dynamics, previously hidden by the T_1ρ(¹H) effect, can be observed in dipolar-coupled spin systems.     

The normal form of germs of four-dimensional real submanifolds in ℂ n at generic ℝℂ-singular points

Mathematical Notes -     

Theory of mixed-polarization propagation in anisotropic cubic media

Polarization dynamics are considered in the presence of an anisotropic Kerr non-linearity in the most common semiconductor waveguide geometry. The equations of motion are formulated in terms of Stokes polarization parameters and their Hamiltonian form is derived. Stationary solutions and their stability are found for plane-wave propagation. It is found that the non-integrable problem of mixed-polarization spatial soliton dynamics can be largely explained in terms of the equivalent plane-wave solutions.     

Nuclear fusion in the mesic molecule d μ 3He

A new scheme is presented for the physical processes leading to the nuclear fusion reaction d(³He, ⁴He)p catalyzed by a negatively charged muon μ⁻. It is shown that the observable rate and yield of the nuclear reaction depend on a chain of ion-molecular reactions involving the participation of the dμ ³He molecule. New calculations of the nuclear fusion rates in the dμ³He molecule are presented. Pis’ma Zh. éksp. Teor. Fiz. 67, No. 2, 89–94 (25 January 1998) Published in English in the original Russian journal. Edited by Steve Torstveit.     

Statistical hydrodynamics of magnetic fluids. I. the nonequilibrium statistical operator method

The Zubarev nonequilibrium statistical operator is used to describe the generalized hydrodynamic state of a magnetic fluid in an external magnetic field. The magnetic fluid is modeled with “liquid-state” and “magnetic” subsystems described using the classical and quantum statistics methods respectively. Equations of the generalized statistical hydrodynamics for a magnetic fluid in a nonhomogeneous external magnetic field with the Heisenberg spin interaction are derived for “liquid-state” and “magnetic” subsystems characterized by different nonequilibrium temperatures. These equations can be used to describe both the weakly and strongly nonequilibrium states. Some limiting cases are analyzed in which the variables of one of the subsystems can be formally neglected. Translated from Teoreticheskaya i Matematicheskaya Fizika. Vol. 115, No. 1, pp. 132–153, April, 1998.     

Records in the Fα-scheme. II. Limit laws

Limit theorems for the number of records in a sequence of independent nonidentically distributed random variables are obtained. A generalization of the so-called F^α-scheme is given. Bibliography: 4 titles. Translated fromZapiski Nauchnykh Seminarov POMI, Vol. 216, 1994, pp. 42–51. Translated by A. Sudakov.