Properties of Monocarboxy Cellulose Containing Sorbed Fe(III), Al(III), and Cr(III) Cations

Sorption of Fe(III), Al(III), and Cr(III) on monocarboxy cellulose at various pH, concentrations of metal chloride or sulfate in solution, and time was studied. The effect of type and amount of the cation sorbed on the physicomechanical properties, swelling, and stability in phosphate buffer of monocarboxy cellulose fibers was considered.     

Pyrazolines — Derivatives of 2-nitrochalcone

By the reaction of 2-nitrochalcone with hydrazine hydrate, 5-(2-nitrophenyl)-3-phenyl-1H-2-pyrazoline (I) and the hydrazone of 3-(5-(2-nitrophenyl)-3-phenyl-2-pyrazolin-1-yl)-3-(2-nitrophenyl)propiophenol (II) have been prepared. The acylation of both compounds I and II leads to N-acyl derivatives of the first. The acylating ability of formamide and N,N-dimethylformamide was observed in reactions with pyrazoline I. An x-ray structural study was carried out on compound II.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 360–366, March, 1993.     

Ecdysteroids of a culture of tissues and cells ofAjuga turkestanica

The possibility has been studied of obtaining ecdysteroids — ecdysterone and turkesterone — with the aid of a culture of the tissues and cells of the plantAjuga turkestanica. Conditions have been selected under which the yield of ecdysteroids in the culture of tissues and cells is comparable with amounts of the same substances in the organs of the whole plant.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 51–52, January–February, 1990.     

Mass spectrometric study of mixed fluorinated rare earth element β-diketonates with triphenylphosphine oxide

A series of new adducts of fluorinated REE -diketonates with triphenylphosphine oxide was synthesized. The paths of their fragmentation under electron impact were investigated. It was shown that in contrast to the complex with 1,1,1,2,2,3,3-heptafluoro-7,7-dimethyloctane-4,6-dione, the complexes of europium with 1-trifluoromethoxy-1,1-difluoro-5,5-dimethylhexane-2,4-dione and 1, 1,1-trifluoro-5,5-dimethylhexane-2,4-dione form dimeric associates in the gaseous phase. The reasons for this difference in the behavior of the complexes and the possible structure of one of the dimers are discussed.Translated from Teoreticheskaya i Eksperimental'naya Khimiya, Vol. 26, No. 2, March–April, 1990.     

Mesoionic compounds with a bridge nitrogen atom. 19. Thiazolo[3,2-a]quinoxalinium oxides

(2-Quinoxalylthio)acetic acids have been found to cyclize on treatment with acetic anhydride to give the mesoionic thiazolo[3,2-a]quinoxalinium oxides. Some reactions of these compounds have been studied, and the relationship of the color of the compounds to their chemical structure examined.For Communication 18, see [1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1680–1684, December, 1989.     

The reaction of thiocaprylic acid with methyl thiocyanate

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2154–2155, September, 1989.