全文获取类型
收费全文 | 457141篇 |
免费 | 2928篇 |
国内免费 | 882篇 |
专业分类
化学 | 218102篇 |
晶体学 | 7140篇 |
力学 | 24411篇 |
综合类 | 7篇 |
数学 | 61463篇 |
物理学 | 149828篇 |
出版年
2021年 | 4078篇 |
2020年 | 4527篇 |
2019年 | 5374篇 |
2018年 | 7677篇 |
2017年 | 7812篇 |
2016年 | 10254篇 |
2015年 | 5203篇 |
2014年 | 9336篇 |
2013年 | 19210篇 |
2012年 | 15544篇 |
2011年 | 18441篇 |
2010年 | 14324篇 |
2009年 | 14405篇 |
2008年 | 17403篇 |
2007年 | 17399篇 |
2006年 | 15991篇 |
2005年 | 14085篇 |
2004年 | 13416篇 |
2003年 | 12184篇 |
2002年 | 12321篇 |
2001年 | 12813篇 |
2000年 | 10053篇 |
1999年 | 7565篇 |
1998年 | 6717篇 |
1997年 | 6566篇 |
1996年 | 5999篇 |
1995年 | 5495篇 |
1994年 | 5410篇 |
1993年 | 5299篇 |
1992年 | 5658篇 |
1991年 | 6012篇 |
1990年 | 5921篇 |
1989年 | 5708篇 |
1988年 | 5556篇 |
1987年 | 5624篇 |
1986年 | 5187篇 |
1985年 | 6338篇 |
1984年 | 6783篇 |
1983年 | 5692篇 |
1982年 | 6082篇 |
1981年 | 5750篇 |
1980年 | 5408篇 |
1979年 | 5935篇 |
1978年 | 6104篇 |
1977年 | 6195篇 |
1976年 | 6351篇 |
1975年 | 5875篇 |
1974年 | 5716篇 |
1973年 | 6002篇 |
1972年 | 4578篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
In this work, the natural convection in a concentric annulus between a cold outer square cylinder and a heated inner circular cylinder is simulated using the differential quadrature (DQ) method. The vorticity‐stream function formulation is used as the governing equation, and the coordinate transformation technique is introduced in the DQ computation. It is shown in this paper that the outer square boundary can be approximated by a super elliptic function. As a result, the coordinate transformation from the physical domain to the computational domain is set up by an analytical expression, and all the geometrical parameters can be computed exactly. Numerical results for Rayleigh numbers range from 104 to 106 and aspect ratios between 1.67 and 5.0 are presented, which are in a good agreement with available data in the literature. It is found that both the aspect ratio and the Rayleigh number are critical to the patterns of flow and thermal fields. The present study suggests that a critical aspect ratio may exist at high Rayleigh number to distinguish the flow and thermal patterns. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
12.
V. YILDIRIM 《Journal of sound and vibration》2002,252(3):479-491
Numerical and analytical studies are performed for the free vibration analysis of non-cylindrical (conical, barrel and hyperboloidal types) helical springs. The stiffness matrix method is used in the numerical analysis. A total of 12 degrees of freedom (six displacements and six rotations) is described for an element. The exact element stiffness matrix and the exact concentrated element inertia matrix are used in the formulation. The rotary inertia, the shear and extensional deformation effects are considered in the analysis. Comparison of the numerical results with the reported results obtained numerically and experimentally gives satisfactory values. After verification of the numerical frequencies, the non-dimensional fundamental frequencies of fixed-fixed non-cylindrical helical springs with circular section are expressed in a simple formula with a maximum absolute relative error of 5% using those numerical values for the constant helix pitch angles (5°, 10°, and 15°). These expressions restricted to the fundamental frequencies are also verified with ANSYS results. 相似文献
13.
LYNDA D. RODWELL EDWARD B. BARBIER CALLUM M. ROBERTS TIM R. McCLANAHAN 《Natural Resource Modeling》2002,15(4):453-486
ABSTRACT. The excessive and unsustainable exploitation of our marine resources has led to the promotion of marine reserves as a fisheries management tool. Marine reserves, areas in which fishing is restricted or prohibited, can offer opportunities for the recovery of exploited stock and fishery enhancement. In this paper we examine the contribution of fully protected tropical marine reserves to fishery enhancement by modeling marine reserve‐fishery linkages. The consequences of reserve establishment on the long‐run equilibrium fish biomass and fishery catch levels are evaluated. In contrast to earlier models this study highlights the roles of both adult (and juvenile) fish migration and larval dispersal between the reserve and fishing grounds by employing a spawner‐recruit model. Uniform larval dispersal, uniform larval retention and complete larval retention combined with zero, moderate and high fish migration scenarios are analyzed in turn. The numerical simulations are based on Mombasa Marine National Park, Kenya, a fully protected coral reef marine reserve comprising approximately 30% of former fishing grounds. Simulation results suggest that the establishment of a fully protected marine reserve will always lead to an increase in total fish biomass. If the fishery is moderately to heavily exploited, total fishery catch will be greater with the reserve in all scenarios of fish and larval movement. If the fishery faces low levels of exploitation, catches can be optimized without a reserve but with controlled fishing effort. With high fish migration from the reserve, catches are optimized with the reserve. The optimal area of the marine reserve depends on the exploitation rate in the neighboring fishing grounds. For example, if exploitation is maintained at 40%, the ‘optimal’ reserve size would be 10%. If the rate increases to 50%, then the reserve needs to be 30% of the management area in order to maximize catches. However, even in lower exploitation fisheries (below 40%), a small reserve (up to 20%) provides significantly higher gains in fish biomass than losses in catch. Marine reserves are a valuable fisheries management tool. To achieve maximum fishery benefits they should be complemented by fishing effort controls. 相似文献
14.
J. S. Chiou J. W. Barlow D. R. Paul 《Journal of Polymer Science.Polymer Physics》1987,25(7):1459-1471
The miscibility of bisphenol-A polycarbonate (PC) with poly(methyl methacrylate) (PMMA) has been reexamined using differential scanning calorimetry (DSC) and optical indications for phase separation on heating, i.e., lower critical solution temperature (LCST) behavior. Various methods have been used to prepare the blends including methylene chloride (CH2Cl2) and tetrahydrofuran (THF) solution casting, melt mixing, and precipitation of PC and PMMA simultaneously from THF solution by using the nonsolvents methanol and heptane. It is shown that the resulting phase behavior for PC/PMMA blends is strongly affected by the blend preparation method. However, these blends are miscible over the whole blend composition range (unambiguous single composition-dependent Tg's and LCST behavior) when prepared by precipitation from solution using heptane as the nonsolvent. To the contrary, solution-cast and melt-mixed PC/PMMA blends were all phase separated, which may be attributed to the “solvent” effect and LCST behavior, respectively, not discovered in previous reports. Methanol precipitation does not lead to fully mixed blends, which demonstrates the importance of the choice of nonsolvent when using the precipitation method. 相似文献
15.
The purpose of this paper is to investigate problems of the Navier-Stokes approximation to kinetic equations in terms of the
so-called Chapman-Enskog projection. One considers properties of the Chapman-Enskog projection for the Cauchy problem for
moment approximations of the kinetic equation and primarily the Chapman-Enskog projection for the Boltzmann-Peierls kinetic
equation. The existence of the Chapman-Enskog projection for the Cauchy problem is proved for the phase space of conservative
variables (phenomena of nonlinear diffusion) and for the phase space of physical variables (the second sound projection).
__________
Translated from Trudy Seminara imeni I. G. Petrovskogo, No. 25, pp. 184–225, 2005. 相似文献
16.
I. J. Lozada J. C. Osorio D. V. Griffiths M. Cerrolaza 《Numerical Methods for Partial Differential Equations》2006,22(2):296-316
The semi‐analytical integration of an 8‐node plane strain finite element stiffness matrix is presented in this work. The element is assumed to be super‐parametric, having straight sides. Before carrying out the integration, the integral expressions are classified into several groups, thus avoiding duplication of calculations. Symbolic manipulation and integration is used to obtain the basic formulae to evaluate the stiffness matrix. Then, the resulting expressions are postprocessed, optimized, and simplified in order to reduce the computation time. Maple symbolic‐manipulation software was used to generate the closed expressions and to develop the corresponding Fortran code. Comparisons between semi‐analytical integration and numerical integration were made. It was demonstrated that semi‐analytical integration required less CPU time than conventional numerical integration (using Gaussian‐Legendre quadrature) to obtain the stiffness matrix. © 2005 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2006 相似文献
17.
Nonlinear Theory of Spectra of Thermally Stimulated Currents in Complex Crystals with Hydrogen Bonds
Tonkonogov M. P. Ismailov Zh. T. Timokhin V. M. Fazylov K. K. Kalitka V. A. Baimukhanov Z. K. 《Russian Physics Journal》2002,45(10):1008-1018
The nonlinear theory of thermally stimulated depolarization currents is developed. The theory explains the processes of hetero- and homocharge relaxation in complex crystals with hydrogen bonds and allows the relaxation oscillator parameters to be calculated using the quadratic approximation for the external electric field. 相似文献
18.
The results of experimental investigations on thermal nonequilibrium ionization in CO2: N2: He mixtures are presented. Measurements of electron density, ne, in vibrationally excited nitrogen were made in a supersonic flow with different CO2 contents as well as in a CO2: N2: He = 1 : 5 : 4 mixture laser gas. The mixtures were heated in a shock tube and expanded through a supersonic nozzle. Furthermore, supersonic mixing of N2 and CO2 + He was used in some experiments. The measured values of ne in the plenum chamber and in the supersonic nozzle are reported, and the processes responsible for nonequilibrium ionization in a laser-active medium are discussed. 相似文献
19.
P. R. Latthe P. S. Shinge Bharati V. Badami P. B. Patil S. N. Holihosur 《Journal of Chemical Sciences》2006,118(3):249-256
3-[4-(Azidocarbonyl)]phenylsydnone (2) obtained from 3-(4-hydrazinocarbonyl) phenylsydnone (1) on Curtius rearrangement with alcohols, water and amines afforded the corresponding carbamates (3a-h), 4,4′-(sydnone-3-yl) diphenyl urea (4) and 4-(heterocyclyl)phenyl ureas (5a-l). Compounds (5a-l) on one-pot ring conversion yielded the 1,3,4-oxadiazolin-2-one derivatives (6a-l), which on reaction with N2H4 gave the 4-amino-1,2,4-triazolin-3-ones (7a-l). All these compounds exhibited moderate antimicrobial activity against the few microbes tested. The carbamates have been
found to be more toxic against fourth instar larvae ofAedes aegypti, in particular, then-butyl derivative (3e). 相似文献
20.
Summary Using a saturated non-boiling hydrocarbon mixture, the influence of two parameters on the results of field ionization mass spectrometry (FI-MS) measurements was studied: (a) the potential difference between the FI emitter and the counterelectrode; (b) the emitter temperature.Variation of the potential difference had only a minor effect on the average molecular mass measured and had no evident effect on the relative ring number distribution in the sample. In contrast, when the emitter temperature was increased, higher average molecular masses were recorded. Moreover, the average molecular masses shifted to higher ring numbers. In order to control the relationship between the described influences during mixture analysis, measuring instructions have been developed that enable the quantitative analysis of unknown saturated samples. However, average molecular mass of the mixture must be known.
Entwicklung einer quantitativen FI-MS-Methode zur Charakterisierung von gesättigten hoch- und nichtsiedenden Kohlenwasserstoffgemischen相似文献