Kinetic Instability of Anisotropic Drift Wave Accompanied by Field Aligned Currents in Solar Coronal Loop

Solar coronal loops are frequently accompanied by the field-aligned currents, which drive instabilities if the drift velocity u₀> v_A the Alfvén velocity. For our choice of parameters, the critical threshold value of u₀/v_A is~3.0 for growth and the corresponding current filling factor~10^-3-10^-4. Below this value we are no longer in the kinetic regime. The coronal loops also have short-scale density gradients within each loop. The electron resonance in the presence of density gradient causes the drift mode to grow. We study the effect of these two free energy sources, the electron drift and the density gradient, in the presence of temperature anisotropy T_⊥α > T_||α. These effects simultaneously exist in the coronae. Using gyrokinetic theory, we investigate the influence of these effects, examine how they interplay with each other and study the consequent growth of the magnetosonic wave. We observe that kinetic instability driven by density gradient can be suppressed by field-aligned currents. The temperature anisotropy with chosen signatures causes further stabilizing effect. The results may prove useful to study the heating mechanism of solar coronal loops, acceleration of particles and confinement of particles in the thermonuclear reactors.     

New Correlative Models to Improve Prediction of Fracture Permeability and Inertial Resistance Coefficient

Presence of fracture roughness and occurrence of nonlinear flow complicate fluid flow through rock fractures. This paper presents a qualitative and quantitative study on the effects of fracture wall surface roughness on flow behavior using direct flow simulation on artificial fractures. Previous studies have highlighted the importance of roughness on linear and nonlinear flow through rock fractures. Therefore, considering fracture roughness to propose models for the linear and nonlinear flow parameters seems to be necessary. In the current report, lattice Boltzmann method is used to numerically simulate fluid flow through different fracture realizations. Flow simulations are conducted over a wide range of pressure gradients through each fracture. It is observed that creeping flow at lower pressure gradients can be described using Darcy’s law, while transition to inertial flow occurs at higher pressure gradients. By detecting the onset of inertial flow and regression analysis on the simulation results with Forchheimer equation, inertial resistance coefficients are determined for each fracture. Fracture permeability values are also determined from Darcy flow as well. According to simulation results through different fractures, two parametric expressions are proposed for permeability and inertial resistance coefficient. The proposed models are validated using 3D numerical simulations and experimental results. The results obtained from these two proposed models are further compared with those obtained from the conventional models. The calculated average absolute relative errors and correlation coefficients indicate that the proposed models, despite their simplicity, present acceptable outcomes; the models are also more accurate compared to the available methods in the literature.     

Synthesis,in vitro $$\alpha $$-glucosidase inhibitory activity,and in silico study of ( E)-thiosemicarbazones and ( E)-2-(2-(arylmethylene)hydrazinyl)-4-arylthiazole derivatives

This study is focused on the identification of thiazole-based inhibitors for the \(\alpha \)-glucosidase enzyme. For that purpose, (E)-2-(2-(arylmethylene)hydrazinyl)-4-arylthiazole derivatives were synthesized in two steps and characterized by various spectroscopic techniques. All derivatives and intermediates were evaluated for their in vitro \(\alpha \)-glucosidase inhibitory activity. Thiosemicarbazones 20 and 35, and cyclized thiazole derivatives 2, 5–11, 13, 15, 21–24, 27–31, and 36–37 showed significant inhibitory potential in the range of \(\hbox {IC}_{50}=6.2\pm 0.19\)–\(43.6\pm 0.23~\upmu \hbox {M}\) as compared to standard acarbose (\(\hbox {IC}_{50}=37.7\pm 0.19~\upmu \hbox {M}\)). A molecular modeling study was carried out to understand the binding interactions of compounds with the active site of enzyme.     

Group preserving scheme and reproducing kernel method for the Poisson–Boltzmann equation for semiconductor devices

This paper introduces that the nonlinear Poisson–Boltzmann equation for semiconductor devices describing potential distribution in a double-gate metal oxide semiconductor field effect transistor (DG-MOSFET) is exactly solvable. The DG-MOSFET shows one of the most advanced device structures in semiconductor technology and is a primary focus of modeling efforts in the semiconductor industry. Lie symmetry properties of this model is investigated in order to extract some exact solutions. The reproducing kernel Hilbert space method and group preserving scheme also have been applied to the nonlinear equation. Numerical results show that the present methods are very effective.

     

Hydrodynamic analysis of electrostatic counter-streaming instability in a spin-polarized electron–positron–ion plasma

In this study, we present linear analysis of electrostatic counter-streaming instability in spin-polarized electron–positron–ion (e-p-i) plasma. With the aid of the separate spin evolution-quantum hydrodynamic (SSE-QHD) model, we derive the dispersion relation of counter-streaming instability. We numerically solve the dispersion and find four wave solutions: Langmuir wave, positron acoustic mode, and two electron and positron spin-dependent waves. It is noted that coupling of streaming and spin effects excites Langmuir instability and positron acoustic mode instability. However, in the absence of spin effect, only Langmuir instability will survive in e-p-i plasma. We have also discussed the effects of positron concentration, streaming speed, and spin polarization on the real frequency of waves and the growth rate. The present study may be helpful for understanding longitudinal wave propagation and instabilities in dense magnetized environments.     

Thermally stratified flow of hybrid nanofluids with radiative heat transport and slip mechanism: multiple solutions

Research on flow and heat transfer of hybrid nanofluids has gained great significance due to their efficient heat transfer capabilities.In fact,hybrid nanofluids are a novel type of fluid designed to enhance heat transfer rate and have a wide range of engineering and industrial applications.Motivated by this evolution,a theoretical analysis is performed to explore the flow and heat transport characteristics of Cu/Al₂O₃ hybrid nanofluids driven by a stretching/shrinking geometry.Further,this work focuses on the physical impacts of thermal stratification as well as thermal radiation during hybrid nanofluid flow in the presence of a velocity slip mechanism.The mathematical modelling incorporates the basic conservation laws and Boussinesq approximations.This formulation gives a system of governing partial differential equations which are later reduced into ordinary differential equations via dimensionless variables.An efficient numerical solver,known as bvp4c in MATLAB,is utilized to acquire multiple(upper and lower)numerical solutions in the case of shrinking flow.The computed results are presented in the form of flow and temperature fields.The most significant findings acquired from the current study suggest that multiple solutions exist only in the case of a shrinking surface until a critical/turning point.Moreover,solutions are unavailable beyond this turning point,indicating flow separation.It is found that the fluid temperature has been impressively enhanced by a higher nanoparticle volume fraction for both solutions.On the other hand,the outcomes disclose that the wall shear stress is reduced with higher magnetic field in the case of the second solution.The simulation outcomes are in excellent agreement with earlier research,with a relative error of less than 1%.     

Biodiesel Production from Alkali-Catalyzed Transesterification of Tamarindus indica Seed Oil and Optimization of Process Conditions

Biodiesel is considered a sustainable alternative to petro-diesel owing to several favorable characteristics. However, higher production costs, primarily due to the use of costly edible oils as raw materials, are a chief impediment to its pecuniary feasibility. Exploring non-edible oils as raw material for biodiesel is an attractive strategy that would address the economic constraints associated with biodiesel production. This research aims to optimize the reaction conditions for the production of biodiesel through an alkali-catalyzed transesterification of Tamarindus indica seed oil. The Taguchi method was applied to optimize performance parameters such as alcohol-to-oil molar ratio, catalyst amount, and reaction time. The fatty acid content of both oil and biodiesel was determined using gas chromatography. The optimized conditions of alcohol-to-oil molar ratio (6:1), catalyst (1.5% w/w), and reaction time 1 h afforded biodiesel with 93.5% yield. The most considerable contribution came from the molar ratio of alcohol to oil (75.9%) followed by the amount of catalyst (20.7%). In another case, alcohol to oil molar ratio (9:1), catalyst (1.5% w/w) and reaction time 1.5 h afforded biodiesel 82.5% yield. The fuel properties of Tamarindus indica methyl esters produced under ideal conditions were within ASTM D6751 biodiesel specified limits. Findings of the study indicate that Tamarindus indica may be chosen as a prospective and viable option for large-scale production of biodiesel, making it a substitute for petro-diesel.     

Semiconductor nanoparticles for photoinitiation of free radical polymerization in aqueous and organic media

Photoinduced free radical polymerization of vinyl monomers by using semiconductor inorganic nanoparticles (NPs) is investigated. Zinc oxide and iron‐doped zinc oxide were used as photosensitive compounds to initiate the polymerization of acrylamide as a water‐soluble monomer in aqueous environment and methyl methacrylate as an oil‐soluble monomer in organic media under UV‐light irradiation. The method uses photochemically generated electrons and holes from the NPs to form initiating hydroxyl radicals in aqueous media, while tertiary amines and iodonium salt served as coinitiator in organic media. The initiation mechanism in organic media involves hydrogen abstraction or reduction processes via charge carriers, respectively. The kinetic of the polymerization in both environments was studied by means of a photo‐differential scanning calorimetry. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 1500–1507     

Synthesis, gas-phase photoelectron spectroscopic, and theoretical studies of stannylated dinuclear iron dithiolates

Stannylated dinuclear iron dithiolates (mu-SSnMe(2)CH(2)S)[Fe(CO)(3)](2), (mu-SCH(2)SnMe(2)CH(2)S) [Fe(CO)(3)](2), and (mu-SCH(2)SnMe(3))(2)[Fe(CO)(3)](2), which are structurally similar to the active site of iron-only hydrogenase, were synthesized and studied by gas-phase photoelectron spectroscopy. The orbital origins of ionizations were assigned by comparison of He I and He II photoelectron spectra and with the aid of hybrid density functional electronic structure calculations. Stannylation lowers the ionization energy of sulfur lone pair orbitals in these systems owing to a geometry-dependent interaction. The Fe-Fe sigma bond, which is the HOMO in all these systems, is also substantially destabilized by stannylation due to a previously unrecognized geometry-dependent interaction between axial sulfur lone pair orbitals and the Fe-Fe sigma bond. Since cleaving the Fe-Fe sigma bond is a key step in the mechanism of action of iron-only hydrogenase, these newly recognized geometry-dependent interactions may be utilized in designing biologically inspired hydrogenase catalysts.