全文获取类型
收费全文 | 2467篇 |
免费 | 100篇 |
国内免费 | 22篇 |
专业分类
化学 | 1803篇 |
晶体学 | 26篇 |
力学 | 112篇 |
综合类 | 3篇 |
数学 | 273篇 |
物理学 | 372篇 |
出版年
2024年 | 6篇 |
2023年 | 18篇 |
2022年 | 162篇 |
2021年 | 111篇 |
2020年 | 64篇 |
2019年 | 73篇 |
2018年 | 66篇 |
2017年 | 55篇 |
2016年 | 96篇 |
2015年 | 83篇 |
2014年 | 92篇 |
2013年 | 218篇 |
2012年 | 161篇 |
2011年 | 167篇 |
2010年 | 96篇 |
2009年 | 92篇 |
2008年 | 92篇 |
2007年 | 93篇 |
2006年 | 82篇 |
2005年 | 65篇 |
2004年 | 60篇 |
2003年 | 58篇 |
2002年 | 64篇 |
2001年 | 42篇 |
2000年 | 48篇 |
1999年 | 20篇 |
1998年 | 23篇 |
1997年 | 17篇 |
1996年 | 26篇 |
1995年 | 21篇 |
1994年 | 23篇 |
1993年 | 11篇 |
1992年 | 14篇 |
1991年 | 19篇 |
1990年 | 14篇 |
1989年 | 17篇 |
1988年 | 11篇 |
1987年 | 16篇 |
1986年 | 12篇 |
1985年 | 22篇 |
1984年 | 20篇 |
1983年 | 19篇 |
1982年 | 17篇 |
1981年 | 13篇 |
1980年 | 11篇 |
1979年 | 8篇 |
1978年 | 6篇 |
1977年 | 9篇 |
1975年 | 9篇 |
1973年 | 5篇 |
排序方式: 共有2589条查询结果,搜索用时 15 毫秒
51.
A. Jeyabharathi M. N. Ponnuswamy S. Nanjundan Hoong‐Kun Fun Suchada Chantrapromma Anwar Usman Ibrahim Abdul Razak 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(1):o26-o28
Chalcones (α,β‐unsaturated ketones) are effective antitumour agents. It has been proved that having halogen or methoxy groups substituted in various positions of the phenyl ring enhances the activity of chalcones many times. The title compounds, C21H20O5 and C19H15BrO3, respectively, were chosen for crystallographic study in order to determine their structures and conformations. In both compounds, the keto group is in the s‐cis conformation and is almost planar. There are weak intramolecular interactions in both structures. 相似文献
52.
Talaat Ibrahim El‐Emary 《中国化学会会志》2006,53(2):391-401
New derivatives of pyrazolo[3,4‐b]pyrazine and related heterocycles were prepared starting from 6‐amino‐3‐methyl‐1‐phenyl‐1H‐pyrazolo[3,4‐b]pyrazine‐5‐carbonitrile ( 2 ) and using the key intermediates 4 , 5 , 6 , 14 , 15 and 16 . Some of the prepared compounds were evaluated for their antifungal and antibacterial activities. 相似文献
53.
INTRODUCTION Epoxy resins are reactive polymers which when cured with a variety of chemicals lead to a host of useful thermosets. Since the epoxide is a strained ring, it readily undergoes addition and homopolymerization. The homopolymerization is a process catalysed by acids, bases, Lewis acids, t-amines as well as by inorganic salts. 相似文献
54.
3-[1′(1′H)-Substituent-pyrazol-5′-yl]benzo[5,6]coumarins and 3-(1′,2′-oxazol-5′-yl)benzo[5,6]coumarin were prepared via condensation of 3-(2′-formyl-1′-chlorovinyl)benzo[5,6] coumarin with hydrazine derivatives or hydroxylamine.Reaction of 3-[1′(1′H)-pyrazol-5′-yl]benzo[5,6]coumarin with alkyl halides,olefinic compunds or acid chlorides are described. 相似文献
55.
Jia‐Xiang Yang Yu‐Peng Tian Qing‐Liang Liu Yong‐Shu Xie Hoong‐Kun Fun Suchada Chantrapromma Ibrahim Abdul Razak 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(1):m43-m44
In the title compound, [Fe(C5H5)(C16H12N3OS)], the 8‐aminoquinoline and acylthiourea moieties are almost planar. There are two perpendicular arrangements of the molecules in the crystal with slightly different conformations. The two cyclopentadienyl rings in each molecule are parallel and eclipsed. 相似文献
56.
ViqarUddin Ahmad MuhammadAthar Abbasi Muhammad Zubair Naheed Fatima Umar Farooq M.Iqbal Choudhary 《Helvetica chimica acta》2004,87(1):67-72
Phytochemical investigation of Symplocos racemosa resulted in the isolation of two new glycosides, symploracemoside ( 1 ) and symplomoside ( 2 ), which are structurally related to the reported benzoylsalireposide ( 3 ) and salireposide ( 4 ). The structure elucidation of the isolated compounds was based primarily on 1D‐ and 2D‐NMR analysis, including COSY, NOESY, HMQC, and HMBC correlations. These glycosides showed inhibitory activity against snake‐venom phosphodiesterase I. 相似文献
57.
We report experimentally measured cross sections for pressure broadening of ammonia inversion transitions by J=0, ortho-D2 at temperatures of 18-40 K. These measurements were made in a quasiequilibrium cell using the collisional cooling technique. Cross sections for broadening of the metastable (J,K)=(1, 1), (2, 2) and (3, 3) inversion transitions ranged from 67.5 A2 for (1, 1) at 20.0 K to 100.1 A2 for (3, 3) at 25.0 K. The J=0, ortho-D2 cross sections were found to be consistently larger than previously measured cross sections for low temperature broadening of NH3 by both He and H2. 相似文献
58.
Ayoko Godwin Adefikayo Iyun Johnson Femi El-Idris Ibrahim Faskari 《Transition Metal Chemistry》1992,17(1):46-49
Transition Metal Chemistry - The kinetics of the silver(I) ion catalysed reduction of peroxodisulphate by 12-tungstocobaltate(II) anion in aqueous HC1O4 has been studied. Although the reaction in... 相似文献
59.
Mohamed M. Shoukry Ibrahim M. Kenawy Ibrahim H. El-Haj 《Transition Metal Chemistry》1991,16(6):637-640
Summary The formation and equilibria of the binary and ternary palladium(II) complexes of diethylenetriamine (dien) with other selected amines have been investigated. The results of pH titration measurements allowed the calculation of equilibrium constants, characteristic for the binary and ternary complexes formed. The concentration distribution of various complex species was evaluated and the chelation mode ascertained by conductivity measurements. 相似文献
60.
The ionization of six compounds of bis-phenolic amides was studied spectrophotochemically in DMF-water mixture. The compounds showed two pKa values in the range of 5.97-7.32 for pKa1 and 7.61-8.44 for pKa2. The obtained values of Ka were normalized using the distribution diagrams of the different species and found to be in the range of 5.81-7.42 for pKa1 and 7.48-8.27 for pKa2. 相似文献