Some Aspects of Time-Reversal in Chemical Kinetics

Chemical kinetics govern the dynamics of chemical systems leading towards chemical equilibrium. There are several general properties of the dynamics of chemical reactions such as the existence of disparate time scales and the fact that most time scales are dissipative. This causes a transient relaxation to lower dimensional attracting manifolds in composition space. In this work, we discuss this behavior and investigate how a time reversal effects this behavior. For this, both macroscopic chemical systems as well as microscopic chemical systems (elementary reactions) are considered.     

The Width-Volume Inequality

We prove that a bounded open set U in has k-width less than C(n) Volume(U) ^k/n . Using this estimate, we give lower bounds for the k-dilation of degree 1 maps between certain domains in . In particular, we estimate the smallest (n – 1)-dilation of any degree 1 map between two n-dimensional rectangles. For any pair of rectangles, our estimate is accurate up to a dimensional constant C(n). We give examples in which the (n – 1)-dilation of the linear map is bigger than the optimal value by an arbitrarily large factor. Received: January 2006, Revision: May 2006, Accepted: June 2006     

Entanglement dynamics of coupled qubits and a semi-decoherence free subspace

We study the entanglement dynamics and relaxation properties of a system of two interacting qubits in the cases of (I) two independent bosonic baths and (II) one common bath. We find that in the case (II) the existence of a decoherence-free subspace (DFS) makes entanglement dynamics very rich. We show that when the system is initially in a state with a component in the DFS the relaxation time is surprisingly long, showing the existence of semi-decoherence free subspaces.     

Flow equations for the relevant part of the pure Yang—Mills action

Wilson’s exact renormalization group equations are derived and integrated for the relevant part of the pure Yang-Mills action. We discuss in detail how modified Slavnov—Taylor identities control the breaking of BRST invariance in the presence of a finite infrared cutoff k through relations among different parameters in the effective action. In particular they imply a nonvanishing gluon mass term for nonvanishing k. The requirement of consistency between the renormalization group flow and the modified Slavnov—Taylor identities allows to control the self—consistency of truncations of the effective action.     

Flight gate scheduling with respect to a reference schedule

This paper considers the problem of assigning flights to airport gates. We examine the general case in which an aircraft serving a flight may be assigned to different gates for arrival and departure processing and for optional intermediate parking. Restrictions to this assignment include gate closures and shadow restrictions, i.e., the situation where certain gate assignments may cause blocking of neighboring gates. The objectives include maximization of the total assignment preference score, a minimal number of unassigned flights during overload periods, minimization of the number of tows, maximization of a robustness measure as well as a minimal deviation from a given reference schedule. We show that in case of a one period time horizon this objective can easily be integrated into our existing model based on the Clique Partitioning Problem. Furthermore we present a heuristic algorithm to solve the problem for multiple periods.     

On quantitative versions of theorems due to F.E. Browder and R. Wittmann

This paper is another case study in the program of logically analyzing proofs to extract new (typically effective) information (‘proof mining’). We extract explicit uniform rates of metastability (in the sense of T. Tao) from two ineffective proofs of a classical theorem of F.E. Browder on the convergence of approximants to fixed points of nonexpansive mappings as well as from a proof of a theorem of R. Wittmann which can be viewed as a nonlinear extension of the mean ergodic theorem. The first rate is extracted from Browder's original proof that is based on an application of weak sequential compactness (in addition to a projection argument). Wittmann's proof follows a similar line of reasoning and we adapt our analysis of Browder's proof to get a quantitative version of Wittmann's theorem as well. In both cases one also obtains totally elementary proofs (even for the strengthened quantitative forms) of these theorems that neither use weak compactness nor the existence of projections anymore. In this way, the present article also discusses general features of extracting effective information from proofs based on weak compactness. We then extract another rate of metastability (of similar nature) from an alternative proof of Browder's theorem essentially due to Halpern that already avoids any use of weak compactness. The paper is concluded by general remarks concerning the logical analysis of proofs based on weak compactness as well as a quantitative form of the so-called demiclosedness principle. In a subsequent paper these results will be utilized in a quantitative analysis of Baillon's nonlinear ergodic theorem.     

Lattice triangulations of $\mathbb{E}^3 $ and of the 3-torus

This paper gives answers to a few questions concerning tilings of Euclidean spaces where the tiles are topological simplices with curvilinear edges. We investigate lattice triangulations of Euclidean 3-space in the sense that the vertices form a lattice of rank 3 and such that the triangulation is invariant under all translations of that lattice. This is the dual concept of a primitive lattice tiling where the tiles are not assumed to be Euclidean polyhedra but only topological polyhedra. In 3-space there is a unique standard lattice triangulation by Euclidean tetrahedra (and with straight edges) but there are infinitely many non-standard lattice triangulations where the tetrahedra necessarily have certain curvilinear edges. From the view-point of Discrete Differential Geometry this tells us that there are such triangulations of 3-space which do not carry any flat discrete metric which is equivariant under the lattice. Furthermore, we investigate lattice triangulations of the 3-dimensional torus as quotients by a sublattice. The standard triangulation admits such quotients with any number n ≥ 15 of vertices. The unique one with 15 vertices is neighborly, i.e., any two vertices are joined by an edge. It turns out that for any odd n ≥ 17 there is an n-vertex neighborly triangulation of the 3-torus as a quotient of a certain non-standard lattice triangulation. Combinatorially, one can obtain these neighborly 3-tori as slight modifications of the boundary complexes of the cyclic 4-polytopes. As a kind of combinatorial surgery, this is an interesting construction by itself.     

Ultrafast transverse thermoelectric response in c‐axis inclined epitaxial La0.5Sr0.5CoO3 thin films

Ultrafast transverse thermoelectric voltage response has been observed in c‐axis inclined epitaxial La_0.5Sr_0.5CoO₃thin films. Voltage signals with the rise time of 7 ns have been detected under the irradiation of pulse laser with duration of 28 ns. A concept, named response rate ratio, has been proposed to evaluate the intrinsic response rate, and this ratio in La_0.5Sr_0.5CoO₃is smaller than that in other reported materials. The low resistivity is thought to be responsible for the ultrafast response, as low resistivity induces small optical penetration depth, and response time has a monotonous increasing relationship with this depth.

     

Optimal control of single-server queueing networks

A general single-server queueing network model is considered. It is well-known that an optimal policy is determined by the largest-index policy. There is an index for each given queue and one allocates the server to a queue with largest current index. Using discounted dynamic programming we give a new and short proof of this result and derive some characterizations and bounds of the indices. Moreover, it is shown that an approximate largest-index policy yields an approximately optimal policy. These results lead to efficient methods for computing the indices. In particular, we present a general largest-remaining-index method.