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61.
We report a simple method for synthesis of 4-hydroxy 6-methyl 3-β-arylpropionyl 2-pyrones 1 from 3-cinnamoyl 4-hydroxy 6-methyl 2-pyrones by selective hydrogenation at ambient temperature under pressure using 10% palladium on carbon as catalyst. 相似文献
62.
Julia Rebholz Peter Bonanati Udo Weimar Nicolae Barsan 《Analytical and bioanalytical chemistry》2014,406(16):3977-3983
A model for sensing with semiconducting metal oxide (SMOX)-based gas sensors was developed which takes the effect of the shape of the grains in the sensing layers into account. Its validity is limited to materials in which the grains of the SMOX sensing layer are large enough to have an undepleted bulk region (large grains). This means that in all experimental conditions, the SMOX properties ensure that the influence of surface phenomena is not extended to the whole grain. The model takes the surface chemistry and its impact on the electrical properties of the sensing material into consideration. In this way, it relates the sensor signal—defined as the relative change of the sensor’s conductance—directly to the concentration of the target gas and also exhibits meaningful chemical parameters, such as the type of reactive oxygen species, the reaction constants, and the concentration of adsorption sites. The validity of the model is confirmed experimentally by applying it to data gathered by measuring homemade sensors in relevant conditions. 相似文献
63.
64.
Mingming Huang Dr. Jiefeng Hu Shasha Shi Dr. Alexandra Friedrich Johannes Krebs Prof. Dr. Stephen A. Westcott Prof. Dr. Udo Radius Prof. Dr. Todd B. Marder 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(24):e202200480
Defunctionalization of readily available feedstocks to provide alkenes for the synthesis of multifunctional molecules represents an extremely useful process in organic synthesis. Herein, we describe a transition metal-free, simple and efficient strategy to access alkyl 1,2-bis(boronate esters) via regio- and diastereoselective diboration of secondary and tertiary alkyl halides (Br, Cl, I), tosylates, and alcohols. Control experiments demonstrated that the key to this high reactivity and selectivity is the addition of a combination of potassium iodide and N,N-dimethylacetamide (DMA). The practicality and industrial potential of this transformation are demonstrated by its operational simplicity, wide functional group tolerance, and the late-stage modification of complex molecules. From a drug discovery perspective, this synthetic method offers control of the position of diversification and diastereoselectivity in complex ring scaffolds, which would be especially useful in a lead optimization program. 相似文献
65.
Comparison of Electrochemical Oxidation of Flavonols and Calculated Proton Affinity and Electron Transfer Enthalpy in Water 下载免费PDF全文
Flavonols, a class of flavonoids, are present in flowers, fruits and vegetables. They are jointly responsible for antioxidant activity as free radical acceptors. The redox behaviour of myricetin, quercetin, isorhamnetin, fisetin, morin and kaempferol is investigated using cyclic and differential pulse voltammetry. Quantum chemical calculations of proton affinities and electron transfer enthalpies were performed to identify possible reactive sites and radical species to compare them with measured oxidation potentials of the flavonols. Regarding to their chemical structure, these flavonols showed an oxidation order: myricetin > quercetin > isorhamnetin > fisetin > morin > kaempferol. 相似文献
66.
C,C‐ and N,C‐Coupled Dimers of 2‐Aminotetraphenylporphyrins: Regiocontrolled Synthesis,Spectroscopic Properties,and Quantum‐Chemical Calculations 下载免费PDF全文
Dr. Torsten Bruhn Dipl.‐Chem. Franziska Witterauf Dr. Daniel C. G. Götz Carina T. Grimmer Dipl.‐Chem. Max Würtemberger Prof. Dr. Udo Radius Prof. Dr. Gerhard Bringmann 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(14):3998-4006
β,β′‐Bisporphyrins are intrinsically chiral porphyrin dimers with fascinating properties. The configurational stability at their axes can be directed by variation of the central metal atoms. Herein, we present a regioselective functionalization of the monomeric 2‐amino‐tetraphenyl‐porphyrin as a versatile substrate for dimerization by oxidative coupling. By simple variation of the reaction conditions (solvent and oxidant), the oxidation selectively gave either the axially chiral C,C‐coupled diaminobisporphyrin in high yields or, under Ullmann conditions, the twofold N,C‐linked achiral dimer, also in good yields. A generalized mechanism for the coupling reaction is proposed based on DFT calculations. The axially chiral β,β′‐coupled porphyrin dimers were isolated as racemic mixtures, but can be resolved by HPLC on a chiral phase. TDDFT and coupled‐cluster calculations were used to explain the spectroscopic properties of the aminoporphyrins and their dimers and to elucidate the absolute configurations of the C,C‐coupled bisporphyrins. 相似文献
67.
Francis R. Costa Sudip Pradhan Udo Wagenknecht Anil K. Bhowmick Gert Heinrich 《Journal of Polymer Science.Polymer Physics》2010,48(22):2302-2311
In elastomer/organo clay nanocomposites, the morphological characteristics, and hence the mechanical properties, of the vulcanizates are strongly influenced by the organic modifier and the vulcanization process. When the elastomer itself undergoes strain‐induced crystallization, both the organic modifier and the dispersed filler particles could significantly influence the crystallization process. These phenomena are very common in case of natural rubber‐based vulcanizates. In this study, the similar effects have been demonstrated with carboxylated nitrile rubber (XNBR) and organically modified layered double hydroxide (O‐LDH)‐based nanocomposites. The effect of size of the organic modifier was obviously visible on the interlayer distance of O‐LDH and also on the morphological reorganization of the dispersed O‐LDH particles during vulcanization process. The strain‐induced crystallization of the XNBR was found to be strongly dependent on the morphological change that occurs during vulcanization process. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2010 相似文献
68.
Francis E. Burstall Udo Hertrich-Jeromin Wayne Rossman 《Comptes Rendus Mathematique》2010,348(11-12):661-664
We propose a Lie geometric point of view on flat fronts in hyperbolic space as special Ω-surfaces and discuss the Lie geometric deformation of flat fronts. 相似文献
69.
Diode-pumped passively mode-locked Nd:YAG laser with 10-W average power in a diffraction-limited beam 总被引:2,自引:0,他引:2
Spühler GJ Paschotta R Keller U Moser M Dymott MJ Kopf D Meyer J Weingarten KJ Kmetec JD Alexander J Truong G 《Optics letters》1999,24(8):528-530
We present a passively mode-locked Nd:YAG laser with 10.7-W average output power in a diffraction-limited beam. Stable self-starting mode locking with a pulse duration of 16 ps and a pulse energy of 120 nJ is obtained with a semiconductor saturable-absorber mirror. The laser is directly side pumped with two 20-W diode bars. Single-pass frequency doubling in an external 5-mm-thick KTP crystal yields 3.2-W average power at 532 nm. 相似文献
70.
Udo Mayer 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》1972,84(4):176-176