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101.
The synthesis of a specific isotopomer, C6D4H(ortho)-H(ortho)D4C6 of biphenyl is reported. The intramolecular dipolar coupling of the protons leads to a well-resolved single-crystal proton
nuclear magnetic resonance (NMR) spectrum and allows one to study the dynamics of the phenyl rings in a unique way. At room
temperature and above, the most conspicuous dynamical mode consists of 180° ring flips. The present data together with previous
measurements of the total flip rate allow us to conclude that the rings flip almost exclusively independently of each other.
Between the incommensurate (IC) phase transition of biphenyl at 38 K andT=250 K, the prominent namical mode consists of oscillatory twists ϕ(t) of the two rings. The data allow us to infer the mean square, (φ2), of these twists. (φ2) is found to grow linearly withT for 50<T<200 K. From the slope of (φ2) vs.T the frequency (the wave number[(v)\tilde]\tilde v) is derived. The result is[(v)\tilde] = 20\tilde v = 20 cm−1. ForT<38 K, the spectra give direct evidence of the IC phase transition and its nature (stripelike rather than quiltlike). The
temperature dependence of the magnitude of the order parameter of the IC phase is obtained. 相似文献
102.
Yu. Kh. Vekilov E. I. Isaev A. V. Godoniuk 《Journal of Experimental and Theoretical Physics》2003,97(5):1005-1009
The electronic spectrum of the three-dimensional Penrose lattice with “central” decoration by atoms is investigated using the tight binding model with nearest-neighbor interaction. Inverse participation ratios, higher moments of density probabilities, and fractal dimensions of the system are determined. The WFs are critical (they have a power-law dependence on the distance) at all energies in the band and are multifractal measures leading to the entire spectrum of the exponents. The results show that the system is in the critical state of the metal-insulator transition. On critical WFs, the cubic root temperature dependence of the conductivity is obtained. 相似文献
103.
B. G. Tagiev U. F. Kasumov N. N. Musaeva R. B. Dzhabbarov 《Physics of the Solid State》2003,45(3):426-432
The current-voltage characteristics of Ca4Ga2S7: Eu3+ single crystals are measured for the first time, and the processes affecting these characteristics are analyzed theoretically. It is demonstrated that Ca4Ga2S7: Eu3+ single crystals are high-resistance semiconductors with a resistivity of ~109 Ω cm and a relative permittivity of 10.55. The electrical properties of the studied materials are governed by traps with activation energies of 0.13 and 0.19 eV and a density ranging from 9.5×1014 to 2.7×1015 cm?3. The one-carrier injection is observed in weak electric fields. In electric fields with a strength of more than 4×103 V/cm, traps undergo thermal field ionization according to the Pool-Frenkel mechanism. At low temperatures and strong fields (160 K and 5×104 V/cm), the electric current is most likely due to hopping conduction by charge carriers over local levels in the band gap in the vicinity of the Fermi level. 相似文献
104.
Dinesh Topwal U. Manju Sugata Ray S. Raj D. D. Sarma S. R. Krishnakumar M. Bertolo S. La Rosa G. Cautero 《Journal of Chemical Sciences》2006,118(1):87-92
Disordered Sr2FeMoO6 shows a drastic reduction in saturation magnetization compared to highly ordered samples, moreover magnetization as a function
of the temperature for different disordered samples shows qualitatively different behaviours. We investigate the origin of
such diversity by performing spatially resolved photoemission spectroscopy on various disordered samples. Our results establish
that extensive electronic inhomogeneity, arising most probably from an underlying chemical inhomogeneity in disordered samples, is
responsible for the observed magnetic inhomogeneity. It is further pointed out that these inhomogeneities are connected with
composition fluctuations of the type Sr2Fe1+x
Mo1-x
O6 with Fe-rich (x > 0) and Mo-rich (x < 0) regions.
Dedicated to Prof J Gopalakrishnan on his 62nd birthday. 相似文献
105.
106.
S K Samanta U C Gupta R K Sharma 《The Journal of the Operational Research Society》2007,58(3):368-377
This paper investigates a discrete-time single-server finite-buffer queueing system with multiple vacations in which arrivals occur according to a discrete-time renewal process. Service and vacation times are mutually independent and geometrically distributed. We obtain steady-state system length distributions at prearrival, arbitrary and outside observer's observation epochs under the late arrival system with delayed access and early arrival system. The analysis of actual waiting-time for both the systems has also been carried out. The model has potential application in high-speed computer network, digital communication systems and other related areas. 相似文献
107.
A nonlinear pulse systems with a time-variant continuous linear part is considered. A method for synthesizing an output-feedback robust stabilizing control is suggested. 相似文献
108.
Microstructure and oxygen stoichiometry of YBaCuO films manufactured by laser ablation are investigated. Dependence of the specific electrical resistivity and superconducting
parameters of films on microstructure and oxygen stoichiometry is demonstrated. Conditions of deposition are determined, under
which films with minimum microstructure defects and good conducting properties are formed.
__________
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 2, pp. 41–45, February, 2007. 相似文献
109.
A. Yu. Kolesov E. F. Mishchenko N. Kh. Rozov 《Proceedings of the Steklov Institute of Mathematics》2007,259(1):101-127
We carry out a detailed analysis of the existence, asymptotics, and stability problems for periodic solutions that bifurcate
from the zero equilibrium state in systems with large delay. The account is based on a specific meaningful example given by
a certain scalar nonlinear second-order differential-difference equation that is a mathematical model of a single-circuit
RCL oscillator with delay in a feedback loop. 相似文献
110.
Gunhild U. von Oertzen 《Journal of Physics and Chemistry of Solids》2007,68(3):324-330
Ab initio density functional calculations (plane wave GGA, CASTEP) were performed to determine the effect of O deficiency on the electronic structure of rutile, TiO2. O deficiency was introduced through either the removal of O or the insertion of interstitial Ti atoms. At physically realistic concentrations of O vacancies in the rutile lattice (i.e. 25% and less) O deficiency results in the population of the bottom of the conduction band, the location of the Ti 3d orbitals in the pure structure, increasingly with increasing vacancy concentration. We propose that this could be confused with the formation and population of gap states especially where O vacancies occur in isolated positions in the lattice. In contrast, Ti interstitials introduce a defect state into the energy gap, without an overall reduction in the size of the energy gap. O vacancies result in a spin polarized solution, whereas Ti interstitials do not. 相似文献