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991.
992.
S. Park T. U. Kampen T. Kachel P. Bressler W. Braun D. R. T. Zahn 《Applied Surface Science》2002,190(1-4):376-381
The interaction of Ag and In with a thin film of 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) was studied by near-edge X-ray absorption fine structure (NEXAFS). Upon Ag deposition on a PTCDA film of 20 nm thickness the relative intensities and lineshapes, as well as the angular dependence of the spectra remains unchanged, illustrating the formation of a chemically unreactive Ag/PTCDA interface. On the other hand, the adsorption of 0.3 nm In strongly decreases the intensity of the π* resonances in C and O K-edge NEXAFS spectra. This is attributed to a strong charge transfer between In and PTCDA, leading to a redistribution of the charge in the molecule. However, the absence of a strong shift or new features and negligible dependence of peak intensities corresponding to π* resonances on the In thickness indicate that the interaction between In and PTCDA is not accompanied by a covalent bond formation. 相似文献
993.
This paper presents an improved generalized differential quadrature (GDQ) method for the investigation of the effects of boundary conditions on the free vibration characteristics of truncated conical panels. The truncated conical panel is an important geometrical shape in the fields of aerospace, marine and structural engineering. However, despite this importance, few works in free vibration analysis have dealt with this particular geometry. In this work, the vibration characteristics of clamped and simply supported truncated conical shells are obtained for various circumferential wave numbers. Further, the effects of the vertex and subtended angles on the frequency parameters are also examined in detail. Due to limited published results in the open literature, results for a range of cases are compared with those generated from the commercial finite element solver McNeal-Schwendler Corporation Nastran, and excellent agreement is observed. 相似文献
994.
Combinations of problem structuring methods with hard OR methodologies are seldom described in the literature. This paper will reflect on the barriers to such combinations that can be seen at the philosophical level—paradigm incommensurability—and cognitive level—type of personality and difficulty of switching paradigm. This paper examines the combination of Soft Systems Methodology and Discrete Event Simulation within an Intermediate Care case study. The paper will argue, by way of the practical application, that these problems are not insurmountable and that the result can be seen as interplay of the soft and hard paradigms. The idea of yin and yang is proposed as a metaphor for this process. 相似文献
995.
N Murakami T Tanase S Nagai Y Sato T Ueda J Sakakibara H Ando Y Hotta K Takeya 《Chemical & pharmaceutical bulletin》1991,39(8):1962-1966
The Diels-Alder reactions of a cardiac glycoside, proscillaridin (1), with some dienophiles were investigated. The reaction of 1 with alkenes such as methyl vinyl ketone and methyl acrylate afforded 3-oxo-2-oxabicyclo[2.2.2]oct-7-enes (2-5) and para-substituted benzene derivatives (6 and 7), while 1 reacted with alkynes (3-butyn-2-one, methyl propiolate) to yield para- or meta-substituted benzene derivatives (6-9). The biological activities of the resulting derivatives were evaluated by the use of isolated guinea-pig papillary muscle preparations and Na+,K(+)-adenosine triphosphatase (ATPase) preparation from dog kidney. Among the proscillaridin derivatives, compounds 4 and 7 moderately inhibited Na+,K(+)-ATPase activity. Furthermore, the concentration range of 7 over which its positive inotropic effect on guinea-pig papillary muscle preparations, increased from 5% to 95% of maximum was broader than that of 1, i.e., concentration dependency was maintained over a greater range of concentration. 相似文献
996.
A Haag-Ruelle Scattering Theory for Euclidean Lattice Field Theories is developed.Work supported by DAAD, Deutscher Akademischer Austauschdienst. Partially supported by CNPq 相似文献
997.
998.
Gulis I. M. Komyak A. I. Saechnikov K. A. Tsvirko V. A. 《Journal of Applied Spectroscopy》1989,50(3):257-262
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 50, No. 3, pp. 385–391, March, 1989. 相似文献
999.
S. D. Borkute U. H. Nagvekar S. A. Balakrishnan R. S. Mani 《Journal of Radioanalytical and Nuclear Chemistry》1987,119(4):297-302
A novel method to eliminate T3 from gross sera/plasma based on prior treatment with 8-anilino-1-naphthalene sulphonic acid has been standardized. This method is rapid with a minimum loss of protein and uses only small quantities of charcoal. The treated sera have been tested for acceptance in the RIA system for routine assays. 相似文献
1000.
Summary The influence of internal degrees of freedom on the behaviour of one-dimensional systems is discussed. For systems with half-filled
bands the coupling to internalviz. lattice coordinates decides whether Peierls distortion is caused by intramonomer coordinates or by a lattice coordinate.
Thereby the various intramonomer degrees of freedom act cooperatively. We show that there is a small regime of parameters
where both kinds of distortion exist simultaneously. For increasing temperature we find that distortions can also move from
the lattice coordinate to the intramonomer coordinate. 相似文献