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排序方式: 共有227条查询结果,搜索用时 15 毫秒
11.
Manuela Zanetti Devid Maniglio Cristian Fasoli Marco Pola Elisa Borga Claudio Corradi Mauro Dalla Serra Salvatore Iannotta Antonella Motta Tullio Toccoli 《Electroanalysis》2014,26(8):1653-1659
We report the fabrication of a microfluidic apparatus and the realization of a sensors based on PEDOT : PSS, a biocompatible semiconductor polymer used in substitution of standard electrodes for electrophysiological studies and for detection of nanopores in membrane. This gives the possibility to study the mechanisms of ions balance and molecular transport though cell membranes. In particular the apparatus is based on two chambers connected through an aperture in a PTFE sheet where lipid bilayer are formed using Montal‐Mueller method, and the pore‐forming proteins activity is detected by polymeric electrodes. This methodology could be applied to examine different membrane proteins for the purpose of biosensing, drug screening and nanopore technologies. 相似文献
12.
13.
Prof. Tiziana Benincori Dr. Valentina Bonometti Dr. Roberto Cirilli Prof. Patrizia R. Mussini Dr. Andrea Marchesi Prof. Marco Pierini Dr. Tullio Pilati Dr. Simona Rizzo Prof. Francesco Sannicolò 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(1):165-181
A series of tris‐aryl phosphane oxides existing as residual enantiomers or diastereoisomers with substituents on the aryl rings differing in size and electronic properties were synthesized and characterized. Their electronic properties were evaluated on the basis of their electrochemical oxidation and reduction potentials together with those of the corresponding “blade bromides” (i.e., the naphthalene derivatives displaying the same substitution pattern of the tris‐naphthyl phosphane oxide blades, with a bromo substituent where the phosphorus atom is located) determined by CV. The residual stereoisomeric phosphane oxides were isolated in a stereochemically pure state and were found to be highly configurationally stable at room temperature (stereoisomerization barriers of about 27 kcal mol?1). The chiroptical properties of the residual stereoisomers and the assignments of absolute configuration are discussed. The configurational stability of residual tris‐aryl phosphane oxides was found to be scarcely influenced by the electronic properties of the substituents present on the aromatic rings constituting the blades, while steric effects play the most relevant role. Detailed theoretical calculations are in agreement with the experimental results and also contribute to a rational interpretation of the stereodynamics of these systems. 相似文献
14.
Wu Y Toccoli T Koch N Iacob E Pallaoro A Rudolf P Iannotta S 《Physical review letters》2007,98(7):076601
The key role of the pentacene kinetic energy (Ek) in the early stages of growth on SiOx/Si is demonstrated: islands with smooth borders and increased coalescence differ remarkably from fractal-like thermal growth. Increasing Ek to 6.4 eV, the morphology evolves towards higher density of smaller islands. At higher coverage, coalescence grows with Ek up to a much more uniform, less defected monolayer. The growth, interpreted by the diffusion mediated model, shows the critical nucleus changing from 3 to 2 pentacene for Ek>5-6 eV. Optimal conditions to produce single crystalline films are envisaged. 相似文献
15.
Costanza Aricò Marco Sinagra Tullio Tucciarelli 《Journal of computational physics》2012,231(4):1387-1425
A novel methodology is proposed for the solution of the flow equation in a variably saturated heterogeneous porous medium. The computational domain is descretized using triangular meshes and the governing PDEs are discretized using a lumped in the edge centres numerical technique. The dependent unknown variable of the problem is the piezometric head. A fractional time step methodology is applied for the solution of the original system, solving consecutively a prediction and a correction problem. A scalar potential of the flow field exists and in the prediction step a MArching in Space and Time (MAST) formulation is applied for the sequential solution of the Ordinary Differential Equation of the cells, ordered according to their potential value computed at the beginning of the time step. In the correction step, the solution of a large linear system with order equal to the number of edges is required. A semi-analytical procedure is also proposed for the solution of the prediction step. The computational performance, the order of convergence and the mass balance error have been estimated in several tests and compared with the results of other literature models. 相似文献
16.
17.
Tullio Carolina Angelo Clerici Dianella Coggiola Sergio Morrocchi 《Journal of heterocyclic chemistry》1981,18(7):1421-1423
Chemical evidence is given that the title photo-reactions proceed via hydrogen abstraction by the photo-excited base from the alcohol in neutral medium and via electron-transfer process between the photo-excited base and the alcohol in hydrochloric acid acidified medium. 相似文献
18.
Tullio Zolezzi 《Annali di Matematica Pura ed Applicata》1971,91(1):97-118
Summary In the first two sections of this paper existence theorems are proved for optimal control problems described either by Fredholm
systems of integral equations (with control appearing nonlinearly) on a given (possibly infinite) measure space, eventually
in presence of eigenvalues, or by Urysohn systems, both with pointwise and integral constraints on controls and states. Controllability
is assumed throughout the paper. In the last section necessary conditions are proved for optimal controls of Fredholm systems
(a minimum principle in pointwise, or ? differential ? form), and theorems (that seem to be new also for the corresponding
ordinary differential control systems) are deduced about bang-bang and regularization properties of the optimal control (s)
(which turns out to be a continuous function except for a finite number of points, if positivity and semicontinuity assumptions
hold about the data): in some particular cases the optimal control will be piecewise constant. All these results are independent
on the known ones.
Lavoro eseguito nell'ambito del Centro di Matematica e Fisica Teorica del C.N.R. presso l'Università di Genova.
Entrata in Redazione il 6 maggio 1971. 相似文献
Lavoro eseguito nell'ambito del Centro di Matematica e Fisica Teorica del C.N.R. presso l'Università di Genova.
Entrata in Redazione il 6 maggio 1971. 相似文献
19.
Gabriella Cavallo Giancarlo Terraneo Alessandro Monfredini Marco Saccone Arri Priimagi Tullio Pilati Giuseppe Resnati Pierangelo Metrangolo Duncan W. Bruce 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2016,128(21):6408-6412
Unconventional ionic liquid crystals in which the liquid crystallinity is enabled by halogen‐bonded supramolecular anions [CnF2 n+1‐I⋅⋅⋅I⋅⋅⋅I‐CnF2 n+1]− are reported. The material system is unique in many ways, demonstrating for the first time 1) ionic, halogen‐bonded liquid crystals, and 2) imidazolium‐based ionic liquid crystals in which the occurrence of liquid crystallinity is not driven by the alkyl chains of the cation. 相似文献
20.
Yu Wu Tullio Toccoli Jian Zhang Norbert Koch Erica Iacob Alessia Pallaoro Salvatore Iannotta Petra Rudolf 《Applied Physics A: Materials Science & Processing》2009,95(1):21-27
Organic molecular beam deposition is studied systematically at thermal and hyperthermal regimes aiming at investigating the
role of molecular kinetic energy on the growth mechanism of pentacene submonolayers on SiO
x
/Si. We show that the kinetic energy of the impinging molecule (E
k
) plays a crucial role in determining island structure and shape, distribution of island sizes, the crystalline quality of
the first monolayer, and even the growth mode of subsequent layers. With increasing E
k
, the island structure changes from fractal to nonfractal, the shape becomes more anisotropic and the island size more uniform,
pointing to correlated island growth. Moreover, while 3D island growth is observed for thermal organic molecular beam deposition,
supersonic molecular beam deposition gives rise to layer-by-layer growth, at least for the first two layers. When E
k
≥5.0 eV, the first monolayer is composed of large single crystalline domains which can extend over up to 10 μm, inferred from
comparing atomic force micrographs of height and net transverse shear force. In these growth conditions both the high surface
diffusivity and energy redistribution play a major role. We propose a mechanism where the energy dissipation occurring during
the molecule–surface collision leads to the reorientation of whole islands during island coalescence, resulting in the elimination
of grain boundaries. 相似文献