Dynamics of the magnetic flux component normal to the layers of Bi<Subscript>2</Subscript>Sr<Subscript>2</Subscript>CaCu<Subscript>2</Subscript>O<Subscript>8</Subscript> in a tilted field

High-frequency losses in the strongly anisotropic layered superconductor Bi₂Sr₂CaCu₂O₈ are measured at 600 MHz under a magnetic field rocking about the ab plane. Anomalies in losses and hysteretic phenomena are found while performing periodic rocking, i.e., cycling the magnetic field component normal to the sample surface. Based on these observations, conclusions are drawn about the nature of magnetic-flux penetration into the superconductor. It is found that, in the range between 60 K and T _c , the dynamics of magnetic-flux vortex lines normal to the ab plane in the presence of a constant magnetic field applied parallel to this plane is governed by the critical penetration field H _c ^⊥* and the surface barrier in the presence of thermally activated vortex motion (giant flux creep). The dependences of H _c1 ^⊥* and the characteristic field of the surface barrier on the magnitude of the parallel magnetic field are measured.     

Explosive transition in amorphous microwire

An amorphous microwire in a glass shell offers a quick thermal response and can be rapidly heated to the crystallization point. When heated by a current pulse with a small amplitude and duration, the wire passes from the amorphous to microcrystalline state. The crystallization of the amorphous state may represent a slow or explosive process depending on the parameters of the pulse. In the latter case, the emission of electromagnetic waves (flash of light) and a sharp rise in the resistance are observed. The rate of propagation of the crystallization front in our experiments has been found to be about 1 m/s.     

Quantum oscillations of the critical current of asymmetric superconducting rings

The current-voltage characteristics and the magnetic field dependences of the critical current have been measured for symmetric and asymmetric superconducting rings and systems of such rings. The dependences obtained explain the periodic change in the rectified voltage observed on asymmetric rings as a result of a periodic change in the asymmetry of current-voltage characteristics.     

Contradiction between the results of observations of resistance and critical current quantum oscillations in asymmetric superconducting rings

Magnetic field dependences of critical current, resistance, and rectified voltage of asymmetric (half circles of different widths) and symmetrical (half circles of equal widths) aluminum rings close to the super-conducting transition were measured. All these dependences are periodic magnetic field functions with periods corresponding to the flux quantum in the ring. The periodic dependences of critical current measured in opposite directions were found to be close to each other for symmetrical rings and shifted with respect to each other by half the flux quantum in asymmetric rings with ratios between half circle widths of from 1.25 to 2. This shift of the dependences by a quarter of the flux quantum as the ring becomes asymmetric makes critical current anisotropic, which explains the effect of alternating current rectification observed for asymmetric rings. Shifts of the extrema of the periodic dependences of critical current by a quarter of the flux quantum directly contradict the results obtained by measuring asymmetric ring resistance oscillations, whose extrema are, as for symmetrical rings, observed at magnetic fluxes equal to an integer and a half of flux quanta.     

Superconducting quantum interference device without Josephson junctions

A new type of a superconducting quantum interference device (SQUID) based on a single superconducting loop without Josephson junctions and with asymmetric contacts has been proposed. This SQUID offers advantages in simplicity of fabrication and a steeper dependence of measured quantities on the magnetic flux. To confirm the possibility of making this type of SQUID, the magnetic field dependence of the critical current in an aluminum ring with asymmetric contacts has been experimentally investigated.     

Physicotechnical problems in designing a thermionic rectifier for the electroplating industry

The feasibility of using a thermionic thermal-to-electrical energy converter as a rectifier of industrial-frequency alternating current is considered. The design of a rectifier module with a high-current converter the emitter of which is heated by a gas torch to 1400 K is described. The basic operating performance of the module is studied, and the prospects for using this module in electroplating are discussed.     

Fluorine transfer to alkyl radicals

The development of new synthetic technologies for the selective fluorination of organic compounds has increased with the escalating importance of fluorine-containing pharmaceuticals. Traditional methods potentially applicable to drug synthesis rely on the use of ionic forms of fluorine (F(-) or F(+)). Radical methods, while potentially attractive as a complementary approach, are hindered by a paucity of safe sources of atomic fluorine (F(?)). A new approach to alkyl fluorination has been developed that utilizes the reagent N-fluorobenzenesulfonimide as a fluorine transfer agent to alkyl radicals. This approach is successful for a broad range of alkyl radicals, including primary, secondary, tertiary, benzylic, and heteroatom-stabilized radicals. Furthermore, calculations reveal that fluorine-containing ionic reagents are likely candidates for further expansion of this approach to polar reaction media. The use of these reagents in alkyl radical fluorination has the potential to enable powerful new transformations that otherwise would take multiple synthetic steps.     

Study on the quality difference of Cyperus rotundus before and after vinegar processing based on ultra-high-performance liquid chromatography-quadrupole-time of flight-mass spectrometry and molecular network combined with color parameters

Cyperus rotundus is the dry rhizome of the Cyperaceae plant Cyperus. Although there are two types of processed products in clinics, their quality differences are not clear, and the identification methods are more complex. In this study, the chemical composition of different processed products of Cyperus rotundus was characterized using ultra-high-performance liquid chromatography-quadrupole-time of flight-mass spectrometry and molecular network analysis, to identify the potential chemical markers and to establish a quick and simple color-based discrimination method. Among the 65 compounds analyzed, 12 showed significant differences. Observing the color, the surface brightness (L*) of Cyperus rotundus decreased after vinegar processing, while red (a*) and yellow (b*) values increased. These color values correlated significantly with chemical compositions. Finally, a color discriminant function was established and verified for raw Cyperus rotundus and vinegar-processing Cyperus rotundus. Based on this study, Cyperus rotundus' quality can be effectively controlled and provides a method for the comprehensive characterization of chemical components and chemical markers of other traditional Chinese medicine and processed products, as well as new ideas and methods in identification and quality evaluation.     

An efficient numerical tank for non-linear water waves,based on the multi-subdomain approach with BEM

An efficient 2D non-linear numerical wave tank called LONGTANK has been developed based on a multi-subdomain (MSD) approach combined with the conventional boundary element method (BEM). The multi-subdomain approach aims at optimized matrix diagonalization, thus minimizing the computing time and reserved storage. The CPU per time step in LONGTANK simulation is found to increase only linearly with the number of surface nodes, which makes LONGTANK highly efficient especially when simulating long-time wave evolutions in space. Appropriate treatment of special points on the boundary ensures high resolution in LONGTANK simulation beyond initial deformation and breaking, which allows detailed study of breaking criterion, breaker morphology, breaking dissipation, vorticity generation, etc. Detailed numerical implementation has been given with demonstration of LONGTANK simulations.