Nitrogen doping effects on the structure of graphene

Graphene and nitrogen doped graphene have been prepared by modified Hummers’ method and the following ammonia heat-treatment process, respectively. The effects of N-doping on the structure of graphene have been systematically investigated by various characterization techniques. SEM, TEM, BET, Raman and XRD analysis were used to distinguish the difference of the microstructures; and FT-IR, XPS, especially XANES were performed to elucidate the bonding information such as C-N. The effect of nitrogen doping on the structure of graphene has been obtained. More defects are present on nitrogen doped graphene as elucidated by BET, XRD, Raman, and XANES characterizations. XANES analysis also indicates that the N-doping decreases the surface oxygen-containing groups.     

Solvent‐induced crystallization in poly(ethylene terephthalate) during mass transport

Solvent transport in poly(ethylene terephthalate) (PET) and related phase transformation were investigated. The data of mass sorption were analyzed according to Harmon's model for Case I (Fickian), Case II (swelling), and anomalous transport. This transport process in PET is accompanied by the induced crystallization of the original amorphous state. The transformation was examined by wide‐angle X‐ray scattering, small‐angle X‐ray scattering, differential scanning calorimetry, and Fourier transform infrared spectroscopy. During this process, the matrix is under a strain state that causes different kinetic paths of crystallization as compared with that by thermal annealing. This state of strain assists the development of the solvent‐induced crystallization. The model regarding crystallization was proposed in terms of the study of long period L, the crystal thickness l_c, and the thickness of amorphous layer l_a obtained from the one‐dimensional correlation function and interface distribution function. Different kinetic paths were discovered for different crystallization processes. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 1444–1453, 2002     

Asymptotic analysis of growing plane strain tensile cracks in elastic-ideally plastic solids

An exact asymptotic analysis is presented of the stress and deformation fields near the tip of a quasistatically advancing plane strain tensile crack in an elastic-ideally plastic solid. In contrast to previous approximate analyses, no assumptions which reduce the yield condition, a priori, to the form of constant in-plane principal shear stress near the crack tip are made, and the analysis is valid for general Poisson ratio ν. Specific results are given for ν = 0.3 and 0.5, the latter duplicating solutions in previous work by L.I. Slepyan, Y.-C. Gao and the present authors. The crack tip field is shown to divide into five angular sectors of four different types ; in the order in which these sweep across a point in the vicinity of the advancing crack, they are : two plastic sectors which can be described asymptotically (i.e., as r → 0, where r is distance from the crack tip) in slip-line terminology as ‘constant stress’ and ‘centered fan’ sectors, respectively ; a plastic sector of non-constant stress which cannot be described asymptotically in terms of slip lines; an elastic unloading sector; and a trailing plastic sector of the same type as that directly preceding the elastic sector. Further, these four different sector types constitute the full set of asymptotically possible solutions at the crack tip. As is known from prior work, the plastic strain accumulated by a material point passing through such a moving ‘centered fan’ sector is O(ln r) as r → 0 ; it is proved in the present work that the plastic strain accumulated by a material point passing through the ‘constant stress’ sector ahead of a growing crack must be less singular than In r as r → 0. As suggested also in earlier studies, the rate of increase of opening gap δ at a point currently at a distance r behind, but very near, the crack tip is given for crack advance under contained yielding by

$\text{δ}\text{?}\text{=}\text{α}\text{J}\text{?}\text{σ}{}_0\text{+β(}\text{σ}{}_0\text{E}\text{)}\text{a}\text{?}\text{ln(}\text{R}\text{r}\text{)}$

where a is crack length, σ0 is tensile yield strength, E is Young's modulus, J is the value of the J-integral taken in surrounding elastic material, and the parameters α and R are undetermined by the asymptotic analysis. The exact solution for ν = 0.3 gives β = 5.462, which agrees very closely with estimates obtained from finite element solutions. An approximate analysis based on use of slip line representations in all plastic sectors is outlined in the Appendix.     

A new melampolide and other secondary metabolites from <Emphasis Type="Italic">Artemisia baldshuanica</Emphasis>

The composition of secondary metabolites in benzene and alcohol extracts of the epigeal part of Artemisia baldshuanica Krasch. et Zarp. (Asteraceae) collected during the vegetative phase was investigated. A new melampolide, the structure of which was established based on spectral data and an x-ray crystal structure analysis, and known compounds were isolated.     

Crystal and molecular structure of 13-diethanolamino-deacetyllaurenobiolide. Macrocycle conformation in linear germacrolides

An x-ray structure analysis of the 13-diethanolamino derivative of deacetyllaurenobiolide, a germacrane sesquiterpene lactone, was performed. The germacrane macrocycle has the chairchair conformation with the ¹⁵D_5,1D¹⁴ configuration. The conformation of the macrocycle in linear germacrolides was analyzed.Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 454–457, November–December, 2004.This revised version was published online in April 2005 with a corrected cover date.     

Biomimetic synthesis of (±)-aculeatin D

A practical, efficient and diastereoselective synthesis of the cytotoxic and antiprotozoal compound aculeatin D (1) is described, employing a biomimetic oxidative cyclisation cascade reaction to generate the tricyclic system of the natural product. The synthesis proceeds in ten steps from commercially available 1-tetradecanol.