全文获取类型
收费全文 | 522篇 |
免费 | 19篇 |
国内免费 | 4篇 |
专业分类
化学 | 299篇 |
晶体学 | 2篇 |
力学 | 20篇 |
数学 | 29篇 |
物理学 | 195篇 |
出版年
2024年 | 3篇 |
2022年 | 5篇 |
2021年 | 8篇 |
2020年 | 8篇 |
2019年 | 6篇 |
2018年 | 9篇 |
2017年 | 4篇 |
2016年 | 12篇 |
2015年 | 6篇 |
2014年 | 7篇 |
2013年 | 26篇 |
2012年 | 31篇 |
2011年 | 30篇 |
2010年 | 16篇 |
2009年 | 17篇 |
2008年 | 25篇 |
2007年 | 29篇 |
2006年 | 27篇 |
2005年 | 22篇 |
2004年 | 24篇 |
2003年 | 30篇 |
2002年 | 15篇 |
2001年 | 6篇 |
2000年 | 11篇 |
1999年 | 5篇 |
1998年 | 5篇 |
1997年 | 3篇 |
1996年 | 8篇 |
1995年 | 11篇 |
1994年 | 6篇 |
1993年 | 8篇 |
1992年 | 8篇 |
1991年 | 8篇 |
1990年 | 4篇 |
1989年 | 6篇 |
1988年 | 3篇 |
1987年 | 5篇 |
1985年 | 6篇 |
1984年 | 6篇 |
1983年 | 5篇 |
1982年 | 5篇 |
1980年 | 8篇 |
1979年 | 6篇 |
1978年 | 12篇 |
1977年 | 4篇 |
1976年 | 13篇 |
1975年 | 3篇 |
1974年 | 2篇 |
1973年 | 7篇 |
1970年 | 3篇 |
排序方式: 共有545条查询结果,搜索用时 15 毫秒
11.
Molecular mass distribution of sodium alginate by high-performance size-exclusion chromatography 总被引:8,自引:0,他引:8
Ci SX Huynh TH Louie LW Yang A Beals BJ Ron N Tsang WG Soon-Shiong P Desai NP 《Journal of chromatography. A》1999,864(2):199-210
A sensitive high-performance size-exclusion chromatography (HPSEC) method with simple UV detection was developed for the molecular mass analysis of sodium alginate. It was used to evaluate alginates of varying molecular mass and the results were compared with the viscosity measurements. This HPSEC method was sensitive to serve as the stability indicating method for alginate after storage under different conditions. The information of relative molecular mass distribution of alginate was provided with reference to pullulan molecular mass standards. The comparison of the HPSEC chromatograms of alginate, pullulan and dextran revealed the effect of chemical composition of a polysaccharide and its effect on apparent molecular mass distribution. 相似文献
12.
A new method in which a series of substituted carbazoles is efficiently produced by the combination of an amide and an arene is described. The key feature of this method is the palladium-catalyzed tandem directed C-H functionalization and amide arylation. The method tolerates substitution on either ring of the biaryl amide substrates, and the products can be assembled in a simple two-step protocol from readily available reagents. The Pd(0) species generated are reoxidized to Pd(II) in the presence of Cu(OAc)2 and an atmosphere of oxygen. 相似文献
13.
A rapid and reliable high performance liquid chromatographic (HPLC) method for the simultaneous determination of heterocyclic
compounds, namely nicotinic acid, nicotinamide, and 3-cyanopyridine, in industrial effluent is described. A Φ4.6 mm × 150
mm, 5 μm C-18 reversed phase stationery phase, and a methanol-acetonitrile-water tertiary mobile phase (20:20:60 v/v) were
used for separation. The detection wavelength of a diode array (DAD) was set at 216 nm with a bandwidth of 16 nm. Phenol was
used as an internal standard. The regression equations revealed a linear relationship between the concentration of the analytes
injected and the peak area detected by DAD. The limits of detection (S/N = 3) ranged from 0.70 to 1.18 mg L−1, the recoveries ranged from 87% to 102% and the precision expressed as % RSD intra-day and inter-day varied from 0.9 to 3.9
and 1.2 to 5.6, respectively. This method is rapid, sensitive and suitable for the monitoring of nicotinic acid, nicotinamide,
and 3-cyanopyridine in effluent of related pharmaceutical manufacturing plants. 相似文献
14.
15.
16.
17.
J. E. A. Whiteaway A. P. Wright B. Garrett G. H. B. Thompson J. E. Carroll L. M. Zhang C. F. Tsang I. H. White K. A. Williams 《Optical and Quantum Electronics》1994,26(7):S817-S842
This paper describes the first general large-signal dynamic multiple-mode laser model that incorporates all the main mechanisms known to influence the dynamic behaviour of DFB laser structures with the exception of thermal effects: longitudinal mode spatial hole burning, carrier transport effects, nonlinear gain, and laser and submount parasitics. The time evolution of the output power and wavelength of all modes is predicted, and full spectra can be plotted as a function of time. The model has been extended to include an approximation to the effects of propagation down dispersive fibre, thereby allowing the simulation of filtered received eye diagrams. Detailed comparison of the model with the experimental performance of 2×/8 DFB lasers has shown good agreement, allowing the performance to be optimized, particularly with respect to longitudinal hole burning and carrier transport. The model is also applied to gain-switched operation of 2×/8 DFB structures, fast pulsing of three-section /4 DFB lasers, and the dynamic behaviour of complex coupling coefficient DFB laser structures. 相似文献
18.
19.
20.