首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2663篇
  免费   94篇
  国内免费   28篇
化学   1483篇
晶体学   13篇
力学   124篇
数学   665篇
物理学   500篇
  2023年   25篇
  2022年   74篇
  2021年   109篇
  2020年   115篇
  2019年   107篇
  2018年   86篇
  2017年   82篇
  2016年   134篇
  2015年   79篇
  2014年   117篇
  2013年   185篇
  2012年   177篇
  2011年   168篇
  2010年   99篇
  2009年   88篇
  2008年   118篇
  2007年   106篇
  2006年   74篇
  2005年   76篇
  2004年   73篇
  2003年   50篇
  2002年   60篇
  2001年   28篇
  2000年   36篇
  1999年   25篇
  1998年   28篇
  1997年   20篇
  1996年   25篇
  1995年   20篇
  1994年   20篇
  1993年   21篇
  1992年   18篇
  1991年   13篇
  1990年   17篇
  1989年   17篇
  1988年   15篇
  1987年   19篇
  1986年   11篇
  1985年   23篇
  1984年   26篇
  1982年   33篇
  1981年   22篇
  1980年   21篇
  1979年   25篇
  1978年   12篇
  1977年   19篇
  1976年   16篇
  1975年   15篇
  1974年   9篇
  1973年   6篇
排序方式: 共有2785条查询结果,搜索用时 15 毫秒
161.
162.
The Alperin Weight Conjecture was stated by J. Alperin in 1986 and constitutes one of the main problems in the representation theory of finite groups. In this paper, we provide a reduction to simple groups and as an application we prove the conjecture in several cases.  相似文献   
163.
The neutron temperature is a characteristic parameter in irradiation channels of reactor. For nuclides which have resonances in the thermal neutron energy range, their Westcott g-factors are different from unity. The values of g-factors and cross-sections of (n, γ) reaction of these nuclides are temperature dependence. The standard energy for tabulation of thermal neutron cross-section (σ0) is that of room temperature (293.59 K or 20.43 °C), corresponding to a neutron energy 0.0253 eV or to a neutron velocity of 2200 m/s. However, in the irradiation channels of reactor, the temperature is not exact at 20.43 °C. Thus, the temperature at the irradiation position must be known to convert σ0 to σ(T). A method for determination of the neutron temperature in irradiation channels of Dalat reactor is presented by fitting the thermal neutron spectrum obtained from the calculation using MCNP code.  相似文献   
164.
In this paper, we consider a task allocation model that consists of assigning a set of m unmanned aerial vehicles (UAVs) to a set of n tasks in an optimal way. The optimality is quantified by target scores. The mission is to maximize the target score while satisfying capacity constraints of both the UAVs and the tasks. This problem is known to be NP-hard. Existing algorithms are not suitable for the large scale setting. Scalability and robustness are recognized as two main issues. We deal with these issues by two optimization approaches. The first approach is the Cross-Entropy (CE) method, a generic and practical tool of stochastic optimization for solving NP-hard problem. The second one is Branch and Bound algorithm, an efficient classical tool of global deterministic optimization. The numerical results show the efficiency of our approaches, in particular the CE method for very large scale setting.  相似文献   
165.
Diketopyrrolopyrrole (DPP)‐based terpolymers—P(DPP‐TPyT) and P(DPP‐T3MTT)—bearing bithiophene donating groups and weak accepting units such as pyridine (Py) or methyl thiophene‐3‐carboxylate (3MT), in the polymer backbone, were successfully synthesized. Although the two polymers had similar physical and electrochemical properties, grazing incidence X‐ray diffraction patterns of P(DPP‐TPyT) and P(DPP‐T3MTT) showed mixed and edge‐on orientations, respectively, in thermally annealed films. Accordingly, the P(DPP‐T3MTT) showed twice the hole mobility of P(DPP‐TPyT) in a thin‐film transistor, and a blended film of P(DPP‐T3MTT) and [6,6]‐phenyl‐C71‐butyric acid methyl ester (PC71BM) showed better power conversion efficiency in a polymer solar cell. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 1339‐1347  相似文献   
166.
The current-voltage relationships of deposited structures are measured for cluster structures consisting of nanoparticles of lead telluride. Variation in the value of the tunnel current is shown. Optimum conditions for the possible emergence of quantum-hopping conductivity due to carrier tunneling (the characteristic sizes of the nanoclusters and the distances between them) are determined.  相似文献   
167.
Nb-Pt co-doped TiO2 and the hybrid SWCNTs/Nb-Pt co-doped TiO2 thin films have been prepared by the sol–gel spin-coating process for gas-sensor fabrication. Field emission scanning electron microscope (FE-SEM, TEM and X-ray diffraction (XRD) characterizations indicated that the SWCNTs inclusion did not affect the morphology of the TiO2 thin film and the particle size. Additionally, the SWCNTs were well embedded in the TiO2 matrix. The gas-sensing properties of Nb–Pt co-doped TiO2 thin films with and without SWCNTs inclusion were investigated. The hybrid sensors with the inclusion of different SWCNTs contents are examined to elucidate the effect of SWCNTs content on the gas-sensing properties. Experimental results revealed that the responses to ethanol of Nb–Pt co-doped TiO2 sensors with SWNCTs inclusion increase by factors of 2–5 depending on the operating temperature and the ethanol concentration, compared to that of the sensor without SWCNTs inclusion. Moreover, all hybrid sensors can operate with high sensitivity and stability at a relatively low operating temperature (<335 °C). The responses of the hybrid sensors are greatly affected by SWCNTs content inclusion. The optimized SWCNTs content of 0.01% by weight was obtained for our experiment. The improved gas-sensing performance should be attributed to the additional formation of the p/n junction between SWCNTs (p-type) and TiO2 (n-type).  相似文献   
168.
The purpose of this note is to provide a -group whose mod-3 cohomology ring has a nilpotent element satisfying .

  相似文献   

169.
Our research involves the development of new cationic materials for anion-based applications. We report the solvothermal synthesis and characterization of Pb(3)F(5)NO(3), a new layered lead fluoride material that, unlike the majority of layered and open-framework materials, is cationic in charge. The structure consists of polyhedral lead centers connected by doubly and triply bridging fluoride groups. We quantitatively exchanged the interlamellar nitrate groups of Pb(3)F(5)NO(3) for dichromate, under ambient aqueous conditions. Nuclear magnetic resonance and UV-vis spectroscopy show the reaction proceeds to 61.0% completion in several days. The material is also stable to 450 degrees C, which is vastly superior to organic resins that are still the standard for anion-exchange. The presence of extraframework anions also opens up other potentially unique anion-based properties, such as new catalytic reactions, anion intercalation, or growth of anionic clusters within the void spaces of the cationic material.  相似文献   
170.
From the MeOH extract of the aerial part of Vietnamese Orthosiphon stamineus, five new isopimarane-type diterpenes [orthosiphols F-J (1-5)] and two new diterpenes [staminols A (6) and B (7)] with a novel carbon-framework, to which we proposed the name "staminane", and three new highly-oxygenated staminane-type diterpenes [staminolactones A (8) and B (9) and norstaminol A (10)1 were isolated. Moreover, staminolactone A (8) is 8,14-secostaminane-type and staminolactone B (9) is 13,14-secostaminane-type, while norstaminol A (10) is 14-norstaminen-type. Together with these new diterpenes, sixteen known compounds were also isolated and identified to be: 7,3',4'-tri-O-methylluteolin (11), eupatorin (12), sinensetin (13), 5-hydroxy-6,7,3',4'-tetramethoxyflavone (14), salvigenin (15), ladanein (16), tetramethylscutellarein (17), 6-hydroxy-5,7,4'-trimethoxyflavone (18), vomifoliol (19), aurantiamide acetate (20), rosmarinic acid (21), caffeic acid (22), oleanolic acid (23), ursolic acid (24), betulinic acid (25), and beta-sitosterol (26). All the isolated compounds were tested for their cytotoxicity towards highly liver metastatic murine colon 26-L5 carcinoma cells, and the new diterpenes, except for 4, and flavonoids (11, 12, 16, 18) showed cytotoxicity with an ED50 value between 10 and 90 microg/ml.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号