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31.
J. Toušek 《Czechoslovak Journal of Physics》1973,23(12):1403-1409
This paper presents the results of the quantum efficiency measurement of CdTe over the photon energy range 1·5–4·5 eV obtained from the photovoltaic effect on special photodiodes. There are two kinks observable in the increase of the quantum efficiency which can be explained on the basis of the band structure of CdTe. The first is due to electron, the second due to hole ionization.I wish to thank Prof. E.Klier and Doc. R.Kuel, CSc. for their valuable discussions and Ing. P.Polívka, CSc. for the preparation of CdTe single crystals. 相似文献
32.
The trivalent diphenylarsine derivatives studied gave molecular ions and diagnostic common fragment ions at m/e 229, 227, 154, 153, 152, 151, 77 and 51. The diphenylarsine odd electron ion, m/e 229, undergoes the “ortho coupling” reaction before splitting off the arsenic atom. The correlation between the ion fragmentation and the pyrolytic decompositions is discussed. 相似文献
33.
Wee-Ong Siew Wai-Keat Lee Hin-Yong Wong Thian-Khok Yong Seong-Shan Yap Teck-Yong Tou 《Applied Physics A: Materials Science & Processing》2010,101(4):627-632
In the process of pulsed laser deposition of nickel (Ni) and ruthenium (Ru) thin films, the occurrence of phase explosion
in ablation was found to affect the deposition rate and enhance the optical emissions from the plasma plume. Faster thin-film
growth rates coincide with the onset of phase explosion as a result of superheating and/or sub-surface boiling which also
increased the particulates found on the thin-film surface. These particulates were predominantly droplets which may not be
round but flattened and also debris for the case of silicon (Si) ablation. The droplets from Ni and Ru thin films were compared
in terms of size distribution and number density for different laser fluences. The origins of these particulates were correlated
to the bubble and ripple formations on the targets while the transfer to the thin film surface was attributed to the laser-induced
ejection from the targets. 相似文献
34.
A method which allows the simultaneous separation of the isochromatic and isopachic fringes for transient plane-stress problems is presented. A double pulsed ruby laser and a terbium glass Faraday rotator is employed to resolve the transient isochromatic and isopachic patterns. Separated fringe patterns for a structural component are recorded at nine different instants after impact loading. The dynamic material-fringe values of isochromatics and isopachics are obtained within the experiment. Finally, dynamic stresses distributed along a section at different time intervals are resolved. 相似文献
35.
Direct current magnetron sputter-deposited ZnO thin films 总被引:1,自引:0,他引:1
Jian-Wei HoonKah-Yoong Chan Jegenathan KrishnasamyTeck-Yong Tou Dietmar Knipp 《Applied Surface Science》2011,257(7):2508-2515
Zinc oxide (ZnO) is a very promising electronic material for emerging transparent large-area electronic applications including thin-film sensors, transistors and solar cells. We fabricated ZnO thin films by employing direct current (DC) magnetron sputtering deposition technique. ZnO films with different thicknesses ranging from 150 nm to 750 nm were deposited on glass substrates. The deposition pressure and the substrate temperature were varied from 12 mTorr to 25 mTorr, and from room temperature to 450 °C, respectively. The influence of the film thickness, deposition pressure and the substrate temperature on structural and optical properties of the ZnO films was investigated using atomic force microscopy (AFM) and ultraviolet-visible (UV-Vis) spectrometer. The experimental results reveal that the film thickness, deposition pressure and the substrate temperature play significant role in the structural formation and the optical properties of the deposited ZnO thin films. 相似文献
36.
Naomi Kishii Morie Shimadu Shun Maruyama Sayuri Tou Ikuo Sasaki Hideyuki Sugimura 《Tetrahedron letters》2018,59(8):776-780
Tetrasubstituted pyrroles bearing C-2 α-azido side-chains were synthesized employing a new class of diazides, α,γ-diazido α,β-unsaturated esters, and 1,3-dicarbonyl compounds under simple thermal conditions. Further investigation of the synthetic utility of the obtained pyrroles reveals unexpected displacement of the α-azido group at the C-2 side-chain by a variety of nucleophiles. This two-step process exhibits a broad substrate scope, good functional group tolerance, simple operation, and high reaction efficiency, providing an easy access to polyfunctional pyrroles with novel substitution patterns. 相似文献
37.
38.
Summary : The surface photovoltage method was used for the study of thin polymer layers made of poly{(9,9-dihexylfluorene-2,7-diyl)[-3-(3-methylbutyl)thiophene-2,5-diyl]} prepared by spin-coating on ITO coated glass substrates. The surface photovoltage (SPV) in a thin polymer layer is a result of dissociation of photogenerated free excitons in electric field of the space charge region (SCR) which forms spontaneously at the surface. The photovoltage signal was formed between a transparent electrode capacitively coupled to the surface of the sample and the back ITO electrode. Photovoltaic spectra were measured under illumination both the free surface (SPVfs) and the substrate (SPVITO) side and for various layer thicknesses. The shape of the SPVITO spectrum is very similar to that of the absorption spectrum, whereas the SPVfs spectrum maximum is shifted to longer wavelengths. Fitting theory to the experimental data, the thickness of the space charge region and the diffusion lengths were evaluated. The results are discussed also in relation to photoluminescence study of thin films. 相似文献
39.
Experiments are performed to study the single-phase transient forced convection heat transfer on an array of four in-line, flush-mounted simulated electronic chips in a vertical rectangular channel. Water is the coolant media and the flow covers the wide range of laminar flow regime with Reynolds number, based on heat source length, from 800 to 2,625. The heat flux ranges from 1 W/cm2 to 7 W/cm2. The heat transfer characteristics are studied and correlations are presented. The transient correlation for overall data recommended is Nu= 0.945(Pe 1/3) Fo–1/2. 相似文献
40.
Thian-Khok Yong Yeh-Yee Kee Sek-Sean Tan Seong-Shan Yap Wee-Ong Siew Teck-Yong Tou 《Applied Physics A: Materials Science & Processing》2010,101(4):621-626
The depth profile of ITO on glass was measured by the time-of-flight secondary ion mass spectroscopy (TOFSIMS) which revealed
high sodium (Na) ion concentration at the ITO surface as well as at the ITO–glass interface as a result of out diffusion with
substrate heating. Effects of Na ions on the performance of organic light-emitting diode (OLED) were studied by etching away
a few tens of nanometers off the ITO surface with a dilute aquaregia solution of HNO3:HCl:H2O. A single-layer, molecularly doped ITO/(PVK+TPD+Alq3)/Al OLEDs were fabricated on bare and etched ITO samples. Although the removal of a 10-nm layer of ITO surface increased
the voltage range, brightness, and lifetime, it was insufficient to correlate these improvements with solely to the Na ion
reduction without considering the surface roughness. 相似文献