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排序方式: 共有1321条查询结果,搜索用时 31 毫秒
971.
Kei Matsuzaki Hiroshi Ito Tokiji Kawamura Toshiyuki Uryu 《Journal of polymer science. Part A, Polymer chemistry》1973,11(5):971-987
13C nuclear magnetic resonance (CMR) spectra were obtained for 2,4-dimethoxypentane, which is a model compound of poly(methyl vinyl ether), and the effects of the solvent and temperature on the chemical shifts were investigated. CMR spectra of poly-(alkyl vinyl ethers) were also determined and analyzed. The diad tacticities were obtained from β-methylene carbon resonances of poly(methyl vinyl ether), poly(ethyl vinyl ether), and poly(isobutyl vinyl ether), but not from those of poly(isopropyl vinyl ether) and poly(tert-butyl vinyl ether). The methoxyl carbon resonance of poly(methyl vinyl ether) and the ethoxyl methylene carbon resonance of poly(ethyl vinyl ether) showed splittings corresponding to pentad and triad sequences, respectively. The α-methine and quaternary carbon resonances of poly(tert-butyl vinyl ether) showed splittings corresponding to pentad and triad sequences, respectively. 相似文献
972.
Tamotsu Hashimoto Koji Ishizuka Akihiro Umehara Toshiyuki Kodaira 《Journal of polymer science. Part A, Polymer chemistry》2002,40(22):4053-4064
To establish the optimum conditions for obtaining high molecular weight polyacetals by the self‐polyaddition of vinyl ethers with a hydroxyl group, we performed the polymerization of 4‐hydroxybutyl vinyl ether (CH2?CH? O? CH2CH2CH2CH2? OH) with various acidic catalysts [p‐toluene sulfonic acid monohydrate, p‐toluene sulfonic anhydride (TSAA), pyridinium p‐toluene sulfonate, HCl, and BF3OEt2] in different solvents (tetrahydrofuran and toluene) at 0 °C. All the polymerizations proceeded exclusively via the polyaddition mechanism to give polyacetals of the structure [? CH(CH3)? O? CH2CH2CH2CH2? O? ]n quantitatively. The reaction with TSAA in tetrahydrofuran led to the highest molecular weight polymers (number‐average molecular weight = 110,000, weight‐average molecular weight/number‐average molecular weight = 1.59). 2‐Hydroxyethyl vinyl ether, diethylene glycol monovinyl ether, cyclohexane dimethanol monovinyl ether, and tricyclodecane dimethanol monovinyl ether were also employed as monomers, and polyacetals with various main‐chain structures were obtained. This structural variety of the main chain changed the glass‐transition temperature of the polyacetals from approximately ?70 °C to room temperature. These polyacetals were thermally stable but exhibited smooth degradation with a treatment of aqueous acid to give the corresponding diol compounds in quantitative yields. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 4053–4064, 2002 相似文献
973.
Thermal desorption of the alkaloids in opium samples at 300 degrees C using a vertical microfurnace pyrolyzer was followed by their on-line gas chromatographic (GC) analysis on a large-bore glass capillary column. This method permitted rapid and sensitive determination of the content of the main alkaloid, morphine, in the small (ca. 100 microg) opium samples with a relative standard deviation within 4% for 5 runs. The observed morphine contents of about 12 to 15 w/w% in the given opium samples were in fairly good agreement with those estimated by a conventional GC-MS method. 相似文献
974.
Katsuki Takai Teruhiko Baba Toshiyuki Kanamori 《Journal of fluorine chemistry》2004,125(12):1959-1964
A fluorinated oleic acid 1-Z containing a perfluorooctyl group and its analogues (E-isomer 1-E, alkyne type 2 and saturated type 3) were synthesized in good yields. In these syntheses, it was found that a key compound 5 could be converted to each of 1-Z, 1-E and 2. Furthermore, equilibrium spreading pressures of their monolayers at the air-water interface were measured in order to demonstrate how the degree of unsaturation in the hydrophobic chain, the geometric isomerization, and the presence of F-atoms influence the monolayer stability. Irrespective of the structural alteration in the hydrophobic chains, the fluorinated fatty acids formed more stable monolayers with high spreading pressures as compared to their hydrocarbon counterparts. 相似文献
975.
Nobuhito Imanaka Toshiyuki Masui Young Woon Kim 《Journal of solid state chemistry》2004,177(10):3839-3842
Single crystals of Tb16O30 (TbO1.875) were successfully grown for the first time by DC electrolysis of the Tb3+ ion conducting Tb2(MoO4)3 solid electrolyte at 11 V, 900 °C. The Tb16O30 phase is the intermediate phase of fluorite-related rare earth oxides and it is extremely difficult to grow in a single crystal form, because this intermediate phase is usually obtained as one of the mixture of the fluorite related TbOx phases. Because there are many non-stoichiometric phases in the terbium oxide system, it is impossible to grow a specific intermediate phase in a single crystal form by the conventional methods via melt. Although single crystals of TbOx have been recently obtained by anodic electrocrystallization from alkaline hydroxide melts containing TbCl3, the composition has been confirmed to be TbOx with 1.75<x<1.82. On the contrary, the presently developed DC electrolysis method can be simply applicable at moderate temperatures around 900 °C to artificially grow an intermediate phase of Tb16O30 (x=1.875) in a single crystal form, which was evidenced by the electron diffraction patterns for each particle. 相似文献
976.
Takamuku T Maruyama H Kittaka S Takahara S Yamaguchi T 《The journal of physical chemistry. B》2005,109(2):892-899
Large-angle X-ray scattering (LAXS) measurements over a temperature range from 223 to 298 K have been made on methanol confined in mesoporous silica MCM-41 with two different pore diameters, 28 A (C14) and 21 A (C10), under both monolayer and capillary-condensed adsorption conditions. To compare the structure of methanol in the MCM-41 pores with that of bulk methanol, X-ray scattering intensities for bulk methanol in the same temperature range have also been measured. The radial distribution functions (RDFs) for the monolayer methanol samples showed that methanol molecules are strongly hydrogen bonded to the silanol groups on the MCM-41 surface, resulting in no significant change in the structure of adsorbed methanol with respect to the pore size and temperature. On the other hand, the RDFs for the capillary-condensed methanol samples showed that hydrogen-bonded chains of methanol molecules are formed in both pores. However, the distance and number of hydrogen bonds estimated from the RDFs suggested that hydrogen bonds between methanol molecules in the pores are significantly distorted or partly disrupted. It has been found that the hydrogen bonds are more distorted in the smaller pores of MCM-41. With decreasing temperature, however, the hydrogen-bonded chains of methanol in the pores were gradually ordered. A comparison of the present results on methanol in MCM-41 pores with those on water in the same pores revealed that the structural change with temperature is less significant for confined methanol than for confined water. 相似文献
977.
DMSO or DMF as a solvent strongly accelerated the thiocarboxylation of amines and alcohols with carbon monoxide and sulfur. Under mild conditions (1 atm, 20 °C), this thiocarboxylation of amines assisted by DMSO with carbon monoxide and sulfur has been developed into a practical and convenient synthetic method for S-alkyl thiocarbamates in good to excellent yields, including EPTC, thiobencarb, orbencarb, and molinate (herbicides). DMF also showed the similar solvent effect. NMP slightly decreased the effect for the thiocarboxylation of amines, and the yield of S-alkyl thiocarbamate was lowered in DMAc. Surprisingly, no formation of S-alkyl thiocarbamate was observed at the use of the other solvents, such as THF, hexane, toluene, AcOEt, MeCN, MeOH, and H2O. The present solvent-assisted thiocarboxylation with carbon monoxide and sulfur could be also applied to a new synthesis of S-alkyl O-alkyl carbonothioates from alcohols under mild conditions (1 atm, 20 °C) in DMF using DBU (1,8-diazabicyclo[5.4.0]undec-7-ene). 相似文献
978.
Toshiaki Ito Toshiyuki Morii Morimitsu Tanimoto 《Zeitschrift fur Physik C Particles and Fields》1993,59(1):57-61
We have studied the heavy flavored hadron spectroscopy, which is motivated by the heavy quark effective theory. TheQ \(\bar q\) ,Qqq andQQq hadrons have been investigated systematically. Regarding thes-quark as a member of heavy quarks, the predicted mass levels of both theQqq andQQq baryons are quite consistent with experimental ones. 相似文献
979.
Toshiyuki Gotoh 《Journal of statistical physics》1990,59(1-2):371-402
The Langevin equations for a particle of an arbitrary shape and the correlation functions for the fluctuating forces, torques, or force-torque acting on the particle in a rotating flow are derived from the semimicroscopic level of coarse graining by using fluctuating hydrodynamics. In order to obtain the solution of the Navier-Stokes Langevin equation valid over the entire flow region, use is made of the method of matched asymptotic expansions in (
f
a2/v)1/2 1. The cases of slow and rapid rotation are analyzed. It is shown that the fluctuation-dissipation theorems hold up to the order of (
f
a2/v)1/2 in both slow and rapid rotation, and that the diffusivity tensor depends on the angular velocity of the fluid and becomes anisotropic. 相似文献
980.
Total syntheses of SB-203207 (1) and sphingofungin E (2) were accomplished by utilizing an asymmetric desymmetrization strategy to introduce multiple stereogenic centers into meso starting compounds in a single step. Thus, rhodium carbenoid-mediated CH insertion into 3 provided the bicyclo[3.3.0]framework 4 for 1, while organocatalyst-mediated bromolactonization of 5 afforded 6 for the synthesis of 2. Similarly, we utilized desymmetric rhodium nitrenoid-mediated aziridination reaction of 5 to obtain a key intermediate required for a total synthesis of pactamycin (29), a complex aminocyclopentitol antibiotic featuring six contiguous stereogenic centers. 相似文献