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81.
Representation of Multicomponent Liquid-Liquid Equilibria for Aqueous and Organic Solutions Using a Modified UNIQUAC Model 总被引:6,自引:0,他引:6
Kazuhiro Tamura Yao Chen Kaoru Tada Toshiro Yamada Isamu Nagata 《Journal of solution chemistry》2000,29(5):463-488
A modified form of the UNIQUAC model is presented to accurately reproducebinary phase equilibria and ternary and quaternary liquid-liquid equilibria ofaqueous and organic solutions. The model gives a good representation in thereproduction of binary coexistence curves over a wide temperature range usingtemperature-dependent parameters and of binary vapor-liquid equilibria usingtwo binary energy parameters, and in the correlation of ternary and quaternaryliquid-liquid equilibria using ternary and quaternary parameters, in addition tobinary parameters. The quaternary calculated results are compared with thoseobtained from the modified Wilson and extended UNIQUAC models. 相似文献
82.
[reaction: see text] A titanium complex derived from 3-(3,5-diphenylphenyl)-BINOL exhibits an enhanced catalytic activity in the asymmetric alkylation of aldehydes, allowing the reduction of the catalyst amount to less than 1 mol % without deterioration in enantioselectivity. 相似文献
83.
Lithuanian Mathematical Journal - Abstract. We show that, under the long-tailedness of the densities of normalized Lévy measures, the densities of infinitely divisible distributions on the... 相似文献
84.
Harada T Hiraoka Y Kusukawa T Marutani Y Matsui S Nakatsugawa M Kanda K 《Organic letters》2003,5(26):5059-5062
Bis-BINOLs 7a-c in which two BINOL units are tethered by phenylenebis(ethynyl) groups react with titanium tetraisopropoxide (2 equiv) to form intramolecular dimeric titanium(IV) aggregates 2a-c. Of these, 2a,b with an o-phenylenebis(ethynyl) tether are stable in the presence of excess titanium tetraisopropoxide. Complex 2a exhibits a relatively high enantioselectivity in asymmetric addition of diethylzinc to an aldehyde. [structure: see text] 相似文献
85.
The toxicities of some benzofurazans (BZs), benzofurazan (1), 4,7-dimethylbenzofurazan (2), 4,7-dibromobenzofurazan (3), 4-bromo-6-cyanobenzofurazan (4), 4,7-dicyanobenzofurazan (5) and 4,5-dicyanobenzofurazan (6), were examined on Escherichia coli. Compound 5 at 4 microM and compound 6 at 7 microM completely inhibited the growth of E. coli in a simple nutritionally restricted medium (GM medium). These compounds were more toxic in GM medium than in a nutritionally rich medium (YE medium), which contained yeast extract as an additive in GM medium. Compound 4 also inhibited the growth of E. coli at 300 microM in GM medium. The toxicities of BZs were in the order of 1 approximately 2 approximately 3 less than 4 approximately 5 approximately 6. Compounds 4, 5 and 6 induced manganese-superoxide dismutase (Mn-SOD) and catalase activities of E. coli in YE medium. The induced SOD and catalase provide a defense against the potential cytotoxicities of O2- and H2O2. The rate of dioxygen uptake in cyanide-resistant respiration of E. coli was dependent on the concentration of 5, and was correlated with the induction of SOD and catalase. The reduction potentials of BZs followed the order of 1 approximately 2 less than 3 less than 4 less than 5 approximately 6. Compounds 5 and 6, which had redox potentials higher than those of the other BZs, are thought to be more readily reduced in the living system.(ABSTRACT TRUNCATED AT 250 WORDS) 相似文献
86.
Ohno H Miyamura K Tanaka T Oishi S Toda A Takemoto Y Fujii N Ibuka T 《The Journal of organic chemistry》2002,67(4):1359-1367
A general and efficient synthesis of allenes using a palladium(0)/diethylzinc system is described. Treatment of mesylates or trichloroacetates of (E)- or (Z)-2-bromoalk-2-en-1-ols with diethylzinc in the presence of a catalytic amount of palladium(0) affords allenes bearing an aminoalkyl, alkyl, or aryl substituent(s) in good to high yields. No transfer of chirality from the stereogenic center carrying the mesyloxy group to the allene was observed. 相似文献
87.
用动态粘弹函数关系表征PMMA/α-MSAN共混物的相分离 总被引:2,自引:0,他引:2
测定了聚甲基丙烯酸甲酯/聚(α-甲基苯乙烯丙烯腈)共混物熔体的动态粘弹性.考察动态储能模量G′与动态损耗模量G″的关系,发现在终端区域两种聚合物的lgG′~lgG″关系曲线与温度无关,其外推直线斜率接近2;而其共混物的斜率明显小于2,并随组成变化呈现温度依赖性,由此得到的“临界温度”可用于表征这种具有LCST行为的共混物的相容性. 相似文献
88.
Toshihide Baba Yuki Morikawa Norito Komatsu Toshiro Takahashi Hisashi Sugisawa Yoshio Ono 《Research on Chemical Intermediates》2000,26(1):13-20
The dynamic properties of protons in H-[Ga]-ZSM-5, H-[B]-ZSM-5 and H-[Al-B]-ZSM-5 were compared with that of protons in H-[Al]-ZSM-5
by temperature dependence of 1H MAS NMR in the range of 298 k and 473 K. The temperature dependence of the line width of 1H MAS NMR reveals that protons in H-[Ga]-ZSM-5 were more mobile than those in H-[Al]-ZSM-5 at temperature as low as 373 K.
The protons in H-[B]-ZSM-5 were not mobile at 473 K and fixed in the zeolite frame work as the bridging hydroxyl groups, ≡B-OH-Si≡.
The thermal motion of protons in ≡Al-OH-Si≡ was suppressed by introducing B3+ cations into the framework of H-[Al]-ZSM-5. 相似文献
89.
Osamu Araki Masayasu Horie Toshiro Masuda 《Journal of Polymer Science.Polymer Physics》2001,39(3):337-341
The physical aging of polycarbonate was investigated with dynamic viscoelastic measurements. Physical aging was observed for samples aged at 110 °C (QA) and room temperature (QP) after being quenched from the molten state. The shapes of the temperature dispersion curves of the dynamic viscoelastic functions (E′, E″, and tan δ) of the QA and QP samples changed with aging time in a temperature range below the glass‐transition temperature (Tg). However, at temperatures close to but below Tg, the curves for the aged samples merged into the curve of the quenched sample at a temperature denoted TH. TH increased with aging time. The experimental results suggest that the aged sample has a memory of having been quenched and that as the sample approaches the equilibrium state, this memory is lost. Differential scanning calorimetry thermograms showed an endothermic peak below Tg for the QA samples. The peak temperature (Tp) also increased with aging time. TH and Tp of the QA samples were approximately the same. The increase of both TH and Tp with aging time indicates that the structure of the polymeric chain in the glassy state relaxes over larger segment scale lengths because the scale of the movable segments is related to temperature. © 2000 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 39: 337–341, 2001 相似文献
90.