Experimental evidence and theoretical analysis for the chiral symmetry breaking in the growth front of conglomerate crystal phase of 1,1'-binaphthyl

Chirally asymmetric states, chemical oscillations, propagating chemical waves, and spatial patterns, are examples of far-from-equilibrium self-organization. We have found that the crystal growth front of 1,1(')-binaphthyl shows many of the characteristics of an open system in which chiral symmetry breaking has occurred. From its supercooled molten phase, 1,1(')-binaphthyl crystallizes as a conglomerate of R and S crystals when the temperature is above 145 degrees C. In addition, 1,1(')-binaphthyl in its molten phase is always racemic due to its high racemization rate. Under appropriate conditions, bimodal probability distribution of enantiomeric excess (ee) with maxima around 60% was observed. The ee was mass independent, indicating that the growth front maintains a constant ee. A kinetic model that theoretically analyzes the chiral symmetry breaking transition in the growth front of a conglomerate crystal phase was formulated. Computer simulation of the model reproduced not only the average but also the large variation of the ee observed in crystallization experiments.     

Observation of the quantum Hall effect in cleaved InAs surfaces

We have performed the in-plane magnetotransport measurements on the two-dimensional electron gas at the cleaved p-InAs (1 1 0) surface by deposition of Ag. The surface electron density N_s is determined from the Hall coefficient at . The coverage dependence of N_s is well explained by the assumption that each adsorbed Ag atom denotes one electron into InAs until the surface Fermi level reaches the adsorbate-induced donor level. The electron mobility μ is about and does not show a clear dependence on the coverage over . In the high-magnetic field regime of B>1/μ, Shubnikov–de Hass oscillations were observed. A beating pattern due to the strong spin–orbit interaction appears for high N_s. For lower N_s of , an apparent quantum Hall plateau for ν=4 and vanishing of the longitudinal resistivity were observed around .     

Premodified Surface Method to Obtain Ultra‐Highly Dispersed Metals and their 3D Structure Control on an Oxide Single‐Crystal Surface

Precise control of the three‐dimensional (3D) structure of highly dispersed metal species such as metal complexes and clusters attached to an oxide surface has been important for the development of next‐generation high‐performance heterogeneous catalysts. However, this is not easily achieved for the following reasons. (1) Metal species are easily aggregated on an oxide surface, which makes it difficult to control their size and orientation definitely. (2) Determination of the 3D structure of the metal species on an oxide powder surface is hardly possible. To overcome these difficulties, we have developed the premodified surface method, where prior to metal deposition, the oxide surface is premodified with a functional organic molecule that can strongly coordinate to a metal atom. This method has successfully provided a single metal dispersion on an oxide single‐crystal surface with the 3D structure precisely determined by polarization‐dependent total reflection fluorescence X‐ray absorption fine structure (PTRF‐XAFS). Here we describe our recent results on ultra‐high dispersions of various metal atoms on TiO₂(110) surfaces premodified with mercapto compounds, and show the possibility of fine tuning and orientation control of the surface metal 3D structures.     

Extraction of object position from in-line holograms by using single wavelet coefficient

A novel digital method for tracking position of objects from in-line holograms by using single wavelet coefficient is proposed. In the proposed method, a wavelet transform is used to analyze the holograms. An axial position of the object being studied is determined by using a real value of a resultant wavelet coefficient appears at a center position of interference fringes. A feasibility of this method is experimentally verified by analyzing holograms of an optical fiber.     

Laser spectroscopy of the antiprotonic helium atom–molecule {\bar pHe}^+

The metastable antiprotonic helium atom–molecule (in short, atomcule), , which was discovered in 1991 as being the cause of the anomalous longevity of antiprotons with an overall lifetime of about 3 μs, now provides an exotic playground for laser spectroscopy, helped by the existence of numerous long lived states with 1–2 μs lifetimes. This three body system is characterized by a large angular momentum l ∼ 38 of coupled with the electron in the 1s ground orbital, and looks like an exotic hydrogen isotope with many different “nuclear states” as well as an exotic molecule with two centers (He²⁺ and ). So far, a number of laser resonance transitions have been identified. The present talk will cover the following topics: (1) high precision spectroscopy in comparison with three body theories involving the relativistic effect and QED, and (2) hyperfine structure of ;laser-microwave triple resonance. This revised version was published online in August 2006 with corrections to the Cover Date.     

Effects of imaging properties on dynamic speckles produced by a set of moving phase screens

Space-time correlation functions have been derived for the time-varying intensities of speckle patterns in image space produced by a series of moving random-phase screens. The time-correlation length, which measures the changing rate of intensity fluctuations, is evaluated from the correlation functions to examine the effects of the imaging properties on the temporal behaviour of the speckles resulting from the multiple scattering. It is shown that the average velocity and velocity dispersion of the phase screens can be measured from the time-correlation length by using imaging systems which have a small and a large point spread at the front focal plane of the systems, respectively. Theoretical results for the relationship between the focal position of the imaging lens and the time-correlation length are also presented.