Experimental and theoretical results for 21Ne(6Li,d)25Mg

Alpha-particle spectroscopic strengths extracted from ²¹Ne(⁶Li, d) angular distributions agree in both magnitude and multipolarity with predicted strengths. Secondly, strengths calculated using eigenfunctions determined in large shell-model computations are remarkably consistent with pure SU₃ symmetry limit results.     

Alpha-particle strengths from the 16O(6Li,d)20Ne reaction

The ¹⁶O(⁶Li, d)²⁰Ne reaction has been studied at bombarding energies of 20, 32 and 38 MeV. The α-particle spectroscopic strengths have been extracted for levels up to 12.15 MeV in excitation. Nondirect processes appear to contribute significantly to all levels at 20 MeV and to high spin levels (6⁺ and 8⁺) at 32 MeV. Strengths extracted for members of the ground state band assuming (sd)⁴ transfer are unequal at both 32 and 38 MeV, in marked contrast to theoretical predictions. To explain this, particle-hole correlations in ¹⁶O(g.s.), inelastic channel coupling in the reaction and perhaps other effects as well, have to be considered. Strengths extracted for members of excited bands and α-decay reduced widths compare poorly with each other and with simple SU(3) predictions.     

Sur l'analyse générale

Résumé Donner un point de vue pour construire l'analyse générale, et traiter, comme exemple, les fonctions d'ensemble systématiquement.     

Studies on dielectric properties of polyvinylidene chloride

Colloid and Polymer Science - The ?′ and ?″ for polyvinylidene chloride investigated were measured at frequencies from 100 c/s to 2 M c/s, at various fixed temperatures from...     

Mode of oxidations of organosulfur compounds: Example of nucleophilic oxygenations of thiolsulfinates

Two types of oxygenative oxidations (Nucleophilic and Electrophilic Oxidations) of sulfur atom are proposed and a typical mode of nucleophilic oxidation is shown with a few unsymmetrical thiolsulfinates.     

The chemical form and acute toxicity of arsenic compounds in marine organisms

A method for the separation and identification of inorganic and methylated arsenic compounds in marine organisms was constructed by using a hydride generation/cold trap/gas chromatography mass spectrometry (HG/CT/GC MS) measurement system. The chemical form of arsenic compounds in marine organisms was examined by the HG/CT/GC MS system after alkaline digestion. It was observed that trimethylarsenic compounds were distributed mainly in the water-soluble fraction of muscle of carnivorous gastropods, crustaceans and fish. Also, dimethylated arsenic compounds were distributed in the water-soluble fraction of Phaeophyceae. It is thought that most of the trimethylated arsenic is likely to be arsenobetaine since this compound released trimethylarsine by alkaline digestion and subsequent reduction with sodium borohydride. The major arsenic compound isolated from the water-soluble fraction in the muscle and liver of sharks was identified as arsenobetaine from IR, FAB Ms data, NMR spectra and TLC behaviour. The acute toxicity of arsenobetaine was studied in male mice. The LD₅₀ value was higher than 10 g kg⁻¹. This compound was found in urine in the non-metabolized form. No particular toxic symptoms were observed following administration. These results suggest that arsenobetaine has low toxicity and is not metabolized in mice. The LD₅₀ values of other minor arsenicals in marine organisms, trimethylarsine oxide, arsenocholine and tetramethylarsonium salt, were also examined in mice.     

Relative stability of η-cyclopentadienyl(olefin)ruthenium cations: The first estimation of the nature of the Ru-olefin bond

Relative stability in coordination of substituted styrene derivatives to [Ru(η-C₅H₅)(dtpe)]⁺ (dtpe = 1,2-bis(di-p-tolylphosphino)-ethane) was determined by NMR spectroscopy to reveal unusually weak substituent dependency of the stability.