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61.
Tamotsu Hashimoto Yusuke Makino Michio Urushisaki Toshikazu Sakaguchi 《Journal of polymer science. Part A, Polymer chemistry》2008,46(5):1629-1637
Living cationic polymerization of 2‐adamantyl vinyl ether (2‐vinyloxytricyclo[3.3.1.1]3,7decane; 2‐AdVE) was achieved with the CH3CH(OiBu)OCOCH3/ethylaluminum sesquichloride/ethyl acetate [CH3CH(OiBu)OCOCH3/Et1.5AlCl1.5/CH3COOEt] initiating system in toluene at 0 °C. The number‐average molecular weights (Mn's) of the obtained poly(2‐AdVE)s increased in direct proportion to monomer conversion and produced the polymers with narrow molecular weight distributions (MWDs) (Mw/Mn = ~1.1). When a second monomer feed was added to the almost polymerized reaction mixture, the added monomer was completely consumed and the Mn's of the polymers showed a direct increase against conversion of the added monomer. Block and statistical copolymerization of 2‐AdVE with n‐butyl vinyl ether (CH2?CH? O? CH2 CH2CH2CH3; NBVE) were possible via living process based on the same initiating system to give the corresponding copolymers with narrow MWDs. Grass transition temperature (Tg) and thermal decomposition temperature (Td) of the poly(2‐AdVE) (e.g., Mn = 22,000, Mw/Mn = 1.17) were 178 and 323 °C, respectively. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1629–1637, 2008 相似文献
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64.
The cytotoxicity of 39 compounds, including eighteen flavonoids (flavanones, 1-10; flavones, 11-17; flavanol, 18), sixteen phenolic acid derivatives (aromatic acids, 19-24; aldehyde, 25; esters, 26-34) and five glycerides (35-39), isolated from Mexican propolis, were evaluated against a panel of six different cancer cell lines; murine colon 26-L5 carcinoma, murine B16-BL6 melanoma, murine Lewis lung carcinoma, human lung A549 adenocarcinoma, human cervix HeLa adenocarcinoma and human HT-1080 fibrosarcoma. A phenylpropanoid-substituted flavanol, (2R,3S)-8-[4-phenylprop-2-en-1-one]-4',7-dihydroxy-3',5-dimethoxyflavan-3-ol (18), showed the most potent cytotoxicity against A549 cells (IC50, 6.2 microM) and HT-1080 cells (IC50, 3.9 microM), stronger than those of the clinically used anticancer drug, 5-fluorouracil (IC50, 7.5 microM and 5.4 microM, respectively). Based on the observed results, the structure-activity relationships are discussed. 相似文献
65.
Phase diagrams of d-wave superconductivity characterized by an order parameter Δ coexisting with charge-density waves (CDWs) characterized by an order parameter Σ were constructed for the two-dimensional Fermi surface (FS) appropriate to, e.g., cuprates. CDWs were considered as an origin of the pseudogap appearing at antinodal FS sections of the d(x2-y2) superconductor. Two types of the Σ-reentrance were found: with the temperature, T, and with the opening of the CDW sector, 2α. The angular plots in the momentum space for the resulting gap profile over the FS ('gap roses') were obtained. The gap patterns are rather involved, giving insight into the difficulties of the interpretation of photoemission spectra. It was shown that the Σ-Δ coexistence region exists even for the complete dielectric gapping due to the distinction between the superconducting and CDW order parameter symmetries. The checkerboard and unidirectional CDW configurations were examined, and both the phase diagrams and the behavior with T and α of the order parameters were found to differ. A more general case with a non-zero mismatch angle β between the superconducting lobes and the CDW sectors was analyzed, the case β = π/4 corresponding to the d(xy) symmetry of the superconducting order parameter. The phase diagrams were found to be sensitive to β-variations, showing that internal strains and external pressure can drastically affect the behavior of Σ(T) and Δ(T). 相似文献
66.
Ryota Seto Takashi Sato Takahiro Kojima Katsumoto Hosokawa Yasuhito Koyama Gen‐Ichi Konishi Toshikazu Takata 《Journal of polymer science. Part A, Polymer chemistry》2010,48(16):3658-3667
Syntheses of 2,2′‐bisalcoholic group‐substituted 9,9′‐spirobifluorene monomers 2 were performed by the reaction of 2,2′‐dihydroxy‐9,9′‐spirobifluorene 2a with haloalcohols. Polycarbonates consisting of 9,9′‐spirobifluorene skeleton in the main chain (PC 4 ) were synthesized by the polycondensation of 2,2′‐bisalcoholic monomers 2 and triphosgene or diphenyl carbonate. PC 4 showed good thermal stability: the 5% weight loss temperature was over 330 °C under both nitrogen and air atmospheres. The glass transition temperature was in a range of 16–269 °C estimated by differential scanning calorimetry, depending on the flexibility of the alkylene or oxyethylene chains of 2 . PC 4 showed high solubility toward ordinary organic solvents such as CHCl3, benzene, and THF, making possible the preparation of the flexible thin films. Very high refractive index in a range of 1.62–1.66 at 589 nm was observed although PC 4 consists only of C, H, and O atoms, whereas very low degree of birefringence was confirmed. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 3658–3667, 2010 相似文献
67.
Phenylenediamines bearing the ethoxycarbonyl groups were synthesized to modulate luminescent properties. Switching of the luminescent properties was achieved by redox change between the phenylenediamine and quinonediimine derivatives. 相似文献
68.
Closed orbits in homology classes 总被引:2,自引:0,他引:2
Dedicated to Pr. Akihiko Morimoto for his 60th birthday 相似文献
69.
p-Phenylenediamine bearing terminal bipyridyl moieties was synthesized by palladium-catalyzed amination. The corresponding ruthenium(II) complex was formed and characterized, providing a redox-switchable photoinduced electron-transfer system. 相似文献
70.
Horowitz S Nishida T Cattafesta L Sheplak M 《The Journal of the Acoustical Society of America》2007,122(6):3428-3436
This paper describes the design, fabrication, and characterization of a bulk-micromachined piezoelectric microphone for aeroacoustic applications. Microphone design was accomplished through a combination of piezoelectric composite plate theory and lumped element modeling. The device consists of a 1.80-mm-diam, 3-microm-thick, silicon diaphragm with a 267-nm-thick ring of piezoelectric material placed near the boundary of the diaphragm to maximize sensitivity. The microphone was fabricated by combining a sol-gel lead zirconate-titanate deposition process on a silicon-on-insulator wafer with deep-reactive ion etching for the diaphragm release. Experimental characterization indicates a sensitivity of 1.66 microVPa, dynamic range greater than six orders of magnitude (35.7-169 dB, re 20 microPa), a capacitance of 10.8 nF, and a resonant frequency of 59.0 kHz. 相似文献