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541.
Keisuke Chino Toshikazu Takata Takeshi Endo 《Journal of polymer science. Part A, Polymer chemistry》1999,37(1):59-67
1‐Benzocyclobutenyl vinyl ether (1) was easily prepared by the elimination reaction of hydrogen bromide from 1‐benzocyclobutenyl 1‐bromoethyl ether obtained by 1‐bromobenzocyclobutene and ethylene glycol via two steps in a good yield. Cationic polymerizations of 1 was carried out at −78°C for 2 h in toluene in the presence of BF3OEt2 as an initiator to give quantitatively the corresponding polymers (2) as white solids. As a model reaction of the polymer reaction of 2 with dienophiles, the Diels–Alder reactions of 1‐methoxybenzocyclobutene with maleic anhydride (MA) in toluene at 100–140°C for 3 h were carried out to obtain the corresponding Diels–Alder adduct quantitatively at 140°C. The polymer reactions of 2 with MA and N‐phenylmaleimide (MI) in toluene were carried out to yield the corresponding Diels–Alder adduct polymers in good yields. The degree of introduction of the dienophile could be controlled by temperature, and the unreacted benzocyclobutene moiety could further react with another benzocyclobutene moiety or dienophile. The properties (solubilities, Tg, and temperature of 10% weight loss) of the polymers obtained from the polymer reaction were quite different from those of 2. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 59–67, 1999 相似文献
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545.
Hui Li Ruifu Wang Dr. You-lee Hong Zihao Liang Yidan Shen Dr. Yusuke Nishiyama Prof. Toshikazu Miyoshi Prof. Tianbo Liu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(22):5803-5808
Charged or neutral adamantane guests can be encapsulated into the cavity of cationic metal–organic M6L4 (bpy-cage, M=PdII(2,2′-bipyridine), L=2,4,6-tri(4-pyridyl)-1,3,5-triazine) cages through hydrophobic interaction. These encapsulations can provide an approach to control the net charge on the resulting cage–guest complexes and regulate their charge-dominated assembly into hollow spherical blackberry-type assemblies in dilute solutions: encapsulation of neutral guests will hardly influence their self-assembly process, including the blackberry structure size, which is directly related to the intercage distance in the assembly; whereas encapsulating negatively (positively) charged guests resulted in a shorter (longer) intercage distance with larger (smaller) assemblies formed. Therefore, the host–guest chemistry approach can be used to tune the intercage distance accurately. 相似文献
546.
Star‐shaped cyclopolymers: A new category of star polymer with rigid cyclized arms prepared by controlled cationic cyclopolymerization and subsequent microgel formation of divinyl ethers
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Tamotsu Hashimoto Haruki Matsui Michio Urushisaki Toshikazu Sakaguchi 《Journal of polymer science. Part A, Polymer chemistry》2015,53(9):1094-1102
The combination of living/controlled cationic cyclopolymerization and crosslinking polymerization of bifunctional vinyl ethers (divinyl ethers) was applied to the synthesis of core‐crosslinked star‐shaped polymers with rigid cyclized arms. Cyclopolymerization of 4,4‐bis(vinyloxymethyl)cyclohexene ( 1 ), a divinyl ether with a cyclohexene group, was investigated with the hydrogen chloride/zinc chloride (HCl/ZnCl2) initiating system in toluene at 0 °C. The reaction proceeded quantitatively to give soluble poly( 1 )s in organic solvents. The content of the unreacted vinyl groups in the produced polymers was less than ~3 mol%, and therefore, the degree of cyclization of the polymers was determined to be ~97%. The number‐average molecular weight (Mn) of the polymers increased in direct proportion to monomer conversion and further increased on addition of a fresh monomer feed to the almost completely polymerized reaction mixture, indicating that living cyclopolymerization of 1 occurred. The chain linking reactions among the formed living cyclopolymers with 1,4‐bis(vinyloxy)cyclohexane ( 3 ) as a crosslinker in toluene at 0 °C produced core‐crosslinked star‐shaped cyclopoly( 1 )s [star‐poly( 1 )s] in high yield (100%). Dihydroxylation of the cyclohexene double bonds of star‐poly( 1 ) gave hydrophilic water‐soluble star‐shaped polymers with rigid arm structure [star‐poly( 1 )‐OH] with thermo‐responsive function in water. Tgs of star‐poly( 1 ) and star‐poly( 1 )‐OH were 135 °C and 216 °C, respectively; these values are very high as vinyl ether‐based star‐shaped polymers. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 1094–1102 相似文献
547.
Yoshio Yano Prof. Toshikazu Ono Dr. Takashi Ohhara Prof. Yoshio Hisaeda 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(71):17802-17807
X-ray diffraction, neutron diffraction, and theoretical calculations were used to investigate the relationship between the optical properties and degree of protonation in acid-base complexes. We prepared five acid-base complexes by using a pyridine-modified pyrrolopyrrole derivative and salicylic acid. Two of the prepared acid-base complexes were polymorphs of guest-free crystals with green emission; the other three were guest-inclusion crystals with yellow emission containing CH2Cl2, CH2Br2, or C2H4Cl2. The presence or absence of guests caused the emission to change color, altering the hydrogen bond strength between the acid-base complexes. Accurate N⋅⋅⋅H distances between the pyridyl moiety and the carboxy group over the temperature range 123 to 273 K were 1.40 Å for the guest-free crystals and 1.25 Å for the guest-inclusion crystals. Our findings contribute to a better understanding of the complex relationship between photofunction and proton dynamics in acid-base complexes. 相似文献
548.
Constituents of the underground parts of Glehnia littoralis 总被引:9,自引:0,他引:9
From the underground parts of Glehnia littoralis FR. Schmidt ex Miquel (Umbelliferae), 26 compounds, including two new lignan glycosides [giehlinosides A (1) and B (2)], a new neolignan glycoside [glehlinoside C (3)], and a new phenylpropanoid glycoside 14-[beta-D-apiofuranosyl-(1-->6)-beta-D-glucopyranosyloxyl-3-methoxypropiophenone (4)1, were obtained and their structures were determined by analysis of their spectral data. The 1,1-diphenyl-2-picrylhydrazyl radical-scavenging assay disclosed quercetin (8), isoquercetin (9), rutin (10), chlorogenic acid (11), and caffeic acid (24) as the major antioxidative constituents in this crude drug. 相似文献
549.
The production process of whisky consists of malting, mashing, fermentation, distillation and maturation. Sulfur volatile compounds generated during this process have long attracted interest because they influence quality in general. More than forty compounds have been reported: they are formed during malting, fermentation, and distillation, but some may decrease in concentration during distillation and maturation. In sensory analysis, sulfur characteristics are described as sulfury, meaty, cereal, feinty, and vegetable, among others. Their contribution to overall quality depends on their concentration, with a positive contribution at low levels, but a negative contribution at high levels. Chemical analyses of sulfur volatiles have been developed by using sulfur-selective detectors and multi-dimensional gas chromatography to overcome the numerous interferences from the matrix. Formation pathways, thresholds, and contribution have not been elucidated completely; therefore, methods for integrating diverse data and knowledge, as well as novel technical innovations, will be needed to control sulfur volatiles in the future. 相似文献
550.
K. C. Nicolaou Masaru Takayanagi Nareshkumar F. Jain Swaminathan Natarajan Alexandros E. Koumbis Toshikazu Bando Joshi M. Ramanjulu 《Angewandte Chemie (International ed. in English)》1998,37(19):2717-2719
A triazene-based synthetic strategy for the construction of the complex biaryl ethers and a Suzuki coupling reaction were the key steps in the synthesis of precursor 1 of the aglycon of vancomycin, which already contains the complete skeleton of the target compound. The cleavage of the triazene unit from the D ring and the removal of the other protecting groups led to the aglycon of vancomycin. These strategies should be particularly valuable for the synthesis of other naturally occurring glycopeptide antibiotics and offer opportunities for the synthesis of combinatorial libraries of compounds of the vancomycin family for chemical biology studies. 相似文献