全文获取类型
收费全文 | 972篇 |
免费 | 22篇 |
国内免费 | 7篇 |
专业分类
化学 | 701篇 |
晶体学 | 21篇 |
力学 | 19篇 |
数学 | 60篇 |
物理学 | 200篇 |
出版年
2022年 | 5篇 |
2021年 | 7篇 |
2020年 | 18篇 |
2019年 | 10篇 |
2018年 | 12篇 |
2017年 | 13篇 |
2016年 | 17篇 |
2015年 | 12篇 |
2014年 | 29篇 |
2013年 | 47篇 |
2012年 | 57篇 |
2011年 | 76篇 |
2010年 | 39篇 |
2009年 | 38篇 |
2008年 | 77篇 |
2007年 | 65篇 |
2006年 | 67篇 |
2005年 | 44篇 |
2004年 | 35篇 |
2003年 | 46篇 |
2002年 | 37篇 |
2001年 | 21篇 |
2000年 | 14篇 |
1999年 | 9篇 |
1998年 | 12篇 |
1997年 | 6篇 |
1996年 | 9篇 |
1995年 | 6篇 |
1994年 | 16篇 |
1993年 | 11篇 |
1992年 | 5篇 |
1991年 | 8篇 |
1990年 | 3篇 |
1989年 | 6篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1986年 | 8篇 |
1985年 | 17篇 |
1984年 | 11篇 |
1983年 | 8篇 |
1982年 | 10篇 |
1981年 | 7篇 |
1980年 | 7篇 |
1979年 | 3篇 |
1978年 | 6篇 |
1977年 | 7篇 |
1976年 | 12篇 |
1975年 | 6篇 |
1974年 | 4篇 |
1973年 | 3篇 |
排序方式: 共有1001条查询结果,搜索用时 15 毫秒
62.
Toru Kojima 《Discrete Mathematics》2008,308(7):1282-1295
The bandwidth B(G) of a graph G is the minimum of the quantity max{|f(x)-f(y)|:xy∈E(G)} taken over all proper numberings f of G. The strong product of two graphs G and H, written as G(SP)H, is the graph with vertex set V(G)×V(H) and with (u1,v1) adjacent to (u2,v2) if one of the following holds: (a) u1 and v1 are adjacent to u2 and v2 in G and H, respectively, (b) u1 is adjacent to u2 in G and v1=v2, or (c) u1=u2 and v1 is adjacent to v2 in H. In this paper, we investigate the bandwidth of the strong product of two connected graphs. Let G be a connected graph. We denote the diameter of G by D(G). Let d be a positive integer and let x,y be two vertices of G. Let denote the set of vertices v so that the distance between x and v in G is at most d. We define δd(G) as the minimum value of over all vertices x of G. Let denote the set of vertices z such that the distance between x and z in G is at most d-1 and z is adjacent to y. We denote the larger of and by . We define η(G)=1 if G is complete and η(G) as the minimum of over all pair of vertices x,y of G otherwise. Let G and H be two connected graphs. Among other results, we prove that if δD(H)(G)?B(G)D(H)+1 and B(H)=⌈(|V(H)|+η(H)-2)/D(H)⌉, then B(G(SP)H)=B(G)|V(H)|+B(H). Moreover, we show that this result determines the bandwidth of the strong product of some classes of graphs. Furthermore, we study the bandwidth of the strong product of power of paths with complete bipartite graphs. 相似文献
63.
Toru Tsukioka 《Comptes Rendus Mathematique》2005,340(8):581-586
This Note is devoted to the study of the Fano manifolds X obtained by blow-up along a smooth curve C in a complex projective manifold Y. By the Mori theory, we can ensure the existence of an extremal contraction different from the blow-up . Here we give the complete classification of the corresponding pairs in the case where φ is a fiber type contraction of relative dimension 2, i.e. the general fibers of φ are del Pezzo surfaces. In Tsukioka (Thesis, Nancy University 1, 2005), the relative dimension 1 case is also considered. To cite this article: T. Tsukioka, C. R. Acad. Sci. Paris, Ser. I 340 (2005). 相似文献
64.
65.
Defocusing digital particle image velocimetry (DDPIV), as a true three-dimensional (3D) measurement technique, allows for
the measurement of 3D velocities within a volume. Initially designed using a single CCD and 3-pinhole mask (Willert and Gharib
in Exp Fluids 12:353–358, 1992), it has evolved into a multi-camera system in order to overcome the limitations of image saturation due to multiple exposures
of each particle. In order to still use a single camera and overcome this limitation, we have modified the original single
CCD implementation by placing different color filters over each pinhole, thus color-coding each pinhole exposure, and using
a 3-CCD color camera for image acquisition. Due to the pinhole mask, there exists the problem of a significant lack of illumination
in a conventional lighting setup, which we have solved by backlighting the field-of-view and seeding the flow with black particles.
This produces images with a white background superimposed with colored triple exposures of each particle. A color space linear
transformation is used to allow for accurate identification of each pinhole exposure when the color filters’ spectrum does
not match those of the 3-CCD color camera. Because the imaging is performed with a multi-element lens instead of a single-element
lens, an effective pinhole separation, d
e, is defined when using a pinhole mask within a multi-element lens. Calibration results of the system with and without fluid
are performed and compared, and a correction of the effective pinhole separation, d
e, due to refraction through multiple surfaces is proposed. Uncertainty analyses are also performed, and the technique is successfully
applied to a buoyancy-driven flow, where a 3D velocity field is extracted. 相似文献
66.
Photomobile Polymer Materials with Crosslinked Liquid‐Crystalline Structures: Molecular Design,Fabrication, and Functions 下载免费PDF全文
Dr. Toru Ube Prof. Dr. Tomiki Ikeda 《Angewandte Chemie (International ed. in English)》2014,53(39):10290-10299
Crosslinked liquid‐crystalline polymer materials that macroscopically deform when irradiated with light have been extensively studied in the past decade because of their potential in various applications, such as microactuators and microfluidic devices. The basic motions of these materials are contraction–expansion and bending–unbending, which are observed mainly in polysiloxanes and polyacrylates that contain photochromic moieties. Other sophisticated motions such as twisting, oscillation, rotation, and translational motion have also been achieved. In recent years, efforts have been made to improve the photoresponsive and mechanical properties of this novel class of materials through the modification of molecular structures, development of new fabrication methods, and construction of composite structures. Herein, we review structures, functions, and working mechanisms of photomobile materials and recent advances in this field. 相似文献
67.
Tsutomu Ohzuku Ryoji Yamato Toru Kawai Kingo Ariyoshi 《Journal of Solid State Electrochemistry》2008,12(7-8):979-985
Steady-state polarization measurements of lithium titanium oxide (LTO; Li[Li1/3Ti5/3]O4) were carried out using the 0-V lithium-ion cells consisting of two identical LTO-electrodes with a parallel-plate symmetrical electrode configuration. The sinusoidal voltage with the peak amplitude of 1.0 V was imposed at 0.1 Hz upon the 0-V cells and the current response was measured as a function of time. The steady-state polarization, obtained by plotting the current versus applied voltage, was linear in current up to approximately 60 mA cm?2 or 4 A g?1 based on the LTO weight and suggested the resistance polarization only for the lithium insertion electrode of the LTO. The method was also applied to lithium aluminum manganese oxide (LAMO; Li[Li0.1Al0.1Mn1.8]O4) and the resistance polarization of the LAMO-electrode was determined for currents up to approximately 25 mA cm?2 or 2 A g?1 based on the LAMO weight. The validity of the results was examined for the polarization measurements of the 2.5-V lithium-ion battery consisting of LTO and LAMO, and the significance of the polarization measurements of lithium insertion electrodes for high-power applications was discussed. 相似文献
68.
Tsunashima R Long DL Endo T Noro S Akutagawa T Nakamura T Cabrera RQ McMillan PF Kögerler P Cronin L 《Physical chemistry chemical physics : PCCP》2011,13(16):7295-7297
The Dawson-type polyanion [α-Mo(18)O(54)(SO(3))(2)](4-), with two SO(3)(2-) templates embedded inside a polyoxomolybdate(vi) cage, exhibits thermochromism over an exceptionally wide temperature range (~500 K). The temperature dependence of the cluster structure, established from X-ray crystallography, IR and Raman spectroscopy and DFT calculations, is related to a decreasing HOMO-LUMO gap in the near UV with increasing temperature. We postulate this is due to geometrical changes that affect both the occupied and unoccupied frontier molecular orbitals of this cluster anion. 相似文献
69.
Keiji Kinoshita Toru SaitoAkira Ito Takashi KawakamiYasutaka Kitagawa Shusuke YamanakaKizashi Yamaguchi Mitsutaka Okumura 《Polyhedron》2011,30(18):3249-3255
Recently, graphene sheet is one of interesting systems to realize novel electronic properties. Especially, interaction between graphene and adsorbed oxygen molecule is very important to control electronic condition. In this paper, we employed some aromatic hydrocarbons as simple systems of graphene sheet and ab initio MO calculations were carried out to investigate inter-molecular interaction. It is found that not triplet but singlet O2 molecule have potential of chemisorption onto graphene surface. From the calculated potential energy surface (PES) for distance between benzene and O2 molecules, meta-stable structure is found at about 1.5 Å with potential barrier. In the optimized structure of its meta-stable state, structural strain can be relaxed through bending of planer benzene ring. Its energy is estimated at 70.10 kcal/mol for benzene. We also estimated the strain effects for naphthalene and pyrene molecules as larger case of graphene and they were 80.85 and 72.45 kcal/mol, respectively. 相似文献
70.
Hemin was physically adsorbed onto porous carbon felt (CF), a microelectrode ensemble of micro-carbon fiber (ca. 7 μm in diameter) and possessing a three-dimensional random structure. The hemin-CF exhibited a well-defined redox wave that is due to Fe(III)/Fe(II) redox process in hemin, with a formal potential of ?0.32 V (vs. Ag/AgCl) in deoxygenated buffer solution of pH 7.0. The surface coverage of the electroactive hemin molecules on the surface of the CF was calculated to be 5.0?×?10?11 mol cm?2, and the apparent heterogeneous electron transfer rate constant is 3.35 s?1. The hemin-CF electrode displays excellent electrocatalytic activity for the reduction of dissolved oxygen (DO), and the magnitude of the cathodic current increases with increasing concentrations of DO in the sample solution. The electrode was used as a flow-through detector for sensitive and rapid consecutive determination of DO. Deoxygenated pH 7.0 solutions were analyzed at a flow rate of 8.0 mL min?1 at an applied potential of ?0.2 V, and highly reproducible cathodic peak current responses to DO were observed in the 0.72 to 13.3 mg L?1 concentration range. The maximum throughput is 170 samples h?1. The hemin-CF-based amperometric flow-sensor was applied to determine the concentration of DO in environmental water samples. Graphical abstract
Hemin was physically adsorbed onto porous carbon felt (CF), a microelectrode ensemble of micro-carbon fiber (ca. 7 μm in diameter). The hemin-CF electrode was used as a flow-through detector for highly sensitive and rapid determination of dissolved oxygen. 相似文献