Effects of feedback from collimating, focusing, and spot-array generating outcoupler gratings in surface-emitting semiconductor lasers

We experimentally demonstrate that a grating outcoupler used for complex beam shaping (spot-array generation) can produce unintentional optical feedback that severely disturbs the integrated in-plane laser that illuminates the coupler. Simulations show that these outcouplers, in contrast to conventional collimating or focusing outcouplers, tend to produce high levels of feedback in spite of the detuning used to suppress feedback. Further, this feedback is focused to high intensity in the laser gain medium. This focused light acts as a seed for the nonlinear self-focusing that causes wave-front distortion and filamentation, which degrades the beam quality.     

Mise en évidence d'une solution solide de type spinelle dans le diagramme de phase du systeme InS

Evidence is presented for normal-spinel domain of homogeneity between the compositions InS_1.50?ε and InS_1.35. Structural study of a single crystal of composition InS_1.44 indicates indium vacancies on the tetrahedral sites. The compound In₂S₃, regardless of conditions of formation, is a tetragonal superstructure of the spinel lattice (a₀) with $\text{a = a}{}_0\text{2}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ and c = 3a₀. The spinel-type domain shows peritectic decomposition at 850°C for the composition InS_1.40.     

Hydrogen-bond topology and the ice VII/VIII and ice Ih/XI proton-ordering phase transitions

The existence of an ice Ih/XI proton-ordering transition to a low-temperature ferroelectric phase has sparked considerable debate in the literature. Electronic density functional theory calculations, extended using graph invariants, confirm that a transition to a low-temperature ferroelectric phase should occur. The predicted transition at 98 K is in qualitative agreement with the observed transition at 72 K, and the low-temperature phase is the ferroelectric phase determined in diffraction experiments. The theoretical methods used to predict the phase transition are validated by comparing their prediction to the well-characterized ice VII/VIII proton-ordering transition.     

Low-temperature thermal conductivity of superconductors with gap nodes

We report a detailed analytic and numerical study of electronic thermal conductivity in d-wave superconductors. We compare theory of the crossover at low temperatures from T dependence to T(3) dependence for increasing temperature with recent experiments on YBa(2)Cu(3)O(7) in zero magnetic field for T approximately [0.04 K,0.4 K] by Hill et al. [Phys. Rev. Lett. 92, 027001 (2004)]. Transport theory, including impurity scattering and inelastic scattering within strong-coupling superconductivity, can consistently fit the temperature dependence of the data in the lower half of the temperature regime. We discuss the conditions under which we expect power-law dependences over wide temperature intervals.     

Single-frequency operation of a high-power, long-wavelength semiconductor disk laser

An optically pumped, high-power, single-frequency semiconductor disk laser is demonstrated. A thin (50 microm) diamond bonded to an InGaAsP gain chip provides the combined functions of heat removal and spectral filtering, thus eliminating the need for the additional intracavity etalons that are usually employed for single-frequency operation. In a short cavity (4 mm) configuration we obtained a maximum output power of 470 mW at 0 degrees C and 170 mW at 20 degrees C in a near-diffraction-limited beam (M2 < 1.2). The emission wave-length was 1549 nm and the linewidth was less than 200 MHz.     

Direct observation of a self-assembled monolayer of heptyl xanthate at the germanium/water interface: a polarized FTIR study

The adsorption of heptyl xanthate on germanium has been studied by the attenuated total reflection (ATR) technique. Polarized infrared light was used in situ to determine the average orientation of the alkyl chain in heptyl xanthate adsorbed at the germanium/solution interface. Spectra reveal the formation of closely packed xanthate ions with the alkyl chains in the all-trans conformation. The average tilt angle of the alkyl chains of heptyl xanthate was approximately 47 degrees from the surface normal.     

Use of 19F NMR spectroscopy to screen chemical libraries for ligands that bind to proteins

Identification of compounds from chemical libraries that bind to macromolecules by use of NMR spectroscopy has gained increasing importance during recent years. A simple methodology based on (19)F NMR spectroscopy for the screening of ligands that bind to proteins, which also provides qualitative information about relative binding strengths and the presence of multiple binding sites, is presented here. A library of fluorinated compounds was assembled and investigated for binding to the two bacterial chaperones PapD and FimC, and also to human serum albumin (HSA). It was found that library members which are bound to a target protein could be identified directly from line broadening and/or induced chemical shifts in a single, one-dimensional (19)F NMR spectrum. The results obtained for binding to PapD using (19)F NMR spectroscopy agreed well with independent studies based on surface plasmon resonance, providing support for the versatility and accuracy of the technique. When the library was titrated to a solution of PapD chemical shift and linewidth changes were observed with increasing ligand concentration, which indicated the presence of several binding sites on PapD and enabled the assessment of relative binding strengths for the different ligands. Screening by (19)F NMR spectroscopy should thus be a valuable addition to existing NMR techniques for evaluation of chemical libraries in bioorganic and medicinal chemistry.     

Optimal closing of a pair trade with a model containing jumps

A pair trade is a portfolio consisting of a long position in one asset and a short position in another, and it is a widely used investment strategy in the financial industry. Recently, Ekström, Lindberg, and Tysk studied the problem of optimally closing a pair trading strategy when the difference of the two assets is modelled by an Ornstein-Uhlenbeck process. In the present work the model is generalized to also include jumps. More precisely, we assume that the difference between the assets is an Ornstein-Uhlenbeck type process, driven by a Lévy process of finite activity. We prove a necessary condition for optimality (a so-called verification theorem), which takes the form of a free boundary problem for an integro-differential equation. We analyze a finite element method for this problem and prove rigorous error estimates, which are used to draw conclusions from numerical simulations. In particular, we present strong evidence for the existence and uniqueness of an optimal solution.     

A STUDY OF FAT OXIDATION IN A MICROEMULSION SYSTEM

The effect of ascorbic acid and α-tocopherol on fat oxidation has been studied in a microemulsion consisting of soybean oil, sunflower oil monoglycerides and water. It was observed that the presence of ascorbic acid in the water aggregates gave a pronounced reduction in the oxidation rate, and even after storage at 40°C for 100 days only a minor oxidation of the oil was observed, whereas the control, without ascorbic acid, was highly oxidized.