全文获取类型
收费全文 | 1335篇 |
免费 | 39篇 |
国内免费 | 5篇 |
专业分类
化学 | 901篇 |
晶体学 | 8篇 |
力学 | 39篇 |
数学 | 171篇 |
物理学 | 260篇 |
出版年
2023年 | 8篇 |
2022年 | 12篇 |
2021年 | 24篇 |
2020年 | 21篇 |
2019年 | 17篇 |
2018年 | 22篇 |
2017年 | 24篇 |
2016年 | 43篇 |
2015年 | 36篇 |
2014年 | 36篇 |
2013年 | 75篇 |
2012年 | 76篇 |
2011年 | 66篇 |
2010年 | 62篇 |
2009年 | 37篇 |
2008年 | 76篇 |
2007年 | 75篇 |
2006年 | 74篇 |
2005年 | 78篇 |
2004年 | 46篇 |
2003年 | 40篇 |
2002年 | 27篇 |
2001年 | 27篇 |
2000年 | 19篇 |
1999年 | 29篇 |
1998年 | 17篇 |
1997年 | 14篇 |
1996年 | 15篇 |
1995年 | 11篇 |
1994年 | 12篇 |
1993年 | 19篇 |
1992年 | 15篇 |
1991年 | 17篇 |
1990年 | 9篇 |
1989年 | 12篇 |
1988年 | 8篇 |
1986年 | 12篇 |
1985年 | 16篇 |
1984年 | 14篇 |
1983年 | 10篇 |
1982年 | 14篇 |
1981年 | 9篇 |
1980年 | 12篇 |
1979年 | 8篇 |
1978年 | 9篇 |
1977年 | 16篇 |
1976年 | 7篇 |
1975年 | 8篇 |
1974年 | 9篇 |
1973年 | 9篇 |
排序方式: 共有1379条查询结果,搜索用时 15 毫秒
51.
Summary A method for the determination of low relative molecular mass carboxylic acids (C1–C4) in water is reported. The acids are converted to p-bromophenacyl esters prior to a glass-capillary gas chromatographic separation. By utilizing electron-caputre detection the detectability is substantially improved compared to flame-ionization detection. A comparison of three different ways to treat the water samples and to produce the derivatives is made. It is shown that the , p-dibromoacetophenone reagent decomposes to a small extent which limits the utility of the reagent. Nevertheless a detection limit for formic acid of approximately 2.5 mgl–1 is obtained. The method is applied to the determination of formic and acetic acids in a paper kraft water sample. 相似文献
52.
53.
54.
Regioselective hydrolysis of cocaine led, according to the reaction conditions, either to benzoylecgonine or to ecgonine methyl ester. Acylation with benzoylecgonine was readily achieved when benzotriazolyloxytrisdimethylamino-phosphonium (BOP) was used as a coupling agent. 相似文献
55.
56.
Tomas Grinys Mantas Dmukauskas Mindaugas Ščiuka Saulius Nargelas Andrius Melninkaitis 《Applied Physics A: Materials Science & Processing》2014,114(2):381-385
Mg- and Si-doped GaN layers deposited by metalorganic chemical vapor deposition method were irradiated with femtosecond pulse duration laser of three different wavelengths 1,030, 515 and 343 nm. Both single and multiple shot laser induced damage thresholds of doped GaN layers were evaluated and discussed. The scanning electron microscopy employed with electron beam induced current and energy dispersive X-ray techniques were used to study laser damage morphology. It was observed that ablated area and laser-induced damage increased with irradiation fluence. The mechanism of damage generation by Gaussian beam profile laser was considered. 相似文献
57.
L. Narici M. Casolino L. Di Fino M. Larosa O. Larsson P. Picozza V. Zaconte 《Radiation measurements》2012,47(10):1030-1034
Iron abundance in cosmic rays impinging on astronauts in space habitats is of paramount importance when calculating the radiation risk for human space exploration. The concurrent high relative abundance of iron in Galactic Cosmic Rays (GCR) and iron ability to produce damages at cellular and molecular levels, together with recent radiobiology results suggests iron as a major candidate to be studied in order to produce accurate radiation hazard assessments. Iron may be in fact responsible for a large percentage of cancer risk during a long interplanetary voyage, and therefore deserves a specific attention. We built a simple model based on CREME96 for the radiation in the International Space Station (ISS) and tested it against recently performed measurements with the ALTEA and Alteino particle detectors. While we can report a good agreement between 50m and 250 keV/μm (very good for several peaks such as Si, Mg, S) we show an overestimation by this model of iron abundances of about 25–80% when compared to the measurements. New analysis on previously published work, supporting this result, are also reported.Reasons for this overestimation are discussed, they are likely to be related to the not detailed enough transport through the multiplicity of the ISS shielding and to the often used simplification of “aluminum equivalent shielding”. The iron sources in LEO, possibly not yet accurate enough when transported in Low Earth Orbit, can also play a role. New concurrent measurements (inside–outside the ISS) are suggested to help resolving this issue. 相似文献
58.
59.
Eric Johnsen Johan Larsson Ankit V. Bhagatwala William H. Cabot Parviz Moin Britton J. Olson Pradeep S. Rawat Santhosh K. Shankar Bj?rn Sj?green H.C. Yee Xiaolin Zhong Sanjiva K. Lele 《Journal of computational physics》2010,229(4):1213-1237
Flows in which shock waves and turbulence are present and interact dynamically occur in a wide range of applications, including inertial confinement fusion, supernovae explosion, and scramjet propulsion. Accurate simulations of such problems are challenging because of the contradictory requirements of numerical methods used to simulate turbulence, which must minimize any numerical dissipation that would otherwise overwhelm the small scales, and shock-capturing schemes, which introduce numerical dissipation to stabilize the solution. The objective of the present work is to evaluate the performance of several numerical methods capable of simultaneously handling turbulence and shock waves. A comprehensive range of high-resolution methods (WENO, hybrid WENO/central difference, artificial diffusivity, adaptive characteristic-based filter, and shock fitting) and suite of test cases (Taylor–Green vortex, Shu–Osher problem, shock-vorticity/entropy wave interaction, Noh problem, compressible isotropic turbulence) relevant to problems with shocks and turbulence are considered. The results indicate that the WENO methods provide sharp shock profiles, but overwhelm the physical dissipation. The hybrid method is minimally dissipative and leads to sharp shocks and well-resolved broadband turbulence, but relies on an appropriate shock sensor. Artificial diffusivity methods in which the artificial bulk viscosity is based on the magnitude of the strain-rate tensor resolve vortical structures well but damp dilatational modes in compressible turbulence; dilatation-based artificial bulk viscosity methods significantly improve this behavior. For well-defined shocks, the shock fitting approach yields good results. 相似文献
60.