火焰原子吸收光谱法测定鱼腥草、西洋参和茯苓中的铜含量

用硝酸-高氯酸混合酸(4∶1)消化鱼腥草、西洋参和茯苓,在波长324.8nm处,利用火焰原子吸收光谱法测定鱼腥草、西洋参和茯苓中铜的含量。线性回归方程为A=0.1708C 0.0004,相关系数r=0.9997,线性范围为0—5μg/mL,检出限为0.0035μg/mL,测定结果的相对标准偏差为0.09%,加标回收率为98.0%—104.2%。     

Structure and dynamics of the He 2 * (a 3Σ u + molecular complex in condensed phases of helium

An investigation is made of the absorption spectra of triplet metastable helium molecules in the a ³Σ _u ⁺ state in liquid ⁴He and ³He at various pressures and in dense ³He gas. An analysis of the spectrum corresponding to the a ³Σ _u ⁺ → c ³Σ _g ⁺ transition confirms the conclusion that there is a microscopic bubble surrounding the molecule in liquid helium. A simple approximation is proposed for the wave function of the valence electron of the molecule and the parameters of the bubble are determined for various experimental conditions. The coefficient of molecular recombination in liquid ³He and ⁴He was determined experimentally at various pressures and in dense cold ³He gas. The results show good agreement with the theory of mutual recombination limited by molecular diffusion under conditions of strong van der Waals interaction. It is shown that in the condensed phases of helium the polarization of the molecules under the action of the magnetic field does not lead to suppression of their mutual recombination, and this is confirmed experimentally.     

Surface of a 3He crystal: crossover from quantum to classical behavior

3He crystals start to show facets on their surface only at about 100 mK, well below the roughening transition temperature. To understand the reason for that, we have performed the first quantitative investigation on the growth dynamics of the basic (110) facet at 60-110 mK. The obtained values of the step free energy suggest an extremely weak coupling of the solid-liquid interface to the crystal lattice which we show to be the result of quantum fluctuations of the interface. The renormalization group approach by Nozières and Gallet, modified to incorporate quantum fluctuations, explains well the temperature dependence of the step energy measured in this work and at ultralow temperatures by Tsepelin et al., where the coupling is known to be strong. We have thus shown that, paradoxically, the role of quantum fluctuations is at higher temperatures much larger than at low temperature.