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101.
Fachinetti G Funaioli T Marchetti F 《Chemical communications (Cambridge, England)》2005,(23):2912-2914
The reaction with water of acyldicarbonyl-Ru(II) complexes relevant to ruthenium catalysed ethene hydrocarbonylation with CO/H2O is shown to consist of a nucleophilic attack and to proceed via coordination of propionate and CO to the Ru(II) species. 相似文献
102.
Buccolieri A Buccolieri G Cardellicchio N Dell'Atti A Florio ET 《Annali di chimica》2005,95(1-2):15-25
This paper shows the results of a preliminary study of air monitoring in the province of Lecce (Apulia, Southern Italy). In particular, the attention has been focused on the determination of the PM-10 level and of the concentration of nine metals (Cd, Cr, Cu, Fe, Mn, Ni, Pb, V and Zn) present on the filters which were collected in two towns (Lecce and Campi Salentina) from 2002 until 2003. The metals have been chosen on the basis of their toxicity and of their possible use as chemical tracers. The results have proved that PM-10 values and metals concentrations did not show substantial difference between the two towns and that PM-10 level and lead concentration are below the limit established by Italian law in force. The experiments have demonstrated a high correlation between iron and manganese in both sampling sites; this could be attributed to pollution of metallurgical origin. Multivariate statistical analysis, carried out by HCA and PCA methods, has been used in order to differentiate samples in relation to sampling sites, sampling period and meteorological conditions. 相似文献
103.
In this paper we study nonlinear parabolic equations using the method of upper and lower solutions. Using truncation and penalization techniques and results from the theory of operators of monotone type, we prove the existence of a periodic solution between an upper and a lower solution. Then with some monotonicity conditions we prove the existence of extremal solutions in the order interval defined by an upper and a lower solution. Finally we consider problems with discontinuities and we show that their solution set is a compact R
-set in (CT, L
2(Z)). 相似文献
104.
Luigi Angiolini Tiziana Benelli Loris Giorgini Francesco Mauriello Elisabetta Salatelli 《Macromolecular Symposia》2006,234(1):68-75
The synthesis by radical homopolymerization of a novel optically active methacrylic polymer containing a side-chain chiral moiety linked to a photochromic bisazoaromatic chromophore has been carried out starting from the related monomer (S)-3-methacryloyloxy-1-[4′-phenylazo-(4-azobenzene)]-pyrrolidine [(S)- MPAAP ]. The polymeric derivate has been fully characterized and its spectroscopic properties compared to those of the monomer and of the corresponding homopolymer bearing only one azoaromatic chromophore in the side chain. The optical activity displayed by the bisazo polymer is discussed in terms of extent of chiral conformation assumed by the macromolecules as a consequence of dipole-dipole interactions between the bisazoaromatic chromophores. 相似文献
105.
106.
Tiziana Cardinali 《Central European Journal of Mathematics》2014,12(9):1320-1329
In this paper we prove some approximate fixed point theorems which extend, in a broad sense, analogous results obtained by Brânzei, Morgan, Scalzo and Tijs in 2003. By assuming also the weak demiclosedness property we state two fixed point theorems. Moreover, we study the existence of ?-Nash equilibria. 相似文献
107.
Tiziana Cardinali Nikolaos S. Papageorgiou Paola Rubbioni 《Annali di Matematica Pura ed Applicata》2014,193(1):1-21
We consider a nonlinear Neumann logistic equation driven by the p-Laplacian with a general Carathéodory superdiffusive reaction. We are looking for positive solutions of such problems. Using minimax methods from critical point theory together with suitable truncation techniques, we show that the equation exhibits a bifurcation phenomenon with respect to the parameter λ > 0. Namely, we show that there is a λ* > 0 such that for λ < λ*, the problem has no positive solution; for λ = λ*, it has at least one positive solution; and for λ > λ*, it has at least two positive solutions. 相似文献
108.
Capillary electrophoresis separation of human milk neutral and acidic oligosaccharides derivatized with 2‐aminoacridone
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Fabio Galeotti Giovanni V. Coppa Lucia Zampini Francesca Maccari Tiziana Galeazzi Lucia Padella Lucia Santoro Orazio Gabrielli Nicola Volpi 《Electrophoresis》2014,35(6):811-818
Human milk is a unique fluid in glycobiology due to the presence of many free structurally complex oligosaccharides emerging as important dietary factors during early life and having many biological and protective functions. Methods that allow accurate profiling of oligosaccharide mixtures in this complex biological fluid with quantification of the four known genetically determined groups are welcomed. A high‐voltage CE separation and detection at 254 nm of 17 neutral and acidic human milk oligosaccharide (HMO) standard along with lactose derivatized with 2‐aminoacridone, using a BGE containing 20% methanol as an organic modifier and borate, able to form on‐capillary anionic borate‐polyol complexes, is reported. This CE approach was able to separate both neutral HMOs and acidic HMOs, with the sialic acid residue, also in the presence of lactose in high content. This method was applied to the four secretory groups individually extracted by a rapid and simple preparative step. LODs were found ranging from ~50 to 700 fmol. We were able to measure HMO content also in the presence of excess fluorophore, or interference from proteins, peptides, salts, and other impurities normally present in this complex biological fluid. Overall, CE equipped with a UV detector is a common analytical approach and this simple CE separation offers high resolution and sensitivity for the differentiation of human milk samples related to genetic groups and days of lactation by considering that important changes in HMO content are a reflection of the lactation day. 相似文献
109.
Tiziana Masullo Riccardo Puccio Mariarosaria Di Pierro Marcello Tagliavia Paolo Censi Valeria Vetri Valeria Militello Angela Cuttitta Paolo Colombo 《Applied biochemistry and biotechnology》2014,172(4):2175-2187
Fluorescent proteins from marine organisms represent potential candidates for biosensor development. In this paper, we described the isolation of a native green fluorescent protein from Anemonia sulcata and the cloning and purification of its equivalent as a recombinant protein in Escherichia coli. Furthermore, the spectroscopic behaviours of the native and recombinant GFPs were investigated as a function of Cu2+, Cd2+, Pb2+ and Ni2+ concentration. Our results suggest the high selectivity of both proteins at copper than the other metals and, for the recombinant protein, a great sensitivity at a very low concentration (0.1–1 μM). Moreover, starting from these data, using the combination of molecular biology techniques and optical setup, we developed a device for the detection of Cu2+ in water solutions. The quenching effect detected with the device showed that the relative attenuation of the signal (0.46?±?0.02 AU) was slightly larger than the data measured by fluorescence spectra (0.65?±?0.03 AU). The good sensitivity in the span of two orders of the magnitude of Cu2+ concentration, the fact that the instrument is made up of low-cost and sturdy parts and the selective quenching of rAsGFP to copper ions make this setup suited as a low cost, on-the-field, copper ion-specific biosensor. 相似文献
110.
Emanuela Esposito Irene Paterniti Emanuela Mazzon Tiziana Genovese Maria Galuppo Rosaria Meli Placido Bramanti Salvatore Cuzzocrea 《BMC neuroscience》2011,12(1):31