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A CO(2) laser extraction system is described for in situ delta(13)C analysis of organic and inorganic materials. Carbonaceous compounds volatilized by the laser are quantitatively converted to CO(2) gas by a combustion furnace mounted after the sample chamber. Gases produced by the laser and combustion processes are swept by helium carrier gas and separated by a packed gas chromatography column prior to their introduction to an isotope ratio monitoring mass spectrometer. A sample of lentil bean was analyzed at a spatial resolution of 200 μm and yielded delta(13)C values with precision of +/- 0.3 per thousand. The accuracy of delta(13)C measurements was better than +/- 0.5 per thousand from NBS 22 (mineral oil), USGS 24 (graphite), and IAEA CO-1 (calcium carbonate). Copyright 1999 John Wiley & Sons, Ltd. 相似文献
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JÉRÔME DELHOMMELLE 《Molecular physics》2013,111(21):3479-3482
Non-equilibrium molecular dynamics (NEMD) are used to calculate the vortex or rotational viscosity of fluids composed of uniaxial molecules. It is shown that the NEMD homogeneous spin flow algorithm proposed by Edberg, R., Evans, D. J., and Moriss, G. P., 1987, Molec. Phys., 62, 1357 considerably underestimates the vortex viscosity. A modified version of this algorithm is proposed and applied to liquid chlorine and nitrogen. The results are in good agreement with previous work using equilibrium or other NEMD methods, and also show that at high spin rates the vortex viscosity decreases with increase in magnitude of the external torque used to drive the spin flow. 相似文献
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In this paper, we establish several inequalities for some differantiable mappings that are connected with the Riemann-Liouville fractional integrals. The analysis used in the proofs is fairly elementar... 相似文献
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The effect of treating explicitly the coulombic and polarization interactions is investigated through the calculation of the coexistence curve of the pentane-H2S binary mixture. In this work, potential models have been developed for hydrogen sulphide and pentane, which include electrostatic sites—estimated from ab initio calculations—and polarizable sites—estimated from experimental data—in addition to Lennard-Jones sites. Compared to existing models, these new models have the same number of fitting parameters to experimental thermodynamic data. They are shown to correctly describe the coexistence curve of the pure compounds. When applied to the case of mixtures, together with Lorentz-Berthelot combining rules, they allow one to obtain a more accurate prediction of the coexisting compositions of the mixture. Furthermore, it is shown that the interaction energy in this kind of mixture cannot be properly described by using effective potential models usually considered for pure compounds. 相似文献
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Bernardino Tirri Ilaria Ciofini Juan C. Sancho-García Carlo Adamo Éric Brémond 《International journal of quantum chemistry》2020,120(13):e26233
DH-SVPD is a tailored atomic basis set originally developed to enhance the domain of applicability of double-hybrid density functionals to large molecular systems in weak interactions. In combination with any density functional belonging to this approximation, it provides an accurate estimate of noncovalent interaction energies at the cost of a double-ζ basis set, without adding a posteriori an empirical dispersion correction. Here, we show that the accuracy/cost ratio observed previously for energy properties can be safely extended to the modeling of structural parameters of small- and medium-sized organic molecules. In particular, we demonstrate that, in combination with the nonempirical PBE-QIDH double hybrid, DH-SVPD is competitive with very large quadruple-ζ basis sets when modeling both covalent and noncovalent structural parameters. 相似文献
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采用表面印迹法, 以乙烯基三甲氧基硅烷修饰的硅胶为载体, 丙烯酰胺为功能单体, N,N-亚甲基双丙烯酰胺为交联剂, 并将改性聚乙烯醇(PVA)作为辅助识别聚合物链(ARPCs)引入聚合体系中, 制备了牛血红蛋白分子印迹聚合物(MIP). 实验使用红外光谱分析了改性PVA的结构特征, 用扫描电镜(SEM)观察MIP的表面形貌, 考察了ARPCs的含量对MIP吸附性能的影响. 吸附动力学实验研究表明, 聚合体系中ARPCs的引入使MIP对模板牛血红蛋白(BHb)的吸附量明显提高|十二烷基磺酸钠-聚丙烯酰胺凝胶电泳(SDS-PAGE)结果显示, MIP对BHb的特异性吸附能力明显提高. 相似文献
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The transfer phenomena of quinine drug at the aqueous 1,2- dichloroethane (DCE)interface have been studied by the current- scanning polarography. The relationships be-tween the wave height and pH of aqueous phase, concentration of quinine as well as therate of water drop are discussed. The effect of supporting electrolyte, buffer solution andthe nature of organic solvent on the polarographic wave is studied. The transfer char-acteristics of quinine in aqueous phase and in organic phase are compared, The mono- pro-tonated and diprotonated quinines can both transfer at the interface so as to produce twopolarographic waves. The transfer process of quinine at the interface is simultaneouslycontrolled by diffusion and reestablishment of the disturbed protonated equilibrium ofquinine. A further investigation is made by chronopotentiometry. On the basis of thetheoretical analysis, the formulae of the limiting current are derived and discussed. Thetheoretical results are in agreement with the experimental ones. 相似文献
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Ali A. Alhazime M. ME. Barakat Radiyah A. Bahareth E. M. Mahrous Saad Aldawood S. Abd El Aal and S. A. Nouh 《中国物理 B》2022,31(9):97802-097802
We applied an ex-situ casting procedure to prepare a nanocomposite (NCP) from Makrofol polycarbonate (PC) and CdSe nanoparticles. The CdSe nanoparticles were prepared by a thermolysis procedure in the presence of N2 gas flow. Rietveld refinement of x-ray data illustrated that the CdSe adopts a cubic zinc blend structure of 6.057 Å lattice parameter and 2 nm typical grain size. Samples from the prepared NCP were exposed to γ dosages (20 kGy-250 kGy). The modifications induced in the NCP films owing to γ dosages have been studied. The γ irradiation (50 kGy-250 kGy) causes crosslinks that reduce the optical bandgap from 4.15 eV to 3.81 eV, associated with an increase in dielectric parameters and refractive index. This is attributed to an increase in the mass fraction of the disordered regions as specified by x-ray diffraction. The PC-CdSe NCP was found to have a reaction to color modification which makes it suitable for saleable reproduction on a printing press. 相似文献
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The use of two-photon excitation of fluorescence for detection of fluorescence resonance energy transfer (FRET) was studied for a selected fluorescent donor–acceptor pair. A method based on labeled DNA was developed for controlling the distance between the donor and the acceptor molecules. The method consists of hybridization of fluorescent oligonucleotides to a complementary single-stranded target DNA. As the efficiency of FRET is strongly distance dependent, energy transfer does not occur unless the fluorescent oligonucleotides and the target DNA are hybridized. A high degree of DNA hybridization and an excellent FRET efficiency were verified with one-photon excited fluorescence studies. Excitation spectra of fluorophores are usually wider in case of two-photon excitation than in the case of one-photon excitation [1]. This makes the selective excitation of donor difficult and might cause errors in detection of FRET with two-photon excited fluorescence. Different techniques to analyze the FRET efficiency from two-photon excited fluorescence data are discussed. The quenching of the donor fluorescence intensity turned to be the most consistent way to detect the FRET efficiency. The two-photon excited FRET is shown to give a good response to the distance between the donor and the acceptor molecules. 相似文献