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681.
Heiko Dartsch Christian Tessarek Timo Aschenbrenner Stephan Figge Carsten Kruse Marco Schowalter Andreas Rosenauer Detlef Hommel 《Journal of Crystal Growth》2011,320(1):108-112
Thermodynamic analyses of halide vapor phase epitaxy (HVPE) for the growth of ZnO were conducted to investigate the effects of growth conditions against growth rates. The partial pressures of gaseous species in equilibrium with ZnO and the resultant driving force for ZnO deposition are calculated with respect to temperatures, input H2 pressures and input VI/II ratios. It has been revealed that the driving force is weakly dependent on the temperature and is still positive even at 1200 °C, while it greatly decreases at higher temperatures in the presence of H2. The driving force is also significantly influenced when the VI/II ratio is below 1000. The experimental growth rates substantially agree with the dispositions of the driving force expected from the thermodynamic analyses. 相似文献
682.
683.
Knöner G Ratnapala A Nieminen TA Vale CJ Heckenberg NR Rubinsztein-Dunlop H 《Lab on a chip》2006,6(12):1545-1547
We present a method for characterizing microscopic optical force fields. Two dimensional vector force maps are generated by measuring the optical force applied to a probe particle for a grid of particle positions. The method is used to map out the force field created by the beam from a lensed fiber inside a liquid filled microdevice. We find transverse gradient forces and axial scattering forces on the order of 2 pN per 10 mW laser power which are constant over a considerable axial range (>35 microm). These findings suggest future useful applications of lensed fibers for particle guiding/sorting. The propulsion of a small particle at a constant velocity of 200 microm s(-1) is shown. 相似文献
684.
Jones C Aldridge S Gans-Eichler T Stasch A 《Dalton transactions (Cambridge, England : 2003)》2006,(45):5357-5361
The first examples of complexes between a 4-membered amidinato-Group 13 metal(III) heterocycle and a transition metal fragment are formed in salt elimination reactions between Na[CpFe(CO)2] and [MX2(amid)], M=Al, Ga or In; X=Cl or Br; amid-=[(RN)2CBut]-; R=Pri or cyclohexyl (Cy). The formed complexes, [CpFe(CO)2M(X)(amid)] (4 examples) have been crystallographically characterised and subject to halide abstraction reactions. In one case, the cationic complex, [CpFe(CO)2Ga(OEt2){(CyN)2CBut}][BArf4], was isolated and crystallographically characterised. A hydrolysis product of this complex, [{CpFe(CO)2Ga[(CyN)2CBut]}2(micro-OH)][BArf4], was also isolated in low yield from this reaction and structurally characterised. 相似文献
685.
686.
It is known that quadratic polynomials do not have real rationalorbits of period four. By using a two-dimensional model forthe quadratic family, this result is generalized for complexrational orbits. 2000 Mathematics Subject Classification 30D05(primary), 11G30 (secondary). 相似文献
687.
Adnan S. Abu-Surrah Kristian Lappalainen Markku Leskelä Timo Repo 《Transition Metal Chemistry》2010,35(1):7-11
Aldimine 2,6-bis[(imino)methyl]pyridine iron(II) (1, 4, and 6) and cobalt(II) (3 and 5) complexes bearing bulky cycloaliphatic (bornyl and myrtanyl) or aromatic (naphthyl) terminal groups have been applied successfully,
after activation with methyl aluminoxane (MAO), as catalysts for the polymerization of tert-butylacrylate. For comparison reasons, complex 2 that contains the ketimine ligand, 2,6-bis[(−)-cis-myrtanylimino)ethyl]pyridine (BMEP), has also been utilized. All studied complexes showed moderate polymerization activities,
and they produced high molar mass syndiorich-atactic polymers. Surprisingly, the aldimine-based catalyst systems showed comparable
activities compared with the corresponding ketimine complex (2), and they produced high molar mass polymers. In addition, complexes with bulky terminal cycloaliphatic substituents on the
tridentate aldimine ligands showed higher polymerization activity compared with the aromatic ones (6). Polymerization activity and polymer molar masses are dependent on the ligand framework. 相似文献
688.
Conventional data envelopment analysis (DEA) models assume real-valued inputs and outputs. In many occasions, some inputs and/or outputs can only take integer values. In some cases, rounding the DEA solution to the nearest whole number can lead to misleading efficiency assessments and performance targets. This paper develops the axiomatic foundation for DEA in the case of integer-valued data, introducing new axioms of “natural disposability” and “natural divisibility”. We derive a DEA production possibility set that satisfies the minimum extrapolation principle under our refined set of axioms. We also present a mixed integer linear programming formula for computing efficiency scores. An empirical application to Iranian university departments illustrates the approach. 相似文献
689.
We analyse the non-perturbative superpotential due to M5-brane instantons in F-theory compactifications on Calabi–Yau fourfolds. The M5 partition function is obtained via holomorphic factorisation by explicitly performing the sum over chiral 3-form fluxes. Comparison with the partition function of fluxed Euclidean D3-brane instantons in Type IIB orientifolds allows us to fix the spin structure on the intermediate Jacobian of the M5-instanton. We furthermore analyse the contribution of the M5-instanton to the superpotential in the presence of G4 gauge flux, where the superpotential is dressed with matter fields. We explicitly evaluate the pullback of G4 onto the M5-brane as a measure for the presence of charged instanton zero modes. This accounts for the M5 charge both under massless U(1)s, if present, and under what corresponds in Type II language to geometrically massive U(1)s. 相似文献
690.
Simulations of acoustic wave propagation in time-domain are presented. In the simulations, the discontinuous Galerkin method for spatial derivatives and the low-storage Runge–Kutta approach for time derivatives are used. Three different simulation cases are studied. First, the directivity of loudspeaker is simulated. In the second case, acoustic wave propagation in free space is studied using a short pulse. In the last case, acoustic wave scattering from a metallic cylinder is simulated. All simulation results are compared with measurement results. The measurements for the acoustic wave scattering from the metallic cylinder are made in 2D planes using an automated measurement system. Comparison between the simulation and measurement results are made both temporally and spatially and a good agreement between the simulation and measurement results is found. The results suggest that the discontinuous Galerkin method coupled with the low-storage Runge–Kutta approach is a viable tool for modeling acoustic wave propagation in the time-domain. 相似文献