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81.
Kemmitt T Al-Salim NI Gainsford GJ Bubendorfer A Waterland M 《Inorganic chemistry》2004,43(20):6300-6306
Aqueous titanium citrate solutions were prepared from the reaction of citric acid with titanium 2-propoxide in a range of molar ratios. Solutions containing two or fewer citrates per titanium resulted in the slow crystallization of an insoluble titanium oxo-citrate complex. Single-crystal X-ray analysis identified the species as Ti(8)O(10)(citrate)(4)(H(2)O)(12).14H(2)O.3HOPr(i)(), crystallized in the tetragonal space group I4(1)/a, with a = 30.775(7) A, c = 14.528(7) A, V = 13 759(8) A(3), and Z = 8. The trianionic citrate ligands supply both carboxylate and alkoxide coordination and stabilize the structure using simultaneous chelating and bridging modes of attachment. The compound is a neutral species, exhibiting titanium in three contrasting environments. Laser Raman microscopy and (13)C CPMAS solid-state NMR data were consistent with those of the X-ray crystal structure. When exposed to air, the crystals rapidly lost water and became a powder. The dehydrated powder was noncrystalline to X-rays and insoluble, but (13)C NMR results demonstrated retention of the carboxylate linkages. 相似文献
82.
Woonghee Tim Huh 《Operations Research Letters》2004,32(3):212-216
This paper studies the NP-hard problem of finding a minimum size 2-edge connected spanning subgraph (2-ECSS). An algorithm is given that on an r-edge connected input graph G=(V,E) finds a 2-ECSS of size at most |V|+(|E|−|V|)/(r−1). For r-regular, r-edge connected input graphs for r=3, 4, 5 and 6, this gives approximation guarantees of and , respectively. 相似文献
83.
We demonstrate the controlled coherent transport and splitting of atomic wave packets in spin-dependent optical lattice potentials. Such experiments open intriguing possibilities for quantum state engineering of many body states. After first preparing localized atomic wave functions in an optical lattice through a Mott insulating phase, we place each atom in a superposition of two internal spin states. Then state selective optical potentials are used to split the wave function of a single atom and transport the corresponding wave packets in two opposite directions. Coherence between the wave packets of an atom delocalized over up to seven lattice sites is demonstrated. 相似文献
84.
Hong H Gates PJ Staunton J Stinear T Cole ST Leadlay PF Spencer JB 《Chemical communications (Cambridge, England)》2003,(22):2822-2823
LC-MSn analysis of mycolactone toxin from extracts of Mycobacterium ulcerans has shown that minor co-metabolites, including two previously unreported, differ structurally from mycolactone only in a small portion of the polyketide side-chain. 相似文献
85.
Sobolevsky TG Chernetsova ES Revelsky AI Revelsky IA Starostin AB Miller B Oriedo V 《European journal of mass spectrometry (Chichester, England)》2003,9(5):487-495
Mass spectra of trialkylsilyl derivatives of fatty acids, dicarboxylic acids, hydroxyacids, oxoacids, sugars, amino acids and alcohols were obtained. Amino acids were analyzed as tert-butyldimethylsilyl derivatives; all other model compounds were analyzed as trimethylsilyl derivatives. Reproducibility of the electron ionization (EI) mass spectra for the derivatives obtained was discussed. It was shown that, for many investigated derivatives, composition of the respective mass spectra depended greatly on ion source contamination. The trimethylsilylated alpha-tocopherol mass spectrum composition was most significantly influenced by ion source contamination. This compound can be used to test ion source contamination. 相似文献
86.
Craig MR Hutchings MG Claridge TD Anderson HL 《Angewandte Chemie (International ed. in English)》2001,40(6):1071-1074
87.
D. Sohler Zs. Dombrádi J. Blomqvist J. Cederkäll J. Huijnen M. Lipoglavšek M. Palacz A. Atac C. Fahlander H. Grawe A. Johnson A. Kerek W. Klamra J. Kownacki A. Likar L.-O. Norlin J. Nyberg J. Persson D. Seweryniak G. de Angelis P. Bednarczyk D. Foltescu D. Jerrestam S. Juutinen E. Mäkelä M. de Poli H.A. Roth T. Shizuma Ö. Skeppstedt G. Sletten J. Timár S. Törmänen M. Weiszflog 《The European Physical Journal A - Hadrons and Nuclei》2003,16(2):171-175
Excited states of 99Ag were populated via the 50Cr + 58Ni (261 MeV) reaction using the NORDBALL detector array equipped with charged-particle and neutron detector systems for reaction
channel separation. On the basis of the measured γγ-coincidence relations and angular distribution ratios a significantly
extended level scheme has been constructed up to E
x ∼ 7.8 MeV and I = 35/2. The experimental results were described within the framework of the shell model. Candidates for states fully aligned
in the πg
9/2
-3ν(d
5/2, g
7/2)2 valence configuration space were found at 4109 and 6265 keV.
Received: 18 June 2002 / Accepted: 11 October 2002 / Published online: 4 February 2003
RID="a"
ID="a"e-mail: sohler@atomki.hu
Communicated by J. ?yst? 相似文献
88.
We propose a simple abstract version of Calderón–Zygmund theory, which is applicable to spaces with exponential volume growth, and then show that important specific operators can be treated within this framework.
Both authors are part of the European TMR network entitled ``Harmonic Analysis'. The first author was partially supported by KBN grant 5 P03A 050 20 and by the TMR network. The second author was partially supported by his university and by the Italian M.U.R.S.T 相似文献
89.
In this paper k-sets of type (a, b) with respect to hyperplanes are constructed in finite projective spaces using powers of Singer cycles. These are then used to construct further examples of sets of type (a, b) using various disjoint sets. The parameters of the associated strongly regular graphs are also calculated. The construction technique is then related to work of Foulser and Kallaher classifying rank three subgroups of AL(1, p
R). It is shown that the sets of type (a, b) arising from the Foulser and Kallaher construction in the case of projective spaces are isomorphic to some of those constructed in the present paper. 相似文献
90.
Tim Haslett Simon Moss Charles Osborne Paul Ramm 《Nonlinear dynamics, psychology, and life sciences》2000,4(1):67-86
This paper examines the imposition of local rules in five mail delivery centres of Australia Post. Local rules are patterns of behaviour used by subunits of an organization to optimise their payoff. These local rules may ultimately benefit the total organization. Fitness landscapes are used to examine the emergence of local rules in this workplace. This research examined the relationship between the time taken to sort the mail and the volume of this mail. Work rates show a clear catastrophe shift; that is, work rates suddenly drop when the volume of mail exceeds a certain level, as Postal Delivery Officers apply local rules to maximise gains inherent in the pay structures. Such behaviour is close to that predicted by Kauffman (1995) in computer simulations of lattices and may be indicative of the application of local rules in organizations. The implications of the use of local rules are that behaviour in social systems may be dictated by systemic and emergent processes which are outside immediate management control. A further implication is that organizations may be structured to a significant extent by such local rules. 相似文献